The present invention provides for a composition comprising a heterostructure capable of electrochemical CO reduction to a carbon-carbon product, comprising an inorganic material and a porous molecule.

The present invention provides for a composition comprising a heterostructure capable of electrochemical CO reduction to a carbon-carbon product, comprising an inorganic material and a porous molecule.

The present invention provides for a composition comprising a heterostructure capable of electrochemical CO reduction to a carbon-carbon product, comprising an inorganic material and a porous molecule.

Disclosed herein are carbon doped tin disulphide (CSnS.sub.2) and other SnS.sub.2 composites as visible light photocatalyst for CO.sub.2 reduction to solar fuels. The in situ carbon doped SnS.sub.2 photocatalyst provide higher efficiency than the undoped pure SnS.sub.2. Also disclosed herein are methods for preparing the catalysts.

Disclosed herein are carbon doped tin disulphide (CSnS.sub.2) and other SnS.sub.2 composites as visible light photocatalyst for CO.sub.2 reduction to solar fuels. The in situ carbon doped SnS.sub.2 photocatalyst provide higher efficiency than the undoped pure SnS.sub.2. Also disclosed herein are methods for preparing the catalysts.

Carbon dioxide is reacted with methane in a free radical reaction to produce methanol and carbon monoxide. A system for producing carbon dioxide as a feed ingredient for the process through electric power generator is disclosed.

Carbon dioxide is reacted with methane in a free radical reaction to produce methanol and carbon monoxide. A system for producing carbon dioxide as a feed ingredient for the process through electric power generator is disclosed.

Carbon dioxide is reacted with methane in a free radical reaction to produce methanol and carbon monoxide. A system for producing carbon dioxide as a feed ingredient for the process through electric power generator is disclosed.

A compound having formula I that is useful for CO reduction is provided:

##STR00001##

wherein:
M is a transition metal;
X.sub.1, X.sub.2 are each independently a counterion; and
R.sub.1, R.sub.2, R.sub.3 are each independently H, C.sub.1-6 alkyl, C.sub.6-15 aryl, or C.sub.6-15 heteroaryl.

A compound having formula I that is useful for CO reduction is provided:

##STR00001##

wherein:
M is a transition metal;
X.sub.1, X.sub.2 are each independently a counterion; and
R.sub.1, R.sub.2, R.sub.3 are each independently H, C.sub.1-6 alkyl, C.sub.6-15 aryl, or C.sub.6-15 heteroaryl.