A CO.sub.2 separation/recover method in cement production exhaust gas has a step of harmful component removal that removes an acidic component and a harmful component from exhaust gas discharged from a cement production facility; and a step of CO.sub.2 separation and recover that separates and recovers CO.sub.2 by bringing the exhaust gas from which the acidic component and the harmful component are removed into contact with a CO.sub.2 absorption material, so that the acidic component and the harmful component are removed before separating and recovering CO.sub.2, resulting in deterioration of the absorbing ability of the CO.sub.2 absorption material being suppressed; and the cement production exhaust gas can be appropriately disposed.

PROBLEM TO BE SOLVED:

In an apparatus for synthesizing methane from carbon dioxide and hydrogen, a device which is capable to remove the reaction heat and lower the reaction temperature as the reaction progresses in order to increase the conversion ratio to methane has been desired.

SOLUTION:

In the present invention, powders of magnesium hydroxide and magnesium carbonate, which are chemical heat storage agents, are used as part of the fluidizing medium of the multi-stage fluidized bed in the temperature range where the methanation reaction proceeds. The heat generated during the methanation reaction can be absorbed and stored in the powder. At this time, carbon dioxide generated from magnesium carbonate can be used as a raw material gas for the methanation reaction. Furthermore, after discharging the magnesium oxide generated by endotherm, the powder can be regenerated with an external regenerating facility and then the storage heat can be released and recovered. The regenerated powder can be fed to the uppermost stage of the multi-stage fluidized bed at a temperature lower than the internal temperature of the reactor to lower inside temperature. This made it possible to lower the reaction temperature of ascending reaction gas in the reactor along with the reaction progress, and to increase the conversion ratio to the produced methane by this lowered temperature.

The present invention relates to a hybrid iron nanoparticle catalyst comprising: i) 1 to 50 wt. % nanoparticles comprising iron and at least one of a metal M selected from the group consisting of alkali metals, alkaline earth metals, transition metals of groups 3 to 7 and 9 to 11 of the Periodic Table of Elements, lanthanides and combinations of M thereof; and ii) 50 to 99 wt. % of an aluminosilicate or silicoaluminophosphate zeolite, based on the total weight of the catalyst, wherein said nanoparticle has a diameter of about 2 to 50 nm. The present invention also relates to a method of preparing the hybrid iron nanoparticle catalyst and a process for the production of light olefins using the hybrid iron nanoparticle catalyst.

The present invention relates to a hybrid iron nanoparticle catalyst comprising: i) 1 to 50 wt. % nanoparticles comprising iron and at least one of a metal M selected from the group consisting of alkali metals, alkaline earth metals, transition metals of groups 3 to 7 and 9 to 11 of the Periodic Table of Elements, lanthanides and combinations of M thereof; and ii) 50 to 99 wt. % of an aluminosilicate or silicoaluminophosphate zeolite, based on the total weight of the catalyst, wherein said nanoparticle has a diameter of about 2 to 50 nm. The present invention also relates to a method of preparing the hybrid iron nanoparticle catalyst and a process for the production of light olefins using the hybrid iron nanoparticle catalyst.

Generating methane by adding hydrogen to CO.sub.2 in exhaust gas discharged a from cement production facility or CO.sub.2 that is separated and recovered from the exhaust gas, and using the methane as an alternative fuel to fossil fuel such as coal, petroleum, natural gas and the like, by methanation of CO.sub.2 in the exhaust gas from the cement production facility that includes exhaust gas originated from lime stone not from the fossil oil and effectively utilizing it, it is possible to reduce usage of the fossil fuel, suppress CO.sub.2 originated from energy, and improve an effect of reducing greenhouse gas.

Generating methane by adding hydrogen to CO.sub.2 in exhaust gas discharged a from cement production facility or CO.sub.2 that is separated and recovered from the exhaust gas, and using the methane as an alternative fuel to fossil fuel such as coal, petroleum, natural gas and the like, by methanation of CO.sub.2 in the exhaust gas from the cement production facility that includes exhaust gas originated from lime stone not from the fossil oil and effectively utilizing it, it is possible to reduce usage of the fossil fuel, suppress CO.sub.2 originated from energy, and improve an effect of reducing greenhouse gas.

Generating methane by adding hydrogen to CO.sub.2 in exhaust gas discharged a from cement production facility or CO.sub.2 that is separated and recovered from the exhaust gas, and using the methane as an alternative fuel to fossil fuel such as coal, petroleum, natural gas and the like, by methanation of CO.sub.2 in the exhaust gas from the cement production facility that includes exhaust gas originated from lime stone not from the fossil oil and effectively utilizing it, it is possible to reduce usage of the fossil fuel, suppress CO.sub.2 originated from energy, and improve an effect of reducing greenhouse gas.

A carbon compound manufacturing system includes: a recovery unit; a conversion unit; a synthesis unit; a first flow path to supply the supply gas to the recovery unit; a second flow path connecting the recovery and the conversion units; a third flow path connecting the conversion and the synthesis units; at least one of first to third detectors to respectively measure a flow rate of the supply gas flowing through the first flow path to generate a first data signal, a flow rate of the carbon dioxide flowing through the second flow path to generate a second data signal, and a value of voltage or current to the conversion unit to generate a third data signal; and an integration controller to collate at least one data of the first to third data signals with a corresponding plan data to generate at least one of first to third control signals.

A carbon compound manufacturing system includes: a recovery unit; a conversion unit; a synthesis unit; a first flow path to supply the supply gas to the recovery unit; a second flow path connecting the recovery and the conversion units; a third flow path connecting the conversion and the synthesis units; at least one of first to third detectors to respectively measure a flow rate of the supply gas flowing through the first flow path to generate a first data signal, a flow rate of the carbon dioxide flowing through the second flow path to generate a second data signal, and a value of voltage or current to the conversion unit to generate a third data signal; and an integration controller to collate at least one data of the first to third data signals with a corresponding plan data to generate at least one of first to third control signals.

One variation of a method includes: ingesting an air sample captured during an air capture period at a target location for collection of a first mixture including carbon dioxide and a first concentration of impurities; conveying the first mixture through a liquefaction unit to generate a second mixture including carbon dioxide and a second concentration of impurities less than the first concentration of impurities; in a methanation reactor, mixing the second mixture with hydrogen to generate a first hydrocarbon mixture comprising a third concentration of impurities comprising nitrogen, carbon dioxide, and hydrogen; conveying the first hydrocarbon mixture through a separation unit configured to remove impurities from the first hydrocarbon mixture to generate a second hydrocarbon a fourth concentration of impurities less than the third concentration of impurities; and depositing the second hydrocarbon mixture in a diamond reactor containing a set of diamond seeds to generate a first set of diamonds.