Patent classifications
C07C51/412
Formic acid formation from a carbon dioxide source
The disclosure concerns a process for producing formic acid, having (a) a carbon capture step in which a source of carbon dioxide is contacted with an amine solution in a closed-top scrubber, to obtain an ammonium bicarbonate solution; (b) inducing crystallization in the ammonium bicarbonate solution to obtain a concentrated ammonium bicarbonate solution; (c) subjecting the concentrated ammonium bicarbonate solution to a hydrogenation step to obtain an ammonium formate; and (d) heating the ammonium formate to a temperature in the range of 50-150° C., to obtain a gaseous product containing the amine and a liquid product stream containing formic acid. The source of carbon dioxide has a carbon dioxide content of at least 95 vol % and the amine used in step (a) and reformed in step (d) has a partial vapour pressure above a 40 wt % solution of the amine in water at 20° C. of at least 40 kPa. The disclosure further concerns a system for performing the process.
CRYSTALLINE FORMS OF SODIUM SALT OF BEMPEDOIC ACID
The presented invention relates to crystalline Forms (I) or (II) or (III) or (IV) of sodium salt of Bempedoic acid, processes for preparation thereof and a composition comprising it.
CRYSTALLINE FORMS OF SODIUM SALT OF BEMPEDOIC ACID
The presented invention relates to crystalline Forms (I) or (II) or (III) or (IV) of sodium salt of Bempedoic acid, processes for preparation thereof and a composition comprising it.
METHOD FOR PREPARING LITHIUM IRON MANGANESE PHOSPHATE PRECURSOR AND METHOD FOR PREPARING LITHIUM IRON MANGANESE PHOSPHATE
Disclosed are a method for preparing lithium iron manganese phosphate precursor and a method for preparing lithium iron manganese phosphate. The method for preparing lithium iron manganese phosphate precursor comprises the following steps: (1) preparing liquid material A and liquid material B, wherein the liquid material A is a mixed solution of manganese salt and iron salt, and the liquid material B is oxalic acid or phosphoric acid solution; (2) subjecting liquid material A and liquid material B to a co-precipitation reaction in a rotary packed bed (100) to obtain a first slurry; (3) washing and filtering the first slurry to obtain a filter cake; (4) mixing the filter cake with water, adding a carbon source, and stirring until uniform to obtain a second slurry; (5) homogenizing the second slurry; (6) drying the homogenized second slurry, to obtain the lithium iron manganese phosphate precursor. The particle size of the lithium iron manganese phosphate precursor prepared by the method is finer and more uniform than that of a precursor prepared by a traditional method using a reaction kettle, the preparation speed is increased, and the carbon coating is more uniform. FIG. 1: : lithium iron manganese phosphate precursor FIG. 2:
: lithium iron manganese phosphate FIG. 3:
(V): Voltage (V)
(mAh/g): Specific capacity (mAh/g)
: charge curve
: discharge curve FIG. 4:
(mAh/g): Discharge specific capacity (mAh/g)
METHOD FOR PREPARING LITHIUM IRON MANGANESE PHOSPHATE PRECURSOR AND METHOD FOR PREPARING LITHIUM IRON MANGANESE PHOSPHATE
Disclosed are a method for preparing lithium iron manganese phosphate precursor and a method for preparing lithium iron manganese phosphate. The method for preparing lithium iron manganese phosphate precursor comprises the following steps: (1) preparing liquid material A and liquid material B, wherein the liquid material A is a mixed solution of manganese salt and iron salt, and the liquid material B is oxalic acid or phosphoric acid solution; (2) subjecting liquid material A and liquid material B to a co-precipitation reaction in a rotary packed bed (100) to obtain a first slurry; (3) washing and filtering the first slurry to obtain a filter cake; (4) mixing the filter cake with water, adding a carbon source, and stirring until uniform to obtain a second slurry; (5) homogenizing the second slurry; (6) drying the homogenized second slurry, to obtain the lithium iron manganese phosphate precursor. The particle size of the lithium iron manganese phosphate precursor prepared by the method is finer and more uniform than that of a precursor prepared by a traditional method using a reaction kettle, the preparation speed is increased, and the carbon coating is more uniform. FIG. 1: : lithium iron manganese phosphate precursor FIG. 2:
: lithium iron manganese phosphate FIG. 3:
(V): Voltage (V)
(mAh/g): Specific capacity (mAh/g)
: charge curve
: discharge curve FIG. 4:
(mAh/g): Discharge specific capacity (mAh/g)
Processes for Producing Alkyl Salicylic Acids and Overbased Detergents Derived Therefrom
Alkyl salicylic acids, overbased detergents derived from alkyl salicylic acids, lubricating compositions including the alkyl salicylic acids and/or overbased detergents, and processes of making and using the same, are described.
Processes for Producing Alkyl Salicylic Acids and Overbased Detergents Derived Therefrom
Alkyl salicylic acids, overbased detergents derived from alkyl salicylic acids, lubricating compositions including the alkyl salicylic acids and/or overbased detergents, and processes of making and using the same, are described.
Metal organic frameworks and methods of making and using same
Metal Organic Framework (MOF) materials and methods of making MOF materials. The methods include grinding of mixtures of metal hydroxide(s) and ligand(s). The MOF materials may have at least two different ligands. The MOF materials may have open metal sites. The MOF materials can be used in gas storage applications.
Metal organic frameworks and methods of making and using same
Metal Organic Framework (MOF) materials and methods of making MOF materials. The methods include grinding of mixtures of metal hydroxide(s) and ligand(s). The MOF materials may have at least two different ligands. The MOF materials may have open metal sites. The MOF materials can be used in gas storage applications.
FATTY ACID CALCIUM SALT PARTICLES AND COSMETICS
The invention relates to particles of a calcium salt of a fatty acid having 12 to 22 carbon atoms, wherein the median size is 4.0 μm to 15.0 μm, the particle size digest A expressed by the following equation (1) satisfies the relation A≤2.0, and the average thickness is 350 to 800 nm.
Particle size digest A=(D90−D10)/D50 equation (1) (Here, 4.0≤D50≤15.0.) D10: the 10% cumulative size (μm) of the fatty acid calcium salt particles on a volumetric basis D50: the median size (μm) of the fatty acid calcium salt particles on a volumetric basis D90: the 90% cumulative size (μm) of the fatty acid calcium salt particles on a volumetric basis