Patent classifications
C08F255/04
THERMOPLASTIC COMPOSITION AND MOLDED ARTICLE THEREOF
A thermoplastic resin composition includes a rubber-reinforced styrenic thermoplastic resin (A1) in an amount of 97 to 80 parts by mass); and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and primarily including structural units derived from butadiene. The structural units in the block portion (I) and the structural units derived from an aromatic vinyl-based compound in the random portion (II) are present in 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan δ at 0° C. or greater.
Thermoplastic composition and molded article thereof
A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan δ at 0° C. or greater.
Thermoplastic composition and molded article thereof
A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan δ at 0° C. or greater.
Polyolefin based compositions modified by silanes
A thermoplastic polyolefin composition which is capable of being shaped and repeatedly recycled, comprises propylene-based polymers, said composition being modified with 0.01-5 wt % of organic oligomeric silanes selected from partially hydrolyzed alkoxy substituted vinyl, allyl or methacryl silanes, and blends thereof, and 0.0005-0.5 wt % of a compound capable of generating free radicals.
Polyolefin based compositions modified by silanes
A thermoplastic polyolefin composition which is capable of being shaped and repeatedly recycled, comprises propylene-based polymers, said composition being modified with 0.01-5 wt % of organic oligomeric silanes selected from partially hydrolyzed alkoxy substituted vinyl, allyl or methacryl silanes, and blends thereof, and 0.0005-0.5 wt % of a compound capable of generating free radicals.
DISPERSION COMPOSITION
An alcohol-based composition may contain an acryl-modified polyolefin resin and exhibit a good adhesion even at a high solid content, suppress an increase in viscosity, and have good stability such as dispersibility and sustainable stability. A dispersion composition may contain at least a modified polyolefin resin dispersed in a dispersing medium containing an alcohol solvent and an aliphatic hydrocarbon solvent. The modified polyolefin resin may be modified with a (meth)acrylic acid component containing at least a (meth)acrylic ester of formula (I) and a (meth)acrylic ester of formula (II). The total content of the structure derived from the (meth)acrylic acid component in the dispersion composition is 3% to 94% by weight, relative to 100% by weight as a total amount of the modified polyolefin resin and (meth)acrylic acid component polymer, and a solid fraction in the dispersion composition is 30% to 80% by weight.
DISPERSION COMPOSITION
An alcohol-based composition may contain an acryl-modified polyolefin resin and exhibit a good adhesion even at a high solid content, suppress an increase in viscosity, and have good stability such as dispersibility and sustainable stability. A dispersion composition may contain at least a modified polyolefin resin dispersed in a dispersing medium containing an alcohol solvent and an aliphatic hydrocarbon solvent. The modified polyolefin resin may be modified with a (meth)acrylic acid component containing at least a (meth)acrylic ester of formula (I) and a (meth)acrylic ester of formula (II). The total content of the structure derived from the (meth)acrylic acid component in the dispersion composition is 3% to 94% by weight, relative to 100% by weight as a total amount of the modified polyolefin resin and (meth)acrylic acid component polymer, and a solid fraction in the dispersion composition is 30% to 80% by weight.
SILANE CROSSLINKABLE RUBBER COMPOSITION AND SILANE CROSSLINKED RUBBER MOLDED BODY, METHOD OF PRODUCING THE SAME, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE
A silane crosslinkable rubber composition having a silane crosslinkable rubber in which a silane coupling agent is grafted onto a base rubber containing 61 to 99 mass % of ethylene-α-olefin rubber and 1 to 39 mass % of polypropylene-based resin, and with respect to 100 parts by mass of the base rubber, 0.3 to 400 parts by mass of inorganic filler, and 0.0001 to 0.5 parts by mass of silanol condensation catalyst; a silane crosslinked rubber molded body obtained by bringing the rubber composition into contact with water after molding; a silane crosslinked rubber molded article including the rubber molded body; and a method of producing a silane crosslinkable rubber composition and a silane crosslinked rubber molded body.
SILANE CROSSLINKABLE RUBBER COMPOSITION AND SILANE CROSSLINKED RUBBER MOLDED BODY, METHOD OF PRODUCING THE SAME, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE
A silane crosslinkable rubber composition having a silane crosslinkable rubber in which a silane coupling agent is grafted onto a base rubber containing 61 to 99 mass % of ethylene-α-olefin rubber and 1 to 39 mass % of polypropylene-based resin, and with respect to 100 parts by mass of the base rubber, 0.3 to 400 parts by mass of inorganic filler, and 0.0001 to 0.5 parts by mass of silanol condensation catalyst; a silane crosslinked rubber molded body obtained by bringing the rubber composition into contact with water after molding; a silane crosslinked rubber molded article including the rubber molded body; and a method of producing a silane crosslinkable rubber composition and a silane crosslinked rubber molded body.
GRAFTING-MODIFIED POLYPROPYLENE MATERIAL AND PREPARATION METHOD THEREFOR
The invention belongs to the field of polymers, and relates to a grafting-modified polypropylene material for an insulating material and preparation method thereof. The grafting-modified polypropylene material comprises structural units derived from a polypropylene copolymer and structural units derived from an alkenyl-containing polymerizable monomer; the content of the structural units derived from the alkenyl-containing polymerizable monomer and in a grafted state in the grafting-modified polypropylene material is 0.1 to 14 wt %; the polypropylene copolymer has at least one of the following characteristics: the comonomer content is 0.5 to 40 mol %; the content of xylene solubles is 2 to 80 wt %; the comonomer content in the xylene solubles is 10 to 70 wt %; the intrinsic viscosity ratio of the xylene solubles to the polypropylene copolymer is 0.3 to 5. The grafting-modified polypropylene material of the invention can give consideration to both mechanical property and electrical property at a higher working temperature.