A method for producing antibacterial shock absorbing shoes is provided. The method includes the following steps of: designing a shoe tree and a shoe style, and selecting a material; attaching paper to an outside of the shoe tree to make a paper pattern; manufacturing a bottom pad, a middle pad and a foot pad, and punching a circular hole in the middle pad; soaking the leather pad with an antibacterial agent, punching semi-spherical protrusions and a connecting groove on the leather pad, forming a circular pinhole in a top end of the semi-spherical protrusion, pasting the leather pad on the middle pad with a glue and cutting the leather pad to manufacture a shock absorbing massage pad; wrapping the shoes, and shaping; and placing the shock absorbing massage pads and the foot pads into the shoes. The shoes manufactured have good breathability, shock absorbing property and antibacterial property.

A method for producing antibacterial shock absorbing shoes is provided. The method includes the following steps of: designing a shoe tree and a shoe style, and selecting a material; attaching paper to an outside of the shoe tree to make a paper pattern; manufacturing a bottom pad, a middle pad and a foot pad, and punching a circular hole in the middle pad; soaking the leather pad with an antibacterial agent, punching semi-spherical protrusions and a connecting groove on the leather pad, forming a circular pinhole in a top end of the semi-spherical protrusion, pasting the leather pad on the middle pad with a glue and cutting the leather pad to manufacture a shock absorbing massage pad; wrapping the shoes, and shaping; and placing the shock absorbing massage pads and the foot pads into the shoes. The shoes manufactured have good breathability, shock absorbing property and antibacterial property.

A grafted polyvinyl alcohol polymer has a balance between hydrophilicity and hydrophobicity. The grafted polyvinyl alcohol polymer has a chemical functionality that allows for adsorption onto the pulp fibers, polymer film formation upon drying, repelling water upon wetting, polymer film swelling and breaking for prolonged wetting by water. When incorporated into paper products, the polymer can provide a paper having improved wet strength, temporary water repellency, and/or is dispersible in aqueous solutions.

A grafted polyvinyl alcohol polymer has a balance between hydrophilicity and hydrophobicity. The grafted polyvinyl alcohol polymer has a chemical functionality that allows for adsorption onto the pulp fibers, polymer film formation upon drying, repelling water upon wetting, polymer film swelling and breaking for prolonged wetting by water. When incorporated into paper products, the polymer can provide a paper having improved wet strength, temporary water repellency, and/or is dispersible in aqueous solutions.

A composition with an excellent cycle capacity retention rate at high temperatures is provided.

According to the present invention, a composition comprising a graft copolymer, wherein the graft copolymer has a stem polymer and a plurality of branch polymers, the stem polymer has a polyvinyl alcohol structure, each of a first monomer unit and a second monomer unit is included in at least one of the plurality of branch polymers, the second monomer unit is different from the first monomer unit, a glass transition temperature of the composition is 260K to 365K is provided.

A composition with an excellent cycle capacity retention rate at high temperatures is provided.

According to the present invention, a composition comprising a graft copolymer, wherein the graft copolymer has a stem polymer and a plurality of branch polymers, the stem polymer has a polyvinyl alcohol structure, each of a first monomer unit and a second monomer unit is included in at least one of the plurality of branch polymers, the second monomer unit is different from the first monomer unit, a glass transition temperature of the composition is 260K to 365K is provided.

A composition with an excellent cycle capacity retention rate at high temperatures is provided.

According to the present invention, a composition comprising a graft copolymer, wherein the graft copolymer has a stem polymer and a plurality of branch polymers, the stem polymer has a polyvinyl alcohol structure, each of a first monomer unit and a second monomer unit is included in at least one of the plurality of branch polymers, the second monomer unit is different from the first monomer unit, a glass transition temperature of the composition is 260K to 365K is provided.

The present invention relates an emulsifier stabilized formulated copolymer dispersion, processes for forming the emulsifier stabilized formulated copolymer dispersion, and to uses thereof. The emulsifier stabilized formulated copolymer dispersion may be formed by polymerizing at least one monomer in the presence of a stabilizer package, to form an emulsifier stabilizer copolymer dispersion, and introducing a post-addition comprising a polyvinyl alcohol solution to the emulsifier stabilized copolymer dispersion to form an emulsifier stabilized formulated copolymer dispersion. The polyvinyl alcohol, added as solution, may be added in an amount from 1 to 10 % by weight, solid polyvinyl alcohol based on solids content of the emulsifier stabilized copolymer dispersion. The polyvinyl alcohol may have a molecular weight expressed as viscosity from 3 mPa.Math.s to 60 mPa.Math.s based on a 4 % solution at 20° C. and a degree of hydrolysis from 70 mol.% to 85 mol.%, preferably from 78 mol.% to 82 mol.%, more preferably 80 mol.%.

The present invention relates an emulsifier stabilized formulated copolymer dispersion, processes for forming the emulsifier stabilized formulated copolymer dispersion, and to uses thereof. The emulsifier stabilized formulated copolymer dispersion may be formed by polymerizing at least one monomer in the presence of a stabilizer package, to form an emulsifier stabilizer copolymer dispersion, and introducing a post-addition comprising a polyvinyl alcohol solution to the emulsifier stabilized copolymer dispersion to form an emulsifier stabilized formulated copolymer dispersion. The polyvinyl alcohol, added as solution, may be added in an amount from 1 to 10 % by weight, solid polyvinyl alcohol based on solids content of the emulsifier stabilized copolymer dispersion. The polyvinyl alcohol may have a molecular weight expressed as viscosity from 3 mPa.Math.s to 60 mPa.Math.s based on a 4 % solution at 20° C. and a degree of hydrolysis from 70 mol.% to 85 mol.%, preferably from 78 mol.% to 82 mol.%, more preferably 80 mol.%.

A composition including a graft copolymer, wherein the graft copolymer has a stem polymer and a branch polymer; the stem polymer contains a polyvinyl alcohol structure, the branch polymer contains a first monomer unit containing a (meth)acrylonitrile monomer unit and/or a (meth)acrylic acid monomer; the composition has a gel fraction of 30% or more; the gel fraction is represented by following formula: the gel fraction %=A×100/1; A g is an insoluble content left on a filter pater when 1 g of the composition is added to 300 ml of dimethyl sulfoxide to obtain a mixture and the mixture is stirred at 60° C. for 15 hours and then filtered through the filter paper, which is a No. 5C filter paper as specified in JIS P 380.