Monomers and polymers are provided that comprise a carbon alicyclic group or heteroalicyclic group that comprises 1) one or more acid-labile ring substituents and 2) one or more ether or thioether ring substituents. Photoresists that comprise such polymers also are provided.

Monomers and polymers are provided that comprise a carbon alicyclic group or heteroalicyclic group that comprises 1) one or more acid-labile ring substituents and 2) one or more ether or thioether ring substituents. Photoresists that comprise such polymers also are provided.

The present invention provides a resin composition for stereolithography that, with its low consistency, enables easy fabrication while ensuring good shape accuracy and desirable color masking properties in the cured product. The present invention relates to a resin composition for stereolithography comprising: an 80 to 99 mass % polymerizable monomer (a); a 0.1 to 10 mass % photopolymerization initiator (b); a 0.1 to 5.0 mass % inorganic particle (c) having an average particle diameter of 5 to 200 nm; and a 0.01 to 10 mass % metal oxide particle (d) having an average particle diameter of 0.1 to 10 μm, the inorganic particle (c) being different from the metal oxide particle (d).

The present invention provides a resin composition for stereolithography that, with its low consistency, enables easy fabrication while ensuring good shape accuracy and desirable color masking properties in the cured product. The present invention relates to a resin composition for stereolithography comprising: an 80 to 99 mass % polymerizable monomer (a); a 0.1 to 10 mass % photopolymerization initiator (b); a 0.1 to 5.0 mass % inorganic particle (c) having an average particle diameter of 5 to 200 nm; and a 0.01 to 10 mass % metal oxide particle (d) having an average particle diameter of 0.1 to 10 μm, the inorganic particle (c) being different from the metal oxide particle (d).

The present disclosure provides a printable composition. The printable composition includes a polymer, a polymerizable component, a temporary solvent, a photoinitiator, and optionally an inhibitor. The present disclosure also provides an article including an integral blend of a thermoset polymer and a second polymer different from the thermoset polymer. Further, the present disclosure provides a method of making an article. The method includes (i) providing a printable composition; (ii) selectively curing the printable composition to form a gelled article; and (iii) removing at least a portion of the temporary solvent from the gelled article. The method may optionally include (iv) curing unpolymerized polymerizable component remaining before or after step (iii). Also, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying a plurality of layers of an article, the article including: an integral blend of 8 to 50 wt. %, inclusive, of a thermoset polymer and 30 to 90 wt. %, inclusive, of a second polymer different from the thermoset polymer, wherein the weight percent is based on the total weight of the article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure provides a printable composition. The printable composition includes a polymer, a polymerizable component, a temporary solvent, a photoinitiator, and optionally an inhibitor. The present disclosure also provides an article including an integral blend of a thermoset polymer and a second polymer different from the thermoset polymer. Further, the present disclosure provides a method of making an article. The method includes (i) providing a printable composition; (ii) selectively curing the printable composition to form a gelled article; and (iii) removing at least a portion of the temporary solvent from the gelled article. The method may optionally include (iv) curing unpolymerized polymerizable component remaining before or after step (iii). Also, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying a plurality of layers of an article, the article including: an integral blend of 8 to 50 wt. %, inclusive, of a thermoset polymer and 30 to 90 wt. %, inclusive, of a second polymer different from the thermoset polymer, wherein the weight percent is based on the total weight of the article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

The present disclosure provides a laminate having low air permeability and excellent moisture permeability, a partition member for total heat exchange element composed of the laminate, a total heat exchange element provided with a plurality of the partition members for total heat exchange element, and a ventilation device provided with the total heat exchange element. The laminate of the present disclosure is provided with a porous substrate and a moisture-permeable membrane disposed on one side of the porous substrate, the moisture-permeable membrane being provided with a porous substrate and a moisture-permeable membrane disposed on at least one side of the porous substrate, and the moisture-permeable membrane being formed of a thermoplastic copolymer having a side chain containing a hydrophilic group which is a functional group.

The present disclosure provides a laminate having low air permeability and excellent moisture permeability, a partition member for total heat exchange element composed of the laminate, a total heat exchange element provided with a plurality of the partition members for total heat exchange element, and a ventilation device provided with the total heat exchange element. The laminate of the present disclosure is provided with a porous substrate and a moisture-permeable membrane disposed on one side of the porous substrate, the moisture-permeable membrane being provided with a porous substrate and a moisture-permeable membrane disposed on at least one side of the porous substrate, and the moisture-permeable membrane being formed of a thermoplastic copolymer having a side chain containing a hydrophilic group which is a functional group.

To provide a curable composition for imprinting whereby a cured product layer for a replica mold, which is excellent in the adhesion to a mold substrate and the release property from a cured product of a transfer object material when used in an imprinting method is formed; a replica mold for imprinting, using the curable composition for imprinting; its production process and a process for producing an article having a fine pattern on its surface by using the replica mold. A curable composition for imprinting, which comprises a fluorinated polymer comprising structural units (a) based on CH.sub.2═C(R.sup.1)C(O)OR.sup.2R.sup.f (R.sup.1: a hydrogen atom, a methyl group or the like, R.sup.2: a bivalent linking group having no fluorine atom and R.sup.f: a C.sub.2-6 fluoroalkyl group or the like) and structural units (b) having a cationic polymerizable reactive group having an oxygen atom, and a photo-acid generator, wherein the proportion of the fluorinated polymer is from 11 to 89 mass % in 100 mass % of the curable composition for imprinting.

To provide a curable composition for imprinting whereby a cured product layer for a replica mold, which is excellent in the adhesion to a mold substrate and the release property from a cured product of a transfer object material when used in an imprinting method is formed; a replica mold for imprinting, using the curable composition for imprinting; its production process and a process for producing an article having a fine pattern on its surface by using the replica mold. A curable composition for imprinting, which comprises a fluorinated polymer comprising structural units (a) based on CH.sub.2═C(R.sup.1)C(O)OR.sup.2R.sup.f (R.sup.1: a hydrogen atom, a methyl group or the like, R.sup.2: a bivalent linking group having no fluorine atom and R.sup.f: a C.sub.2-6 fluoroalkyl group or the like) and structural units (b) having a cationic polymerizable reactive group having an oxygen atom, and a photo-acid generator, wherein the proportion of the fluorinated polymer is from 11 to 89 mass % in 100 mass % of the curable composition for imprinting.