Patent classifications
C07C2603/54
METHOD OF PREPARING TRITERPENOID COMPOUND
A method of preparing a triterpenoid compound of formula (I):
##STR00001##
including a step of converting a compound of formula (II) into the compound of formula (I),
##STR00002##
wherein R.sub.1 and R.sub.2 independently represent hydrogen or a protecting group selected from the group consisting of C.sub.1-C.sub.8 alkyl, allyl, C.sub.2-C.sub.8 alkenyl, C2-C8 alkynyl, (C.sub.6-C.sub.12)aryl(C.sub.1-C.sub.8)alkyl, tri(C.sub.1-C.sub.8)alkylsilyl, di(C.sub.1-C.sub.8)alkyl(C.sub.6-C.sub.12)arylsilyl, di(C.sub.6-C.sub.12)aryl(C.sub.1-C.sub.8)alkylsilyl ,tri(C.sub.6-C.sub.12)arylsilyl, —C(O)R.sub.7, and —C(O)OR.sub.8, and each of which is substituted with from 0 to 4 substituents independently selected from the group consisting of hydroxy, cyano, halo, halo(C.sub.1-C.sub.6)alkyl, halo(C.sub.1-C.sub.6)alkyloxy, (C.sub.1-C.sub.6)alkylthio, C.sub.1-C.sub.6 alkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 alkynyl, C.sub.3-C.sub.7 cycloalkyl and C.sub.1-C.sub.6 alkoxy, wherein R.sub.7 and R.sub.8 are independently C.sub.1-C.sub.8 alkyl or C.sub.6-C.sub.12 aryl.
Organic electroluminescent devices
The present disclosure relates to display technologies, and particularly discloses an organic electroluminescent device. This organic electroluminescent device includes a light-emitting layer, the light-emitting includes an exciplex composed of a donor molecule and an acceptor molecule, and a wide band gap material for increasing the inter-molecular spacing between the donor molecule and the acceptor molecule. According to the device of the present disclosure, the degree of orbital overlap of HOMO and LUMO of the formed exciplex and the singlet-triplet energy level difference can be reduced, the reverse intersystem crossing rate (k.sub.RISC) of the exciplex host can be increased, the Föster energy transferred to the guest molecule can be enhanced, and the efficiency and the lifetime of the device can be improved.
Methods and systems for wireless to power line communications
Methods, systems, and apparatus for monitoring and controlling electronic devices using wired and wireless protocols are disclosed. The systems and apparatus may monitor their environment for signals from electronic devices. The systems and apparatus may take and disambiguate the signals that are received from the devices in their environment to identify the devices and associate control signals with the devices. The systems and apparatus may use communication means to send control signals to the identified electronic devices. Multiple apparatuses or systems may be connected together into networks, including mesh networks, to make for a more robust architecture.
COMPOSITION FOR FORMING ORGANIC FILM, PATTERNING PROCESS, AND COMPOUND
A composition for forming an organic film, including: a compound represented by the following general formula (1); and an organic solvent, wherein in the general formula (1), X represents any one group of X1 to X3 represented by the following general formulae (2), (3), and (5), and two or more kinds of X are optionally used in combination, wherein in the general formula (3), W represents a carbon atom or a nitrogen atom; “n1” represents 0 or 1; “n2” represents an integer of 1 to 3; and R.sub.1 independently represents any one of groups represented by the following general formula (4), and wherein in the general formula (5), R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and R.sub.3 represents any one of the following groups.
##STR00001## ##STR00002##
Phenanthrene compounds for organic electronic devices
The invention relates to specific phenanthrenes, the use of the compound in an electronic device, and an electronic device containing at least one of said compounds. The invention further relates to a method for producing the compound and a formulation and composition containing one or more of the compounds.
Hypocrellin derivative substituted both in a peri-position and in 2-position by amino, preparation method, and application thereof
The present invention discloses a hypocrellin derivative substituted both in a pen-position and in a 2-position by an amino, and a preparation method and use thereof. A general structural formula of the derivative is as represented by formulas I-a to I-d: ##STR00001## The hypocrellin derivative substituted both in a peri-position and in a 2-position by an amino prepared in the present invention has a maximum absorption wavelength of 600-650 nm and a molar extinction coefficient reaching about 20000-40000 M.sup.−1cm.sup.−1. Compared with unmodified hypocrellin or hypocrellin having only a 2-position modified, an absorption spectrum of the derivative is significantly red-shifted and the molar extinction coefficient is greatly improved, and the derivative can efficiently produce reactive oxygen species such as singlet oxygen in a photosensitive condition. In the same condition, the hypocrellin derivative substituted both in a pen-position and in a 2-position by an amino involved in the present invention, when used as a photosensitizer, has a stronger ability to photo-dynamically inactivate tumor cells than the first and second generation commercial photosensitizers.
ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE USING SAME
An organic electroluminescence device comprising: a cathode, an anode, and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a compound represented by the following formula (1), and a compound A having a Stokes shift of 20 nm or smaller and an emission peak wavelength of 440 nm to 465 nm (at least one of Ar.sub.1 and Ar.sub.2 is a monovalent group having a structure represented by the following formula (2)).
##STR00001##
NOVEL COMPOUND, ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME, AND ELECTRONIC APPARATUS
A compound represented by the following formula (1), wherein in the formula, L.sub.1 and L.sub.2 are predetermined linking groups, and Ar.sub.1 is a monovalent group having a structure represented by the following formula (2).
##STR00001##
Organic functional compounds, mixtures, formulations, organic functional thin films and preparation methods therefor and organic electronic devices
An organic functional compound, having a general formula of ASG).sub.p; wherein A is an organic group having an optoelectronic function; the structural formula of SG is selected from the group consisting of ##STR00001##
wherein ##STR00002##
is selected from the group consisting of an aryl containing 5-40 ring-forming atoms and a heteroaryl containing 5-40 ring-forming atoms; R1 and R2 are each independently selected from the group consisting of H, D, F, CN, an alkyl, an aromatic ring group, an aromatic heterocyclic group, an amino, a silyl, a germyl, an alkoxy, an aryloxy, and a siloxy group; and p is an integer greater than or equal to 1.
ARYL COMPOUNDS AND POLYMERS AND METHODS OF MAKING AND USING THE SAME
Disclosed herein are embodiments of aryl compounds and polymers thereof that are made using methods that do not require harsh conditions or expensive reagents. The methods disclosed herein utilize precursor compounds that can be polymerized to form polycyclic aromatic hydrocarbons and polymers, such as carbon-based polymers like nanostructures (e.g., graphene or graphene-like nanoribbons).