Patent classifications
C06B25/20
Ionone stabilisers for nitrocellulose-based propellants
The present disclosure is directed to a nitrocellulose-based propellant composition comprising: (a) a nitrate ester-based propellant comprising nitrocellulose; and (b) a stabiliser comprising a non-aromatic compound (12) consisting of a general ionone formula (12-I), (12-II), (12-III) or (12-IV): ##STR00001##
wherein R.sup.1 represents a ketone, hydroxyl, carboxyl, aldehyde or an unsaturated alkyl group, preferably C(O)CH.sub.3 (corresponding to alpha, beta, gamma and pseudo ionone).
Ionone stabilisers for nitrocellulose-based propellants
The present disclosure is directed to a nitrocellulose-based propellant composition comprising: (a) a nitrate ester-based propellant comprising nitrocellulose; and (b) a stabiliser comprising a non-aromatic compound (12) consisting of a general ionone formula (12-I), (12-II), (12-III) or (12-IV): ##STR00001##
wherein R.sup.1 represents a ketone, hydroxyl, carboxyl, aldehyde or an unsaturated alkyl group, preferably C(O)CH.sub.3 (corresponding to alpha, beta, gamma and pseudo ionone).
Tocopherol stabilisers for nitrocellulose-based propellants
The present disclosure is directed to a nitrocellulose-based propellant composition comprising: (a) a nitrate ester based propellant comprising nitrocellulose; and (b) a stabilizer consisting of a tocopherol compound with a general formula (I), ##STR00001##
wherein: X is oxygen; R.sup.1 is selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, aryl, heteroaryl, carboxylic acid, carboxylate, ester, saccharide, alkoxy-linked saccharide, alcohol, and ethers; R.sup.2 is selected from the group consisting of hydrogen methyl, benzyl carboxylic acid, benzyl carboxylate, benzylester and saccharide; R.sup.3 is selected from the group consisting of hydrogen, methyl, benzyl carboxylic acid, benzyl carboxylate, benzylester and saccharide; R.sup.4 is selected from the group consisting of methyl, benzyl carboxylic acid, benzyl carboxylate, benzylester and saccharide; and R.sup.5 is selected from the group consisting of alkyl and alkenyl.
Tocopherol stabilisers for nitrocellulose-based propellants
The present disclosure is directed to a nitrocellulose-based propellant composition comprising: (a) a nitrate ester based propellant comprising nitrocellulose; and (b) a stabilizer consisting of a tocopherol compound with a general formula (I), ##STR00001##
wherein: X is oxygen; R.sup.1 is selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, aryl, heteroaryl, carboxylic acid, carboxylate, ester, saccharide, alkoxy-linked saccharide, alcohol, and ethers; R.sup.2 is selected from the group consisting of hydrogen methyl, benzyl carboxylic acid, benzyl carboxylate, benzylester and saccharide; R.sup.3 is selected from the group consisting of hydrogen, methyl, benzyl carboxylic acid, benzyl carboxylate, benzylester and saccharide; R.sup.4 is selected from the group consisting of methyl, benzyl carboxylic acid, benzyl carboxylate, benzylester and saccharide; and R.sup.5 is selected from the group consisting of alkyl and alkenyl.
PROPELLANT STABILIZER
The invention relates generally to propellant stabilizers. The invention also relates to methods of producing a propellant comprising a propellant stabilizer as well as an ammunition cartridge comprising the stabilized propellant. The propellant stabilizer comprises a compound of formula 1
##STR00001##
and the propellant comprises a compound of formula 1 and an energetic material.
PROPELLANT STABILIZER
The invention relates generally to propellant stabilizers. The invention also relates to methods of producing a propellant comprising a propellant stabilizer as well as an ammunition cartridge comprising the stabilized propellant. The propellant stabilizer comprises a compound of formula 1
##STR00001##
and the propellant comprises a compound of formula 1 and an energetic material.
Stabilized nitrocellulose-based propellant composition
The present invention concerns a nitrocellulose-based propellant composition comprising: (a) a nitrate ester based propellant consisting of nitrocellulose alone (single base) or in combination at least with a blasting oil (double or higher base); and (b) a stabilizer consisting of a general formula (I): ##STR00001##
Wherein the stabilizer combines efficient, long term stability of the nitrocellulose-based propellants composition without formation of any detectable amounts of carcinogenic or mutagenic by-products, such as NNO groups.
Stabilized nitrocellulose-based propellant composition
The present invention concerns a nitrocellulose-based propellant composition comprising: (a) a nitrate ester based propellant consisting of nitrocellulose alone (single base) or in combination at least with a blasting oil (double or higher base); and (b) a stabilizer consisting of a general formula (I): ##STR00001##
Wherein the stabilizer combines efficient, long term stability of the nitrocellulose-based propellants composition without formation of any detectable amounts of carcinogenic or mutagenic by-products, such as NNO groups.
Resin Cured Binary Explosive
The devices and methods described below provide for a plasticized, adhesive binary explosive mixture formed with nitromethane (NM) plasticized with nitrocellulose (NC) as an energetic component and a urethane resin mixed with any suitable mechanical sensitizer as the sensitizer component. The addition of the sensitizer component to the plasticized component of NM/NC causes the resulting gel mixture to become explosive while maintaining stability.
Resin Cured Binary Explosive
The devices and methods described below provide for a plasticized, adhesive binary explosive mixture formed with nitromethane (NM) plasticized with nitrocellulose (NC) as an energetic component and a urethane resin mixed with any suitable mechanical sensitizer as the sensitizer component. The addition of the sensitizer component to the plasticized component of NM/NC causes the resulting gel mixture to become explosive while maintaining stability.