The present invention provides a polyvinyl alcohol graft copolymer including a polyvinyl alcohol main chain. The polyvinyl alcohol graft copolymer includes branched chains including structural units derived from the following monomers: (a) a fluorine-including ethylenically unsaturated monomer, (b) an ethylenically unsaturated carboxylic acid monomer, and (c) an ethylenically unsaturated amide monomer. The present invention also provides an aqueous binder composition, and an electrode slurry composition including the polyvinyl alcohol graft copolymer.

The present invention provides a polyvinyl alcohol graft copolymer including a polyvinyl alcohol main chain. The polyvinyl alcohol graft copolymer includes branched chains including structural units derived from the following monomers: (a) a fluorine-including ethylenically unsaturated monomer, (b) an ethylenically unsaturated carboxylic acid monomer, and (c) an ethylenically unsaturated amide monomer. The present invention also provides an aqueous binder composition, and an electrode slurry composition including the polyvinyl alcohol graft copolymer.

Disclosed in the present invention are a polyvinyl alcohol (PVA)-based degradable plastic, a preparation method therefor and application thereof, and a recycling method therefor. The preparation method comprises the following steps: a PVA solution is subjected to a chemical grafting reaction under an acidic condition under the action of a modifier; there are a phenyl group, an aldehyde group, and at least one group capable of forming a hydrogen bond with PVA in a structural formula of the modifier. The polyvinyl alcohol-based degradable plastic provided in the present invention has the advantages of being high in transparency, high in mechanical strength, not affected by environmental humidity, easy to degrade, good in thermal stability and good in biocompatibility, and has the advantages of recyclability, low costs, easy large-scale preparation and the like.

Disclosed in the present invention are a polyvinyl alcohol (PVA)-based degradable plastic, a preparation method therefor and application thereof, and a recycling method therefor. The preparation method comprises the following steps: a PVA solution is subjected to a chemical grafting reaction under an acidic condition under the action of a modifier; there are a phenyl group, an aldehyde group, and at least one group capable of forming a hydrogen bond with PVA in a structural formula of the modifier. The polyvinyl alcohol-based degradable plastic provided in the present invention has the advantages of being high in transparency, high in mechanical strength, not affected by environmental humidity, easy to degrade, good in thermal stability and good in biocompatibility, and has the advantages of recyclability, low costs, easy large-scale preparation and the like.

A method for producing antibacterial shock absorbing shoes is provided. The method includes the following steps of: designing a shoe tree and a shoe style, and selecting a material; attaching paper to an outside of the shoe tree to make a paper pattern; manufacturing a bottom pad, a middle pad and a foot pad, and punching a circular hole in the middle pad; soaking the leather pad with an antibacterial agent, punching semi-spherical protrusions and a connecting groove on the leather pad, forming a circular pinhole in a top end of the semi-spherical protrusion, pasting the leather pad on the middle pad with a glue and cutting the leather pad to manufacture a shock absorbing massage pad; wrapping the shoes, and shaping; and placing the shock absorbing massage pads and the foot pads into the shoes. The shoes manufactured have good breathability, shock absorbing property and antibacterial property.

A method for producing antibacterial shock absorbing shoes is provided. The method includes the following steps of: designing a shoe tree and a shoe style, and selecting a material; attaching paper to an outside of the shoe tree to make a paper pattern; manufacturing a bottom pad, a middle pad and a foot pad, and punching a circular hole in the middle pad; soaking the leather pad with an antibacterial agent, punching semi-spherical protrusions and a connecting groove on the leather pad, forming a circular pinhole in a top end of the semi-spherical protrusion, pasting the leather pad on the middle pad with a glue and cutting the leather pad to manufacture a shock absorbing massage pad; wrapping the shoes, and shaping; and placing the shock absorbing massage pads and the foot pads into the shoes. The shoes manufactured have good breathability, shock absorbing property and antibacterial property.

Provided are: a hydrophilization treatment agent; and a method for forming a hydrophilic coating film, which are capable of forming a coating film which has excellent hydrophilicity and water droplet removal properties and can maintain the excellent water drop removal properties. A polyetheramine is added to a specific aqueous resin dispersion and crosslinkable fine particles in a specific composition. Specifically, this hydrophilization treatment agent contains an aqueous resin dispersion (A), crosslinkable fine particles (B), and a polyetheramine (C), wherein: the aqueous resin dispersion (A) contains an ethylene-vinyl alcohol copolymer (A1) as a resin solid content and a radical polymer (A2) having a structural unit derived from a radically polymerizable carboxylic acid monomer (A2-1); ((A1)/(A2)) is 0.43-2.33; ((B)/(resin solid content of (A)) is 0.11-1.43; and ((C)/((resin solid content of (A))+(B))) is 0.1-0.38.

Provided are: a hydrophilization treatment agent; and a method for forming a hydrophilic coating film, which are capable of forming a coating film which has excellent hydrophilicity and water droplet removal properties and can maintain the excellent water drop removal properties. A polyetheramine is added to a specific aqueous resin dispersion and crosslinkable fine particles in a specific composition. Specifically, this hydrophilization treatment agent contains an aqueous resin dispersion (A), crosslinkable fine particles (B), and a polyetheramine (C), wherein: the aqueous resin dispersion (A) contains an ethylene-vinyl alcohol copolymer (A1) as a resin solid content and a radical polymer (A2) having a structural unit derived from a radically polymerizable carboxylic acid monomer (A2-1); ((A1)/(A2)) is 0.43-2.33; ((B)/(resin solid content of (A)) is 0.11-1.43; and ((C)/((resin solid content of (A))+(B))) is 0.1-0.38.

The present disclosure provides a modified polyvinyl alcohol-based polymer, which comprises a modifying monomer unit represented by Formula

##STR00001##

wherein, X is a moiety comprising an alkenyl group, and the modified polyvinyl alcohol-based polymer has a saponification degree of 67 mol % to 78 mol % and a modification rate of 0.02 mol % to 1.5 mol %. The modified polyvinyl alcohol-based polymer is suitable to be used as a dispersant for suspension polymerization, to make the obtained polyvinyl chloride-based resin have reduced particle diameter and few coarse particles.

The present disclosure provides a modified polyvinyl alcohol-based polymer, which comprises a modifying monomer unit represented by Formula

##STR00001##

wherein, X is a moiety comprising an alkenyl group, and the modified polyvinyl alcohol-based polymer has a saponification degree of 67 mol % to 78 mol % and a modification rate of 0.02 mol % to 1.5 mol %. The modified polyvinyl alcohol-based polymer is suitable to be used as a dispersant for suspension polymerization, to make the obtained polyvinyl chloride-based resin have reduced particle diameter and few coarse particles.