Patent classifications
C08F116/14
Method for producing acid-decomposable polymer
[Problem to be Solved] To Provide a method for producing an acid-decomposable polymer having a reduced metal ion content, which suppresses decomposition and deprotection of the acid-decomposable polymer. [Means to Solve the Problem] The method for producing an acid-decomposable polymer according to the present invention comprises the steps of: preparing a polymer solution comprising an acid-decomposable polymer; washing an acidic cation exchanger with an organic solvent until the water content in the organic solvent discharged from the acidic cation exchanger falls to 400 ppm or less; and passing the polymer solution through the washed acidic cation exchanger to reduce the metal ion content of the polymer.
Method for producing acid-decomposable polymer
[Problem to be Solved] To Provide a method for producing an acid-decomposable polymer having a reduced metal ion content, which suppresses decomposition and deprotection of the acid-decomposable polymer. [Means to Solve the Problem] The method for producing an acid-decomposable polymer according to the present invention comprises the steps of: preparing a polymer solution comprising an acid-decomposable polymer; washing an acidic cation exchanger with an organic solvent until the water content in the organic solvent discharged from the acidic cation exchanger falls to 400 ppm or less; and passing the polymer solution through the washed acidic cation exchanger to reduce the metal ion content of the polymer.
METHOD FOR MANUFACTURING PERFLUOROELASTOMER AQUEOUS DISPERSION, COMPOSITION, CROSSLINKABLE COMPOSITION, AND CROSSLINKED PRODUCT
The present disclosure provides a method for producing a perfluoroelastomer aqueous dispersion by polymerizing a perfluoromonomer in the presence of a polymer (1) and an aqueous medium to produce an aqueous dispersion of a perfluoroelastomer, the polymer (1) containing a polymerization unit (1) based on a monomer (1) represented by a general formula (1) and the polymer (1) having an ion exchange capacity of 1.50 meq/g or more.
METHOD FOR MANUFACTURING PERFLUOROELASTOMER AQUEOUS DISPERSION, COMPOSITION, CROSSLINKABLE COMPOSITION, AND CROSSLINKED PRODUCT
The present disclosure provides a method for producing a perfluoroelastomer aqueous dispersion by polymerizing a perfluoromonomer in the presence of a polymer (1) and an aqueous medium to produce an aqueous dispersion of a perfluoroelastomer, the polymer (1) containing a polymerization unit (1) based on a monomer (1) represented by a general formula (1) and the polymer (1) having an ion exchange capacity of 1.50 meq/g or more.
Method for manufacturing fluoropolymer
A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX.sub.2═CY(—CZ.sub.2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C—C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO.sub.3M, or —OSO.sub.3M, wherein M is —H, a metal atom, —NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.
Chloride-free cationic polymers using acetate anions
A composition contains ethylenically unsaturated quaternary ammonium cations with acetate counterions, where each of the ethylenically unsaturated ammonium cations contain only one non-aromatic carbon-carbon double bond and the composition contains less than one mole-percent chloride relative to quaternary ammonium cations can be polymerized to form a cationic polymer acetate.
Chloride-free cationic polymers using acetate anions
A composition contains ethylenically unsaturated quaternary ammonium cations with acetate counterions, where each of the ethylenically unsaturated ammonium cations contain only one non-aromatic carbon-carbon double bond and the composition contains less than one mole-percent chloride relative to quaternary ammonium cations can be polymerized to form a cationic polymer acetate.
PRODUCTION METHOD OF MODIFIED POLYTETRAFLUOROETHYLENE AND COMPOSITION
A method for producing modified polytetrafluoroethylene including: polymerizing tetrafluoroethylene and a modifying monomer in an aqueous medium in the presence of a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I) to obtain a modified polytetrafluoroethylene:
CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m (I)
wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more. Also disclosed is a composition containing the modified polytetrafluoroethylene and the polymer (I).
METHOD FOR PRODUCING FLUORINE-CONTAINING ELASTOMER AQUEOUS DISPERSION, AND COMPOSITION
Provided is a method for producing an aqueous dispersion of a fluorine-containing elastomer, comprising polymerizing a fluorine-containing monomer in the presence of a polymer (1) containing a polymerization unit (1) based on a monomer (1) represented by general formula (1) and an aqueous medium,
CF.sub.2═CF—R—CZ.sup.1Z.sup.2—COOM (1)
wherein R is a linking group, Z.sup.1 and Z.sup.2 are each independently F or CF.sub.3, and M is H, a metal atom, NR.sup.7.sub.4, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R.sup.7 is H or an organic group.
METHOD FOR PRODUCING AQUEOUS FLUOROPOLYMER DISPERSION, DRAINAGE TREATMENT METHOD, AND AQUEOUS FLUOROPOLYMER DISPERSION
A method for producing a fluoropolymer aqueous dispersion, including a step A of performing ultrafiltration, microfiltration, or dialysis membrane treatment, or a combination thereof on a pretreatment aqueous dispersion containing a fluoropolymer obtained by polymerization in the presence of a polymer (I) including a polymerized unit (I) derived from a monomer represented by the following general formula (I), with the proviso that the fluoropolymer is other than the polymer (I):
CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m (I)
wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.