Patent classifications
C07C33/20
KEY INTERMEDIATE FOR SYNTHESIS OF PROSTAGLANDIN COMPOUND AND PREPARATION METHOD THEREOF
The present invention relates to the technical field of organic chemical engineering, and in particular to a key intermediate for synthesizing prostaglandin compounds and a preparation method therefor. When applied to the synthesis of prostaglandin compounds, the process flow is simplified, the yield and product purity are improved, the production costs are reduced, and the industrial application is easy.
##STR00001##
Preparation of 5-aryl-pentanols
The present invention relates to a method for preparing 5-aryl pentanols from 2-aryl-4-hydroxytetrahydropyrans as starting materials.
Preparation of 5-aryl-pentanols
The present invention relates to a method for preparing 5-aryl pentanols from 2-aryl-4-hydroxytetrahydropyrans as starting materials.
PREPARATION OF 5-ARYL-PENTANOLS
The present invention relates to a method for preparing 5-aryl pentanols from 2-aryl-4-hydroxytetrahydropyrans as starting materials.
PREPARATION OF 5-ARYL-PENTANOLS
The present invention relates to a method for preparing 5-aryl pentanols from 2-aryl-4-hydroxytetrahydropyrans as starting materials.
Monocarbonyl ruthenium and osmium catalysts
The invention relates to monocarbonyl complexes of ruthenium and osmium with bi- and tridentate nitrogen and phosphine ligands. The invention relates to methods for preparing these complexes and the use of these complexes, isolated or prepared in situ, as catalysts for reduction reactions of ketones and aldehydes both via transfer hydrogenation or hydrogenation with hydrogen.
Monocarbonyl ruthenium and osmium catalysts
The invention relates to monocarbonyl complexes of ruthenium and osmium with bi- and tridentate nitrogen and phosphine ligands. The invention relates to methods for preparing these complexes and the use of these complexes, isolated or prepared in situ, as catalysts for reduction reactions of ketones and aldehydes both via transfer hydrogenation or hydrogenation with hydrogen.
Chiral metal complex compounds
The invention comprises novel chiral metal complex compounds of the formula ##STR00001## wherein M, PR.sup.2, R.sup.3 and R.sup.4 are outlined in the description, its stereoisomers, in the form as a neutral complex or a complex cation with a suitable counter ion. The chiral metal complex compounds can be used in asymmetric reactions, particularly in asymmetric reductions of ketones, imines or oximes.
Chiral metal complex compounds
The invention comprises novel chiral metal complex compounds of the formula ##STR00001## wherein M, PR.sup.2, R.sup.3 and R.sup.4 are outlined in the description, its stereoisomers, in the form as a neutral complex or a complex cation with a suitable counter ion. The chiral metal complex compounds can be used in asymmetric reactions, particularly in asymmetric reductions of ketones, imines or oximes.
METHOD AND CATALYST FOR PRODUCING METHYLBENZYL ALCOHOL FROM ETHANOL BY CATALYTIC CONVERSION
The present invention relates to methods and catalysts for producing methylbenzyl alcohol from ethanol by catalytic conversion, and belongs to the field of chemical engineering and technology. The present invention develops a route of producing methylbenzyl alcohol starting from green and sustainable ethanol and provide corresponding catalysts used for the catalytic conversion route. This innovative reaction route has several advantages, such as, simple process, eco-friendly property, and easy separation of products, as compared with a traditional petroleum-based route. This present route has a reaction temperature of 150-450° C. and total selectivity of 72% for methylbenzyl alcohol, and has good industrial application prospect. The innovation of this patent comprises the catalysts synthesis and the reaction route.