A process for preparing C.sub.2 to C.sub.5 paraffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C.sub.2 to C.sub.5 paraffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component.

A process for the production of syngas, the process comprising (i) reacting at least a portion of carbon dioxide with hydrogen within an initial reactor to produce an initial product stream including carbon monoxide, water, unreacted carbon dioxide, and unreacted hydrogen; and (ii) reacting at least a portion of the unreacted carbon dioxide and unreacted hydrogen within a reactor downstream of the first reactor to thereby produce a product stream including carbon monoxide, water, unreacted carbon dioxide, and unreacted hydrogen.

Provided is a first step of causing hydrogen and carbon oxide to react with each other in a presence of a first catalyst to obtain a first fuel gas 2 that contains 2% to 10% hydrogen by volume after dehydration; and a second step of consuming the hydrogen in the first fuel gas 2 to obtain a second fuel gas 4 with a reduced hydrogen concentration. The first catalyst includes a methanation catalyst. The second step includes an exothermic reaction that generates heat of 60 kJ or more per mole of hydrogen, and the exothermic reaction is a reaction through which the hydrogen in the first fuel gas 2 and a predetermined reactant 3 are caused to react with each other in a presence of a second catalyst to generate water or a paraffin hydrocarbon with two to four carbon atoms.

Provided is a first step of causing hydrogen and carbon oxide to react with each other in a presence of a first catalyst to obtain a first fuel gas 2 that contains 2% to 10% hydrogen by volume after dehydration; and a second step of consuming the hydrogen in the first fuel gas 2 to obtain a second fuel gas 4 with a reduced hydrogen concentration. The first catalyst includes a methanation catalyst. The second step includes an exothermic reaction that generates heat of 60 kJ or more per mole of hydrogen, and the exothermic reaction is a reaction through which the hydrogen in the first fuel gas 2 and a predetermined reactant 3 are caused to react with each other in a presence of a second catalyst to generate water or a paraffin hydrocarbon with two to four carbon atoms.

Separation of carbon dioxide from the exhaust of an internal combustion engine, the production of hydrogen from water, and reformation of carbon dioxide and hydrogen into relatively high-octane fuel components.

Ammonia, methanol, Fischer Tropsch products, and derivatives thereof are made by using hydrogen and oxygen supplied from an electrolyzer that is at least partially powered by renewable power, resulting in green process and systems that produce green products disclosed herein. A process using biomass and renewable energy includes producing an unshifted syngas from biomass and oxygen in a gasification unit, introducing water into an electrolyzer to produce an oxygen product and a hydrogen product, and introducing the oxygen product to the gasification unit. The electrolyzer is powered by renewable energy, and the oxygen product supplies at least a portion of the oxygen to the gasification unit.

Embodiments of the present invention relates to two improved catalysts and associated processes that directly converts carbon dioxide and hydrogen to liquid fuels. The catalytic converter is comprised of two catalysts in series that are operated at the same pressures to directly produce synthetic liquid fuels or synthetic natural gas. The carbon conversion efficiency for CO.sub.2 to liquid fuels is greater than 45%. The fuel is distilled into a premium diesel fuels (approximately 70 volume %) and naphtha (approximately 30 volume %) which are used directly as “drop-in” fuels without requiring any further processing. Any light hydrocarbons that are present with the carbon dioxide are also converted directly to fuels. This process is directly applicable to the conversion of CO.sub.2 collected from ethanol plants, cement plants, power plants, biogas, carbon dioxide/hydrocarbon mixtures from secondary oil recovery, and other carbon dioxide/hydrocarbon streams. The catalyst system is durable, efficient and maintains a relatively constant level of fuel productivity over long periods of time without requiring re-activation or replacement.

The present disclosure relates to the field of Fischer-Tropsch synthesis reaction catalysts, and discloses a pure phase ε/ε′ iron carbide catalyst for Fischer-Tropsch synthesis reaction, a preparation method thereof and a Fischer-Tropsch synthesis process, wherein the method comprises the following steps: (1) subjecting the nanometer iron powder or a nano-powder iron compound capable of obtaining the nanometer iron powder through in-situ reduction and H.sub.2 to a surface purification treatment at the temperature of 250-510° C.; (2) pretreating the material obtained in the step (1) with H.sub.2 and CO at the temperature of 80-180° C., wherein the molar ratio of H.sub.2/CO is 1.2-2.8:1; (3) carrying out carbide preparation with the material obtained in the step (2), H.sub.2 and CO at the temperature of 180-280° C., wherein the molar ratio of H.sub.2/CO is 1.0-3.0:1. The preparation method has the advantages of simple and easily obtained raw materials, simple and convenient operation steps, being capable of preparing the 100% pure phase ε/ε′ iron carbide catalyst having lower selectivity of CO.sub.2 and CH.sub.4 and higher selectivity of effective products.

Fischer-Tropsch process for the synthesis of hydrocarbons by bringing a feedstock including synthesis gas into contact with a catalyst prepared by the following: a porous support is brought into contact with a cobalt metal salt of which the melting point of the cobalt metal salt is between 30 and 150° C. for between 5 minutes and 5 hours, in order to form a solid mixture, the weight ratio of said cobalt metal salt to the porous oxide support being between 0.1 and 1; the solid mixture obtained is heated with stirring under atmospheric pressure at a temperature between the melting point of the cobalt metal salt and 200° C. for a period of time of between 30 minutes and 12 hours; the solid obtained is calcined at a temperature above 200° C. and below or equal to 1100° C.

A process for preparing C.sub.2 to C.sub.4 olefins includes introducing a feed stream of hydrogen gas and a carbon-containing gas into a reaction zone of a reactor and converting the feed stream into a product stream including C.sub.2 to C.sub.4 olefins in the reaction zone in the presence of a hybrid catalyst and in a non-oxidative atmosphere. The hybrid catalyst includes a metal oxide catalyst component comprising gallium oxide and zirconia, and a microporous catalyst component having an 8 membered ring structure. The process also includes periodically introducing an oxidative atmosphere into the reaction zone.