Patent classifications
C08G77/12
THERMALLY CONDUCTIVE SILICONE RESIN COMPOSITION
One of the objects of the present invention is to provide a thermally conductive silicone resin composition which has good thermal conductivity, a light weight (namely, a light weight per unit volume), and good reliability in high humidity, and a molded body thereof. The present invention provides a thermally conductive silicone resin composition comprising the following components (A) to (E): (A) an organopolysiloxane having at least two alkenyl groups each bonded to a silicon atom in an amount of 100 parts by mass, (B) an organohydrogen polysiloxane having at least two hydrogen atoms each bonded to a silicon atom in an amount such that a ratio of the number of the hydrogen atom bonded to a silicon atom relative to the number of the alkenyl group in component (A) is 0.1 to 2, (C) a thermally conductive filler in an amount of 2500 to 6000 parts by mass, (D) a catalytic amount of an addition reaction catalyst, and (E) an addition-reaction controlling agent in an amount of 0.01 to 1 part by mass, wherein the thermally conductive filler (C) comprises magnesium oxide having a specific surface area of 0.4 m.sup.2/g or less in an amount of 20 to 50 wt % and aluminum hydroxide in an amount of 10 to 30 wt %, relative to a total weight of component (C).
CURABLE COMPOSITION AND INK FOR INK-JET PRINTING
A curable composition which comprises (A) an organopolysiloxane represented by formula (1)
##STR00001##
(wherein R.sup.1 represents an alkyl group, R.sup.2 represents an alkyl or aryl group, R.sup.3 represents a hydrogen atom or methyl group, Me represents a methyl group, m is an integer of 1-10, and a and b are integers of 1 or larger, a+b being an integer of 3-120), (B) a photopolymerization initiator, and (C) a hydrosilylation catalyst and which has a surface tension at 23° C. of 23-30 mN/m and a viscosity at 23° C. of 5-80 mPa.Math.s.
CURABLE COMPOSITION AND INK FOR INK-JET PRINTING
A curable composition which comprises (A) an organopolysiloxane represented by formula (1)
##STR00001##
(wherein R.sup.1 represents an alkyl group, R.sup.2 represents an alkyl or aryl group, R.sup.3 represents a hydrogen atom or methyl group, Me represents a methyl group, m is an integer of 1-10, and a and b are integers of 1 or larger, a+b being an integer of 3-120), (B) a photopolymerization initiator, and (C) a hydrosilylation catalyst and which has a surface tension at 23° C. of 23-30 mN/m and a viscosity at 23° C. of 5-80 mPa.Math.s.
Polymeric dispersants containing one or two quaternary amine anchoring groups with improved chemical and thermal stability
The present invention relates to a dispersant having a tertiary or quaternary amine anchoring group and a solubilizing polymer selected from C.sub.8-50 fatty acid; a C.sub.8-50 ak(en)yl substituted succinic acid, anhydride or partial ester; a dimer or trimer fatty acid; and/or polymers from repeating units of polyesters, polyethers, polyacrylate, polyamides, polyurethanes or mixtures of said repeating units in a random or blocky copolymer. The dispersants are an improvement in that the alkylene connecting group between the tertiary or quaternized amine and the solubilizing polymer lacks abstractable hydrogen atoms at the geminal carbon atom from the nitrogen of the tertiary or quaternized amine over the prior art. The dispersants are useful as dispersants with improved thermal stability and low amounts yellow color after aging at elevated temperatures.
Polymeric dispersants containing one or two quaternary amine anchoring groups with improved chemical and thermal stability
The present invention relates to a dispersant having a tertiary or quaternary amine anchoring group and a solubilizing polymer selected from C.sub.8-50 fatty acid; a C.sub.8-50 ak(en)yl substituted succinic acid, anhydride or partial ester; a dimer or trimer fatty acid; and/or polymers from repeating units of polyesters, polyethers, polyacrylate, polyamides, polyurethanes or mixtures of said repeating units in a random or blocky copolymer. The dispersants are an improvement in that the alkylene connecting group between the tertiary or quaternized amine and the solubilizing polymer lacks abstractable hydrogen atoms at the geminal carbon atom from the nitrogen of the tertiary or quaternized amine over the prior art. The dispersants are useful as dispersants with improved thermal stability and low amounts yellow color after aging at elevated temperatures.
Anchorage additive and methods for its preparation and use
A pressure sensitive adhesive composition includes (A) 0.1% to 5% an anchorage additive and (B) 95% to 99.9% of a silicone pressure sensitive adhesive composition. This pressure sensitive adhesive composition can be cured to form a pressure sensitive adhesive. When cured on a backing substrate, the resulting adhesive article is useful for protecting electronic devices during fabrication, shipping, and use.
Anchorage additive and methods for its preparation and use
A pressure sensitive adhesive composition includes (A) 0.1% to 5% an anchorage additive and (B) 95% to 99.9% of a silicone pressure sensitive adhesive composition. This pressure sensitive adhesive composition can be cured to form a pressure sensitive adhesive. When cured on a backing substrate, the resulting adhesive article is useful for protecting electronic devices during fabrication, shipping, and use.
Thermally-conductive silicone gel composition, thermally-conductive member, and heat dissipation structure
Provided is: a thermally conductive silicone gel composition which has a high thermal conductivity, and is less likely to flow out and slip off/drop off from a surface on which the gel composition is placed, even when the composition that has not been cured is placed on a sloped surface or in a vertical direction, and has excellent gap-filling ability with respect to a heat dissipation part, etc., and excellent repairability if desired; a thermally conductive member comprising the thermally conductive silicone gel composition; and a heat dissipation structure using the same. The thermally conductive silicone gel composition comprises: (A) an alkenyl group-containing organopolysiloxane; (B) an organohydrogenpolysiloxane; (C) a catalyst for a hydrosilylation reaction; (D) a thermally conductive filler; (E) a silane-coupling agent; and (F) a specific organopolysiloxane having a hydrolyzable silyl group at one end thereof. The gel composition has certain viscosity properties as disclosed herein.
LAMINATE BASED ON SILICONE RUBBER COMPOSITIONS
The invention relates to a laminate comprising a first layer and a second layer directly covering the first layer, the first layer being a layer of a silicone rubber composition comprising a micrometric silicone powder and a mixture of crosslinkable organopolysiloxanes, the second layer being a layer of a silicone rubber composition comprising a hydrophobic silica and a mixture of crosslinkable organopolysiloxanes, the first layer and the second layer being crosslinked. The laminate, in particular when it is used as a coating for the outer surface of an expandable bladder for a tyre curing mould, makes it possible to eliminate moulding defects on the inner liner of the tyre.
LAMINATE BASED ON SILICONE RUBBER COMPOSITIONS
The invention relates to a laminate comprising a first layer and a second layer directly covering the first layer, the first layer being a layer of a silicone rubber composition comprising a micrometric silicone powder and a mixture of crosslinkable organopolysiloxanes, the second layer being a layer of a silicone rubber composition comprising a hydrophobic silica and a mixture of crosslinkable organopolysiloxanes, the first layer and the second layer being crosslinked. The laminate, in particular when it is used as a coating for the outer surface of an expandable bladder for a tyre curing mould, makes it possible to eliminate moulding defects on the inner liner of the tyre.