Patent classifications
C08F26/10
Bismuth-titanium oxide nanowire material used for photocatalysis, and preparation method
The present invention relates to bismuth-titanium oxide composite nanowires used for photocatalysis and a preparation method, belonging to the field of inorganic nanomaterials. The preparation of the bismuth-titanium oxide composite nanowires is: polyvinylpyrrolidone (PVP) and bismuth nitrate are added to NN dimethylformamide (DMF), tetrabutyl titanate and acetylacetone are added after magnetic stirring has been performed for a period of time, continual stirring is performed for more than six hours, and a transparent, stable solution is obtained. Electrospinning is performed on the solution in an electrospinning generation device under certain conditions, and the obtained electrospinning precursor nano fibers are air-fired in a muffle furnace to remove organic matter. After being cooled to room temperature, the electrospinning precursor nano fibers are placed in a tube furnace to be reduced and sintered in a hydrogen atmosphere. The method is energy-saving and environmentally friendly, the conditions are easy to control, costs are low, and large-scale industrial production is easy. The obtained bismuth-titanium oxide nanowires exhibit good degradation activity on methyl orange under illumination, where the methyl orange degradation rate is reaching more than 95% in a reaction lasting for 20 minutes. The obtained bismuth-titanium oxide nanowires have wide application prospects in relation to sewage treatment.
Metal particle dispersion for electroconductive substrates, method for producing the same, and method for producing an electroconductive substrate
The present invention is to provide a metal particle dispersion for electroconductive substrates, which has high dispersibility and dispersion stability and which is able to form a film that shows high electroconductivity after baking. Disclosed is a metal particle dispersion for electroconductive substrates, comprising metal particles, a dispersant and a solvent, wherein the dispersant is a graft copolymer having at least a constitutional unit represented by the following chemical formula (I) and a constitutional unit represented by the following chemical formula (II): ##STR00001##
(Symbols in the formulae are as described in the Description.)
Metal particle dispersion for electroconductive substrates, method for producing the same, and method for producing an electroconductive substrate
The present invention is to provide a metal particle dispersion for electroconductive substrates, which has high dispersibility and dispersion stability and which is able to form a film that shows high electroconductivity after baking. Disclosed is a metal particle dispersion for electroconductive substrates, comprising metal particles, a dispersant and a solvent, wherein the dispersant is a graft copolymer having at least a constitutional unit represented by the following chemical formula (I) and a constitutional unit represented by the following chemical formula (II): ##STR00001##
(Symbols in the formulae are as described in the Description.)
LIGHT-ASSISTED PHOTOCATALYST REGENERATION AND OXYGEN-RESILIENT RADICAL POLYMERIZATION
A photocatalyst can be regenerated with increasing efficiency, turnover number and turnover frequency in the presence of air by irradiating the photocatalyst with a first range of wavelengths of light that excite the photocatalyst to an intermediate and irradiating the intermediate with a second range of wavelengths of light that turns the intermediate to the photocatalyst.
Dispersant, metal particle dispersion for electroconductive substrates, and method for producing electroconductive substrate
The present invention is to provide a dispersant which has excellent dispersibility and which is able to inhibit the oxidation of dispersed particles. Disclosed is a dispersant comprising a graft copolymer having a constitutional unit represented by the following general formula (I) and a constitutional unit represented by the following general formula (II): ##STR00001##
(Symbols shown in the general formulae (I) and (II) are as described in the Description.)
Dispersant, metal particle dispersion for electroconductive substrates, and method for producing electroconductive substrate
The present invention is to provide a dispersant which has excellent dispersibility and which is able to inhibit the oxidation of dispersed particles. Disclosed is a dispersant comprising a graft copolymer having a constitutional unit represented by the following general formula (I) and a constitutional unit represented by the following general formula (II): ##STR00001##
(Symbols shown in the general formulae (I) and (II) are as described in the Description.)
POLYMERIZABLE POLYDIMETHYLSILOXANE-POLYOXYALKYLENE BLOCK COPOLYMERS
The invention provides a polymerizable polydimethylsiloxane-polyoxyalkylene block copolymer which comprises (1) a linear polymer chain comprising at least two polydimethylsiloxane segments, one hydrophilic polyoxyalkylene segment between each pair of polydimethylsiloxane segments, and one amide-rich linker between each pair of one polydimethylsiloxane segment and one hydrophilic polyoxyalkylene segment, and (2) two terminal (meth)acryloyl groups. The hydrophilized polydiorganosiloxane vinylic crosslinker has a weight average molecular weight of at least 3000 Daltons. The invention is also related to a silicone hydrogel contact lens produced from a polymerizable polydimethylsiloxane-polyoxyalkylene block copolymer of the invention.
POLYMERIZABLE POLYDIMETHYLSILOXANE-POLYOXYALKYLENE BLOCK COPOLYMERS
The invention provides a polymerizable polydimethylsiloxane-polyoxyalkylene block copolymer which comprises (1) a linear polymer chain comprising at least two polydimethylsiloxane segments, one hydrophilic polyoxyalkylene segment between each pair of polydimethylsiloxane segments, and one amide-rich linker between each pair of one polydimethylsiloxane segment and one hydrophilic polyoxyalkylene segment, and (2) two terminal (meth)acryloyl groups. The hydrophilized polydiorganosiloxane vinylic crosslinker has a weight average molecular weight of at least 3000 Daltons. The invention is also related to a silicone hydrogel contact lens produced from a polymerizable polydimethylsiloxane-polyoxyalkylene block copolymer of the invention.
Carbon material-polymer strain sensitive film and its preparation method
A carbon material-polymer strain sensitive film and its preparation method are disclosed. The carbon material-polymer strain sensitive film includes multiple layers of carbon sensitive films and multiple layers of polymer films, wherein the multiple layers of carbon sensitive films and the multiple layers of polymer films form a multi-layer composite film in sequence through a layer-by-layer assembly process. The preparation method includes steps of: cleaning, processing a hydrophilic treatment and processing a hydrophobic treatment on a rigid substrate in sequence; preparing a carbon material in dispersion solution and a polymer dispersion solution; through a layer-by-layer self-assembly process, growing the polymer and the carbon material in a form of layer-by-layer on the rigid substrate; transferring the composite film from the rigid substrate to a flexible substrate; and pasting two electrodes at two ends of the composite film and encapsulating with a flexible film.
Carbon material-polymer strain sensitive film and its preparation method
A carbon material-polymer strain sensitive film and its preparation method are disclosed. The carbon material-polymer strain sensitive film includes multiple layers of carbon sensitive films and multiple layers of polymer films, wherein the multiple layers of carbon sensitive films and the multiple layers of polymer films form a multi-layer composite film in sequence through a layer-by-layer assembly process. The preparation method includes steps of: cleaning, processing a hydrophilic treatment and processing a hydrophobic treatment on a rigid substrate in sequence; preparing a carbon material in dispersion solution and a polymer dispersion solution; through a layer-by-layer self-assembly process, growing the polymer and the carbon material in a form of layer-by-layer on the rigid substrate; transferring the composite film from the rigid substrate to a flexible substrate; and pasting two electrodes at two ends of the composite film and encapsulating with a flexible film.