Patent classifications
C07C51/48
METHOD FOR PRODUCING LEVULINIC ACID IN MOLTEN SALT HYDRATE FROM CELLULOSE HYDROLYSIS
The disclosure relates to a method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis. An inorganic molten salt hydrate was prepared by mixing an inorganic salt with water, cellulose is added and stirred to dissolve, a solid catalyst is added and heated up for reaction to obtain a reactant, the reactant is cooled and subjected to a separation to obtain the levulinic acid, and the inorganic molten salt hydrate and the solid catalyst obtained after the separation are recycled, wherein the inorganic salt is one or more selected from the group consisting of LiCl, LiBr, CaBr.sub.2, Ca(NO.sub.3).sub.2, LiNO.sub.3 and KNO.sub.3.
METHOD FOR PRODUCING LEVULINIC ACID IN MOLTEN SALT HYDRATE FROM CELLULOSE HYDROLYSIS
The disclosure relates to a method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis. An inorganic molten salt hydrate was prepared by mixing an inorganic salt with water, cellulose is added and stirred to dissolve, a solid catalyst is added and heated up for reaction to obtain a reactant, the reactant is cooled and subjected to a separation to obtain the levulinic acid, and the inorganic molten salt hydrate and the solid catalyst obtained after the separation are recycled, wherein the inorganic salt is one or more selected from the group consisting of LiCl, LiBr, CaBr.sub.2, Ca(NO.sub.3).sub.2, LiNO.sub.3 and KNO.sub.3.
EXTRACTION OF NATURAL FERULATE AND COUMARATE FROM BIOMASS
A process for a reactive separation of organic molecules from biomass includes a reaction step for the biomass, a simultaneous extraction step using a solvent, and a filtration step to recover products, wherein the products comprise ferulic acid and/or coumaric acid. The products are extracted from the biomass in a pressurized stirred batch reactor using a liquid extraction solvent and a base in which the ferulate and the coumarate remain.
EXTRACTION OF NATURAL FERULATE AND COUMARATE FROM BIOMASS
A process for a reactive separation of organic molecules from biomass includes a reaction step for the biomass, a simultaneous extraction step using a solvent, and a filtration step to recover products, wherein the products comprise ferulic acid and/or coumaric acid. The products are extracted from the biomass in a pressurized stirred batch reactor using a liquid extraction solvent and a base in which the ferulate and the coumarate remain.
EXTRACTION OF NATURAL FERULATE AND COUMARATE FROM BIOMASS
A process for a reactive separation of organic molecules from biomass includes a reaction step for the biomass, a simultaneous extraction step using a solvent, and a filtration step to recover products, wherein the products comprise ferulic acid and/or coumaric acid. The products are extracted from the biomass in a pressurized stirred batch reactor using a liquid extraction solvent and a base in which the ferulate and the coumarate remain.
Process for preparation of methacrylic acid and methacrylic acid esters
The invention relates to a process for preparation of at least one of methacrylic acid and a methacrylic acid ester, comprising the process stepsgas phase oxidation of at least one C.sub.4 compound, quenching of the reaction phase, separation and purification of the obtained methacrylic acid and optionally esterification, wherein the C.sub.4 compound is a methacrolein comprising mixture, originating from at least two different methacrolein sources, a first methacrolein source being a feed stream obtained by the heterogeneously catalyzed gas phase oxidation of isobutylene or tert-butyl alcohol or isobutylaldehyde or a mixture of two or more thereof, a second methacrolein source being a feed stream obtained by the reaction of propionaldehyde with a C.sub.1 extending agent, preferably formaldehyde, and where said methacrolein can be obtained either completely from the first methacrolein source, or completely from the second methacrolein source or from any mixture of both.
Process for preparation of methacrylic acid and methacrylic acid esters
The invention relates to a process for preparation of at least one of methacrylic acid and a methacrylic acid ester, comprising the process stepsgas phase oxidation of at least one C.sub.4 compound, quenching of the reaction phase, separation and purification of the obtained methacrylic acid and optionally esterification, wherein the C.sub.4 compound is a methacrolein comprising mixture, originating from at least two different methacrolein sources, a first methacrolein source being a feed stream obtained by the heterogeneously catalyzed gas phase oxidation of isobutylene or tert-butyl alcohol or isobutylaldehyde or a mixture of two or more thereof, a second methacrolein source being a feed stream obtained by the reaction of propionaldehyde with a C.sub.1 extending agent, preferably formaldehyde, and where said methacrolein can be obtained either completely from the first methacrolein source, or completely from the second methacrolein source or from any mixture of both.
Process for preparation of methacrylic acid and methacrylic acid esters
The invention relates to a process for preparation of at least one of methacrylic acid and a methacrylic acid ester, comprising the process stepsgas phase oxidation of at least one C.sub.4 compound, quenching of the reaction phase, separation and purification of the obtained methacrylic acid and optionally esterification, wherein the C.sub.4 compound is a methacrolein comprising mixture, originating from at least two different methacrolein sources, a first methacrolein source being a feed stream obtained by the heterogeneously catalyzed gas phase oxidation of isobutylene or tert-butyl alcohol or isobutylaldehyde or a mixture of two or more thereof, a second methacrolein source being a feed stream obtained by the reaction of propionaldehyde with a C.sub.1 extending agent, preferably formaldehyde, and where said methacrolein can be obtained either completely from the first methacrolein source, or completely from the second methacrolein source or from any mixture of both.
Process for equilibrium-limited reactions
A process for conducting equilibrium-limited chemical reactions that produce water as a reaction product. Specifically, a process that uses a reactive chromatography unit (RCU) to improve the efficiency of equilibrium-limited reactions, such as a process for reacting glycol ether (GE) and carboxylic acid (CA) to form water and glycol ether ester (GEE). The process includes supplying GE and CA to the RCU, where one of either the CA or the GE is in a stoichiometric deficit relative to the other reactant. The reactant in the stoichiometric deficit reacts in the presence of the catalyst in the RCU to form a mixture of GEE and water. A raffinate is separated from the mixture using the separation media of the RCU contains at least the GEE. An extract separated from the mixture using the separation media of the RCU contains at least the water.
Process for equilibrium-limited reactions
A process for conducting equilibrium-limited chemical reactions that produce water as a reaction product. Specifically, a process that uses a reactive chromatography unit (RCU) to improve the efficiency of equilibrium-limited reactions, such as a process for reacting glycol ether (GE) and carboxylic acid (CA) to form water and glycol ether ester (GEE). The process includes supplying GE and CA to the RCU, where one of either the CA or the GE is in a stoichiometric deficit relative to the other reactant. The reactant in the stoichiometric deficit reacts in the presence of the catalyst in the RCU to form a mixture of GEE and water. A raffinate is separated from the mixture using the separation media of the RCU contains at least the GEE. An extract separated from the mixture using the separation media of the RCU contains at least the water.