A styrenic block copolymer having one or more polymer blocks A and one or more polymer blocks B is disclosed, where “A” is a poly(vinylaromatic) block having a molecular weight of greater than 5 kg/mol. The “B” block has a molecular weight of more than 15 kg/mol, and comprises polymerized 1,3-diene units and vinylaromatic units, wherein the polymerized vinylaromatic units represent 5-40 wt. % of the overall weight of the block “B”. The polymerized 1,3-diene units comprise more than 80 wt. % of polymerized isoprene units in which 45-80 mol % are 1,4-isoprene addition units. The blocks “A” and “B” represent from >5 to <40 wt. %, and >33 to <95 wt. %, respectively, relative to the overall weight of the block copolymer. The polymers have physical properties that make them valuable, e.g., as vibration damping materials.

A styrenic block copolymer having one or more polymer blocks A and one or more polymer blocks B is disclosed, where “A” is a poly(vinylaromatic) block having a molecular weight of greater than 5 kg/mol. The “B” block has a molecular weight of more than 15 kg/mol, and comprises polymerized 1,3-diene units and vinylaromatic units, wherein the polymerized vinylaromatic units represent 5-40 wt. % of the overall weight of the block “B”. The polymerized 1,3-diene units comprise more than 80 wt. % of polymerized isoprene units in which 45-80 mol % are 1,4-isoprene addition units. The blocks “A” and “B” represent from >5 to <40 wt. %, and >33 to <95 wt. %, respectively, relative to the overall weight of the block copolymer. The polymers have physical properties that make them valuable, e.g., as vibration damping materials.

Disclosed are a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 0.1 to 9 mass % of a polyphenylene ether-based resin modified with an unsaturated carboxylic acid or acid anhydride thereof (b), 15 to 50 mass % of a homopolystyrene (c), 1 to 25 mass % of one or more selected from the group consisting of a hydrogenated block copolymer (d-1) and a rubber-modified polystyrene (d-2), and 5 to 35 mass % of glass fibers (e) which are surface-treated, a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 15 to 50 mass % of a homopolystyrene (c), 5 to 35 mass % of glass fibers (e), and 0.01 to 1 mass % of compounds (f), a method of producing the same, a molded article, and a mechanical component and housing.

Disclosed are a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 0.1 to 9 mass % of a polyphenylene ether-based resin modified with an unsaturated carboxylic acid or acid anhydride thereof (b), 15 to 50 mass % of a homopolystyrene (c), 1 to 25 mass % of one or more selected from the group consisting of a hydrogenated block copolymer (d-1) and a rubber-modified polystyrene (d-2), and 5 to 35 mass % of glass fibers (e) which are surface-treated, a resin composition comprising 20 to 50 mass % of a polyphenylene ether-based resin (a), 15 to 50 mass % of a homopolystyrene (c), 5 to 35 mass % of glass fibers (e), and 0.01 to 1 mass % of compounds (f), a method of producing the same, a molded article, and a mechanical component and housing.

A crosslinkable and foamable composition is provided, which comprises a hydrogenated styrenic diblock copolymer, a free radical initiator and a foaming agent, wherein the hydrogenated styrenic diblock copolymer comprises: a first block comprising a conjugated diene monomer unit; and a second block comprising a styrene unit, wherein the hydrogenated styrenic diblock copolymer comprises 10 to 60 wt % of the styrene unit, 50 mol % or more of the conjugated diene monomer unit is hydrogenated, and the hydrogenated styrenic diblock copolymer has a weight average molecular weight of 30000 to 200000. In addition, a foam obtained by crosslinking and foaming the aforesaid crosslinkable and foamable composition is also provided.

The conjugated diene-based polymer has a Mooney viscosity measured at 100° C. of 40 or more and 170 or less, has Mooney stress relaxation measured at 100° C. of 0.35 or less, and has a branch number (Bn) measured by viscosity detector-equipped GPC-light scattering measurement of 8 or more.

Quaternary ammonium tribromides and quaternary phosphonium tribromides are recovered from an organic solvent by washing with an aqueous hydrazine solution. The hydrazine reacts to form nitrogen, hydrobromic acid and a quaternary ammonium or quaternary phosphonium monobromide. The hydrobromic acid and quaternary ammonium or quaternary phosphonium migrate to the aqueous phase, thereby effecting the removal of the tribromides from the organic solvent. The hydrobromic acid can be neutralized with a quaternary ammonium or quaternary phosphonium hydroxide to produce a quaternary ammonium or quaternary phosphonium monobromide. The monobromides produced can be reacted with elemental bromine to regenerate a tribromide brominating agent.

Quaternary ammonium tribromides and quaternary phosphonium tribromides are recovered from an organic solvent by washing with an aqueous hydrazine solution. The hydrazine reacts to form nitrogen, hydrobromic acid and a quaternary ammonium or quaternary phosphonium monobromide. The hydrobromic acid and quaternary ammonium or quaternary phosphonium migrate to the aqueous phase, thereby effecting the removal of the tribromides from the organic solvent. The hydrobromic acid can be neutralized with a quaternary ammonium or quaternary phosphonium hydroxide to produce a quaternary ammonium or quaternary phosphonium monobromide. The monobromides produced can be reacted with elemental bromine to regenerate a tribromide brominating agent.

Quaternary ammonium tribromides and quaternary phosphonium tribromides are recovered from an organic solvent by washing with an aqueous hydrazine solution. The hydrazine reacts to form nitrogen, hydrobromic acid and a quaternary ammonium or quaternary phosphonium monobromide. The hydrobromic acid and quaternary ammonium or quaternary phosphonium migrate to the aqueous phase, thereby effecting the removal of the tribromides from the organic solvent. The hydrobromic acid can be neutralized with a quaternary ammonium or quaternary phosphonium hydroxide to produce a quaternary ammonium or quaternary phosphonium monobromide. The monobromides produced can be reacted with elemental bromine to regenerate a tribromide brominating agent.

A thermoplastic polymer composition (I) comprising: (A) block copolymer A comprising A1: 60 to 95 wt.-% vinyl aromatic monomer, and A2: 5 to 40 wt.-% conjugated diene; (B) a stabilizer combination consisting of: B1: 200 to 2500 ppm 2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino) phenol, B2: 500 to 2500 ppm 2-[1-(2-hydroxy-3,5-di-tert-pentylphenyl)ethyl]-4,6-di-tert-pentylphenyl acrylate and/or 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate, and B3: 500 to 2000 ppm tris(2,4-di-tert.-butylphenyl)phosphite; (C) 0 to 5000 ppm stabilizers different from (B1), (B2) and (B3); (D) optionally additives and/or processing aids other than (B) and (C), (E) optionally thermoplastic polymer TP other than block copolymer A, a process for its preparation, and its use for the preparation of shrink films is described.