A quantum dot film article includes a first barrier layer; a second barrier layer; and a quantum dot layer between the first barrier layer and the second barrier layer. The quantum dot layer includes quantum dots dispersed in a matrix including a cured radiation curable adhesive composition with external quantum efficiency of greater than about 70%. The radiation curable adhesive composition includes about 30 wt % to about 99 wt %, based on the total weight of the radiation curable adhesive composition, of a multifunctional monomer, multifunction oligomer, or mixture thereof, wherein the multifunctional monomer includes (meth)acryl functional groups on a backbone.

A quantum dot film article includes a first barrier layer; a second barrier layer; and a quantum dot layer between the first barrier layer and the second barrier layer. The quantum dot layer includes quantum dots dispersed in a matrix including a cured radiation curable adhesive composition with external quantum efficiency of greater than about 70%. The radiation curable adhesive composition includes about 30 wt % to about 99 wt %, based on the total weight of the radiation curable adhesive composition, of a multifunctional monomer, multifunction oligomer, or mixture thereof, wherein the multifunctional monomer includes (meth)acryl functional groups on a backbone.

Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.

Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.

The present invention provides a three-dimensional printing article for making dental products and the preparation method thereof, which comprises: Ethoxylated bisphenol A dimethacrylate, Diurethane dimethacrylate, Triethylene glycol dimethacrylate, and Diphenyl (2,4,6-trimethylbenzoyl) phosphine oxide. It not only improves the present time-consuming and labor-intensive dental device making, but also can be used in mass production of dental devices.

The present invention provides a three-dimensional printing article for making dental products and the preparation method thereof, which comprises: Ethoxylated bisphenol A dimethacrylate, Diurethane dimethacrylate, Triethylene glycol dimethacrylate, and Diphenyl (2,4,6-trimethylbenzoyl) phosphine oxide. It not only improves the present time-consuming and labor-intensive dental device making, but also can be used in mass production of dental devices.

A preparation method of itaconate-butadiene bio-based engineering rubber belongs to the bio-based engineering rubber area. The bio-based engineering rubber of the present disclosure is formed through chemical crosslinking of copolymers, which are formed by polymerization of itaconate and butadiene emulsion. The number average molecular weight of the itaconate-butadiene copolymer is about 53000-1640000, and weight-average molecular weight is about 110000-2892000. Itaconate-butadiene copolymers are formed by polymerization of itaconate and butadiene emulsion, then and chemical crosslinking of the copolymer is performed to form bio-based engineering rubber using a traditional sulfur vulcanizing system. The bio-based engineering rubber of the present disclosure has high molecular weights as well as lower glass-transition temperatures and can be vulcanized using the traditional sulfur vulcanizing system. The bio-based engineering rubber of the present disclosure has same physic-mechanical property as well as processability as compared to rubber prepared using conventional techniques and may be used for manufacturing tire treads and conveyor belts.

A preparation method of itaconate-butadiene bio-based engineering rubber belongs to the bio-based engineering rubber area. The bio-based engineering rubber of the present disclosure is formed through chemical crosslinking of copolymers, which are formed by polymerization of itaconate and butadiene emulsion. The number average molecular weight of the itaconate-butadiene copolymer is about 53000-1640000, and weight-average molecular weight is about 110000-2892000. Itaconate-butadiene copolymers are formed by polymerization of itaconate and butadiene emulsion, then and chemical crosslinking of the copolymer is performed to form bio-based engineering rubber using a traditional sulfur vulcanizing system. The bio-based engineering rubber of the present disclosure has high molecular weights as well as lower glass-transition temperatures and can be vulcanized using the traditional sulfur vulcanizing system. The bio-based engineering rubber of the present disclosure has same physic-mechanical property as well as processability as compared to rubber prepared using conventional techniques and may be used for manufacturing tire treads and conveyor belts.

A liquid radiation curable composition comprising component a) 20 to 60 weight percent of one or more reactive oligomer(s) containing at least two urethane and/or urea linkages in the backbone and at least two ethylenic unsaturated group(s) which can form polymeric crosslink networks with the other components in the composition in the presence of radicals, anions, nucleophiles or combinations thereof, with a weight average molecular weight (M.sub.w) of greater than 3000 g/mol and glass transition temperature T.sub.g of the cured reactive oligomer(s) itself is greater than 25 C., component b) 20 to 60 weight percent of one or more reactive oligomer(s) containing at least two urethane and/or urea linkages in the backbone and at least two ethylenic unsaturated group(s) which can form multiple polymeric crosslink networks with the other components in the composition in the presence of radicals, anions, nucleophiles or combinations thereof and with component b) having a weight average molecular weight (M.sub.w) average of 1000 g/mol or less and a glass transition temperature T.sub.g of the cured reactive oligomer(s) is greater than 130 C., component c) 20 to 60 weight percent of one or more reactive monomer(s) containing at least one ethylenic unsaturated group capable of forming polymeric crosslinked networks with the other components in the composition in the presence of radicals, anions, nucleophiles or combinations thereof, the said reactive monomer(s) having at least one polar group and the glass transition temperature T.sub.g of the cured monomer(s) is greater than 50 C., component d) 0.01 to 10 weight percent of one or more photoinitiator(s) capable of producing radicals when irradiated with actinic radiation, component e) 0.01 to 30 weight percent of one or more additive(s) selected from the group consisting of filler(s), pigment(s), dispersant(s), defoamer(s), antioxidant(s), light stabilizer(s), light absorber(s) or radical inhibitor(s), with the provision that the liquid radiation curable composition has a viscosity of no more than 10000 mPa.s at 25 C.

A liquid radiation curable composition comprising component a) 20 to 60 weight percent of one or more reactive oligomer(s) containing at least two urethane and/or urea linkages in the backbone and at least two ethylenic unsaturated group(s) which can form polymeric crosslink networks with the other components in the composition in the presence of radicals, anions, nucleophiles or combinations thereof, with a weight average molecular weight (M.sub.w) of greater than 3000 g/mol and glass transition temperature T.sub.g of the cured reactive oligomer(s) itself is greater than 25 C., component b) 20 to 60 weight percent of one or more reactive oligomer(s) containing at least two urethane and/or urea linkages in the backbone and at least two ethylenic unsaturated group(s) which can form multiple polymeric crosslink networks with the other components in the composition in the presence of radicals, anions, nucleophiles or combinations thereof and with component b) having a weight average molecular weight (M.sub.w) average of 1000 g/mol or less and a glass transition temperature T.sub.g of the cured reactive oligomer(s) is greater than 130 C., component c) 20 to 60 weight percent of one or more reactive monomer(s) containing at least one ethylenic unsaturated group capable of forming polymeric crosslinked networks with the other components in the composition in the presence of radicals, anions, nucleophiles or combinations thereof, the said reactive monomer(s) having at least one polar group and the glass transition temperature T.sub.g of the cured monomer(s) is greater than 50 C., component d) 0.01 to 10 weight percent of one or more photoinitiator(s) capable of producing radicals when irradiated with actinic radiation, component e) 0.01 to 30 weight percent of one or more additive(s) selected from the group consisting of filler(s), pigment(s), dispersant(s), defoamer(s), antioxidant(s), light stabilizer(s), light absorber(s) or radical inhibitor(s), with the provision that the liquid radiation curable composition has a viscosity of no more than 10000 mPa.s at 25 C.