A method for producing a polymer containing metal atoms or halogen atoms at the terminals thereof with excellent efficiency while minimizing or eliminating side reactions or the like is provided. The method can also freely control molecular weight characteristics of the polymer.

In general, the invention relates to a process for reducing the content of halogenated organic compounds or complexes with radionuclides in a liquid. The invention further relates to a water treatment plant and the use of a plurality of bodies for treating water and aqueous radioactive waste. The invention relates to a treatment process for preparing a treated liquid, the treatment process comprising the following treatment steps: a. providing a source liquid, the source liquid comprising: i. water at a content of at least 70 wt. %, and ii. one or more X-constituents at a total content of at least 10.sup.?10 wt. %, each X-constituent being a halogenated organic compound having 2 or more halogen atoms per molecular unit, or each X-constituent being a complex ion comprising at least one radionuclide; b. providing a plurality of solid M-bodies, each M-body comprising: i. an R-body of one or more R-constituents at a dry weight total content of at least 80 wt. %, each R-constituent being a polymer, ii. first and optionally further N-constituents adjacent to the R-body at a total dry weight content in the range from 0.1 to 10 wt. %, each N-constituent comprising an N atom present as an amine or an ammonium; iii. optionally water at a content of up to 90 wt. %, based on the total weight of the M-body; c. contacting the source liquid with the plurality of M-bodies to obtain the treated liquid, the treated liquid having a lower total content of X-constituents than the source liquid, wherein at least the first N-constituents have one or more L-chains connected to the N atom, each L-chain having a C chain of length 4 or less.

In general, the invention relates to a process for reducing the content of halogenated organic compounds or complexes with radionuclides in a liquid. The invention further relates to a water treatment plant and the use of a plurality of bodies for treating water and aqueous radioactive waste. The invention relates to a treatment process for preparing a treated liquid, the treatment process comprising the following treatment steps: a. providing a source liquid, the source liquid comprising: i. water at a content of at least 70 wt. %, and ii. one or more X-constituents at a total content of at least 10.sup.?10 wt. %, each X-constituent being a halogenated organic compound having 2 or more halogen atoms per molecular unit, or each X-constituent being a complex ion comprising at least one radionuclide; b. providing a plurality of solid M-bodies, each M-body comprising: i. an R-body of one or more R-constituents at a dry weight total content of at least 80 wt. %, each R-constituent being a polymer, ii. first and optionally further N-constituents adjacent to the R-body at a total dry weight content in the range from 0.1 to 10 wt. %, each N-constituent comprising an N atom present as an amine or an ammonium; iii. optionally water at a content of up to 90 wt. %, based on the total weight of the M-body; c. contacting the source liquid with the plurality of M-bodies to obtain the treated liquid, the treated liquid having a lower total content of X-constituents than the source liquid, wherein at least the first N-constituents have one or more L-chains connected to the N atom, each L-chain having a C chain of length 4 or less.

In general, the invention relates to a process for reducing the content of halogenated organic compounds or complexes with radionuclides in a liquid. The invention further relates to a water treatment plant and the use of a plurality of bodies for treating water and aqueous radioactive waste. The invention relates to a treatment process for preparing a treated liquid, the treatment process comprising the following treatment steps: a. providing a source liquid, the source liquid comprising: i. water at a content of at least 70 wt. %, and ii. one or more X-constituents at a total content of at least 10-10 wt. %, each X-constituent being a halogenated organic compound having 2 or more halogen atoms per molecular unit, or each X-constituent being a complex ion comprising at least one radionuclide; b. providing a plurality of solid M-bodies, each M-body comprising: i. an R-body of one or more R-constituents at a dry weight total content of at least 80 wt. %, each R-constituent being a polymer, ii. first and optionally further N-constituents adjacent to the R-body at a total dry weight content in the range from 0.1 to 10 wt. %, each N-constituent comprising an N atom present as an amine or an ammonium; iii. optionally water at a content of up to 90 wt. %, based on the total weight of the M-body; c. contacting the source liquid with the plurality of M-bodies to obtain the treated liquid, the treated liquid having a lower total content of X-constituents than the source liquid, wherein at least the first N-constituents have one or more L-chains connected to the N atom, each L-chain having a C chain of length 5 or more.

Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) ##STR00001## wherein Z is nitrogen or phosphorous; R.sup.1 is hydrogen or alkyl; R.sup.2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A.sup.1-NR.sup.a).sub.xR.sup.b; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A.sup.1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and R.sup.a and R.sup.b, each independently, is hydrogen or alkyl;
or a corresponding onium salt.

Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) ##STR00001## wherein Z is nitrogen or phosphorous; R.sup.1 is hydrogen or alkyl; R.sup.2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A.sup.1-NR.sup.a).sub.xR.sup.b; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A.sup.1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and R.sup.a and R.sup.b, each independently, is hydrogen or alkyl;
or a corresponding onium salt.

Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) ##STR00001## wherein Z is nitrogen or phosphorous; R.sup.1 is hydrogen or alkyl; R.sup.2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A.sup.1-NR.sup.a).sub.xR.sup.b; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A.sup.1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and R.sup.a and R.sup.b, each independently, is hydrogen or alkyl;
or a corresponding onium salt.

The present invention relates to an iminodiacetic acid chelating resin, wherein the water amount in the resin is from 50 to 75% and the volume ratio of Na form/H form is from 1.4 to 1.8. Furthermore, the present invention relates to a method for producing an iminodiacetic acid chelating resin, wherein an alcohol is used as a solvent for the amination reaction of a chloromethylated styrene crosslinked copolymer with iminodiacetonitrile or sodium iodide and/or potassium iodide is used as a catalyst for the amination reaction.

The present invention relates to an iminodiacetic acid chelating resin, wherein the water amount in the resin is from 50 to 75% and the volume ratio of Na form/H form is from 1.4 to 1.8. Furthermore, the present invention relates to a method for producing an iminodiacetic acid chelating resin, wherein an alcohol is used as a solvent for the amination reaction of a chloromethylated styrene crosslinked copolymer with iminodiacetonitrile or sodium iodide and/or potassium iodide is used as a catalyst for the amination reaction.

Provided is an ionomer resin including a copolymer containing the following first structural unit.

##STR00001##

L.sub.1 to L.sub.5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is Z.sub.2-M.sub.1-Z.sub.1(R.sub.1)(R.sub.2)(R.sub.3). R.sub.1 to R.sub.3 are directly bonded to Z.sub.1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M.sub.1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z.sub.1 is a nitrogen atom or a phosphorus atom, and Z.sub.2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L.sub.6 is a hydrogen atom, a methyl group, or an ethyl group.