C08F210/06

ETHYLENE/alpha-OLEFIN COPOLYMER COMPOSITION AND APPLICATION THEREOF
20220411659 · 2022-12-29 · ·

An object of the present invention is to obtain a composition having, for example, improved anti-sagging properties, pigment dispersibility, and crack resistance, and the present invention relates to an ethylene/α-olefin copolymer composition including: an ethylene/α-olefin copolymer (A) satisfying requirements (a-1) to (a-3) described below; one or more selected from a color material (D), a resin (E) and an oil (F); and a solvent (C), (a-1) a methyl group index measured by .sup.1H-NMR is in a range of 40 to 60%, (a-2) a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) is in a range of 3,000 to 30,000, (a-3) no melting peak is observed at temperatures ranging from −100° C. to 150° C. in differential scanning calorimetry (DSC).

ETHYLENE/alpha-OLEFIN COPOLYMER COMPOSITION AND APPLICATION THEREOF
20220411659 · 2022-12-29 · ·

An object of the present invention is to obtain a composition having, for example, improved anti-sagging properties, pigment dispersibility, and crack resistance, and the present invention relates to an ethylene/α-olefin copolymer composition including: an ethylene/α-olefin copolymer (A) satisfying requirements (a-1) to (a-3) described below; one or more selected from a color material (D), a resin (E) and an oil (F); and a solvent (C), (a-1) a methyl group index measured by .sup.1H-NMR is in a range of 40 to 60%, (a-2) a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) is in a range of 3,000 to 30,000, (a-3) no melting peak is observed at temperatures ranging from −100° C. to 150° C. in differential scanning calorimetry (DSC).

SEMI-AROMATIC POLYAMIDE RESIN COMPOSITION AND METAL-PLATED MOLDED BODY
20220411581 · 2022-12-29 · ·

To provide a semi-aromatic polyamide resin composition having excellent good plating properties, low water absorption properties, and solder reflow resistance. A semi-aromatic polyamide resin composition of the present invention comprises: 10 to 200 parts by mass of an inorganic filler (B) and 2 to 30 parts by mass of a toughness improver (C) based on 100 parts by mass of a semi-aromatic polyamide (A), wherein the semi-aromatic polyamide resin (A) satisfies the following (a) and (b): (a) a melting point (Tm) measured by differential scanning calorimetry (DSC) is 280° C. or higher; and (b) an equilibrium water absorption rate at 80° C. and 95% RH is 3.5% or less.

SEMI-AROMATIC POLYAMIDE RESIN COMPOSITION AND METAL-PLATED MOLDED BODY
20220411581 · 2022-12-29 · ·

To provide a semi-aromatic polyamide resin composition having excellent good plating properties, low water absorption properties, and solder reflow resistance. A semi-aromatic polyamide resin composition of the present invention comprises: 10 to 200 parts by mass of an inorganic filler (B) and 2 to 30 parts by mass of a toughness improver (C) based on 100 parts by mass of a semi-aromatic polyamide (A), wherein the semi-aromatic polyamide resin (A) satisfies the following (a) and (b): (a) a melting point (Tm) measured by differential scanning calorimetry (DSC) is 280° C. or higher; and (b) an equilibrium water absorption rate at 80° C. and 95% RH is 3.5% or less.

PROPYLENE PRELIMINARY POLYMERIZATION

A process for propylene preliminary polymerization in liquid phase that occurs in a continuous preliminary polymerization reactor may include feeding a propylene monomer and a Ziegler-Natta catalyst system having (a) a pro-catalyst having an internal electron donor comprising a substituted phenylene aromatic diester, (b) a catalyst activator and optionally (c) an external donor, into the continuous preliminary polymerization reactor, wherein the feeding is carried out without pre-contact of the pro-catalyst with the catalyst activator, and also without pre-contact of the catalyst activator with the propylene monomer before entering the continuous preliminary polymerization reactor.

PROPYLENE PRELIMINARY POLYMERIZATION

A process for propylene preliminary polymerization in liquid phase that occurs in a continuous preliminary polymerization reactor may include feeding a propylene monomer and a Ziegler-Natta catalyst system having (a) a pro-catalyst having an internal electron donor comprising a substituted phenylene aromatic diester, (b) a catalyst activator and optionally (c) an external donor, into the continuous preliminary polymerization reactor, wherein the feeding is carried out without pre-contact of the pro-catalyst with the catalyst activator, and also without pre-contact of the catalyst activator with the propylene monomer before entering the continuous preliminary polymerization reactor.

Propylene-based block copolymer, production method therefor, and solid titanium catalyst ingredient for olefin polymerization

The purpose of the present invention is to provide a propylene-based block copolymer, the deposition thereof on the inner wall of the polymerization vessel having been sufficiently inhibited. The propylene-based block copolymer of the present invention has a flowability evaluation value of 40% or less, the value being calculated with the following equation wherein X (sec) is the number of seconds over which 100 g of the copolymer having ordinary temperature falls from a stainless-steel funnel having an inner diameter of 11.9 mm and Y (sec) is the number of seconds over which 100 g of the copolymer which has been held at 80° C. for 24 hours under a load of 10 kg falls from the funnel having an inner diameter of 11.9 mm.
Flowability evaluation value (%)={(Y/X)−1}×100.

Propylene-based block copolymer, production method therefor, and solid titanium catalyst ingredient for olefin polymerization

The purpose of the present invention is to provide a propylene-based block copolymer, the deposition thereof on the inner wall of the polymerization vessel having been sufficiently inhibited. The propylene-based block copolymer of the present invention has a flowability evaluation value of 40% or less, the value being calculated with the following equation wherein X (sec) is the number of seconds over which 100 g of the copolymer having ordinary temperature falls from a stainless-steel funnel having an inner diameter of 11.9 mm and Y (sec) is the number of seconds over which 100 g of the copolymer which has been held at 80° C. for 24 hours under a load of 10 kg falls from the funnel having an inner diameter of 11.9 mm.
Flowability evaluation value (%)={(Y/X)−1}×100.

Propylene-based block copolymer, production method therefor, and solid titanium catalyst ingredient for olefin polymerization

The purpose of the present invention is to provide a propylene-based block copolymer, the deposition thereof on the inner wall of the polymerization vessel having been sufficiently inhibited. The propylene-based block copolymer of the present invention has a flowability evaluation value of 40% or less, the value being calculated with the following equation wherein X (sec) is the number of seconds over which 100 g of the copolymer having ordinary temperature falls from a stainless-steel funnel having an inner diameter of 11.9 mm and Y (sec) is the number of seconds over which 100 g of the copolymer which has been held at 80° C. for 24 hours under a load of 10 kg falls from the funnel having an inner diameter of 11.9 mm.
Flowability evaluation value (%)={(Y/X)−1}×100.

RESIN COMPOSITION AND MOLDED ARTICLE

An object of the present invention is to provide a resin composition and a molded article each having suppressed surface stickiness while having high stress-relaxing ability and vibration-absorbing ability at room temperature. A resin composition (X) containing 10 to 50 parts by mass of a thermoplastic resin (A) and 50 to 90 parts by mass of an inorganic substance (B), wherein a tan δ peak temperature and tan δ peak value, obtained by performing dynamic viscoelastic measurement at a frequency of 10 rad/s (1.6 Hz) in the temperature range of −40 to 150° C., are 0° C. or higher and 60° C. or lower, and 0.8 or more and 5.0 or less, respectively.