The present, invention aims to provide an additive which has a reactive group with good active energy ray curability. When incorporated in a paint, the additive does not bleed over time and imparts an excellent leveling property and a defoaming property to the paint. There is provided a (meth)acrylic-modified siloxane compound of formula (a1) which has, as a branch and, optionally, at one or both of the terminals, of a linear polysiloxane backbone, a specific number of moieties having a (meth)acryloyl group at a terminal and a (poly)oxyalkylene structure of the formula —(C.sub.aH.sub.2aO).sub.b—. Also provided is an additive for paints, comprising said (meth)acrylic-modified siloxane compound.

A curable composition including (A) a compound having two or more alkenyl groups and a perfluoro(poly)ether group in one molecule, wherein the perfluoro(poly)ether group is represented by formula: —(OC.sub.6F.sub.12).sub.a—(OC.sub.5F.sub.10).sub.b—(OC.sub.4F.sub.8).sub.c—(OC.sub.3X.sup.10.sub.6).sub.d—(OC.sub.2F.sub.4).sub.e—(OCF.sub.2).sub.f—, a, b, c and d are each independently an integer of 0 to 30, e and f are each independently an integer of 1 to 200, the sum of a, b, c, d, e and f is at least 5, the occurrence order of the respective repeating units in parentheses with the subscript a, b, c, d, e or f is not limited in the formula, a ratio of e to f is 1.0 or more, and each X.sup.10, at each occurrence, is independently a hydrogen atom, a fluorine atom or a chlorine atom, (B) an organosilicon compound which has two or more hydrogen atoms each bonding to a silicon atom, in one molecule, and (C) a catalyst.

The present invention is related to a curable composition for dental impression comprising: a curable base composition and a surfactant system comprising a first surfactant, which is at least one compound having formula (I) and a fluorotelomer having formula (II), which works synergistically with the fluorotelomer so as to permit the composition to surprisingly have a lower contact angle; these results are reached with relatively low concentrations of biodegradable surfactants.

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A polyether-modified siloxane represented by an average composition formula (1): (R.sub.3SiO.sub.1/2).sub.a(R.sub.2R′SiO.sub.1/2).sub.a′(R.sub.2SiO.sub.2/2).sub.b(RR′SiO.sub.2/2).sub.b′(RSiO.sub.3/2).sub.c(SiO.sub.4/2).sub.d. In the formula (1), “R”s each represent a hydrogen atom, a hydroxy group, a monovalent hydrocarbon group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms, “R” 's each represent an organic group selected from groups represented by —C.sub.qH.sub.2q—O—(C.sub.2H.sub.4O).sub.e(C.sub.3H.sub.6O).sub.f—R.sup.1, R.sup.1s each represent a hydrogen atom, a hydrocarbon group having 1 to 30 carbon atoms, or an organic group represented by R.sup.6—(CO)—, and R.sup.6 represents a hydrocarbon group having 1 to 30 carbon atoms. This can provide a novel polyether-modified siloxane that has little environmental impact and that provides excellent antifouling performance.

A polyether-modified siloxane represented by an average composition formula (1): (R.sub.3SiO.sub.1/2).sub.a(R.sub.2R′SiO.sub.1/2).sub.a′(R.sub.2SiO.sub.2/2).sub.b(RR′SiO.sub.2/2).sub.b′(RSiO.sub.3/2).sub.c(SiO.sub.4/2).sub.d. In the formula (1), “R”s each represent a hydrogen atom, a hydroxy group, a monovalent hydrocarbon group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms, “R” 's each represent an organic group selected from groups represented by —C.sub.qH.sub.2q—O—(C.sub.2H.sub.4O).sub.e(C.sub.3H.sub.6O).sub.f—R.sup.1, R.sup.1s each represent a hydrogen atom, a hydrocarbon group having 1 to 30 carbon atoms, or an organic group represented by R.sup.6—(CO)—, and R.sup.6 represents a hydrocarbon group having 1 to 30 carbon atoms. This can provide a novel polyether-modified siloxane that has little environmental impact and that provides excellent antifouling performance.

Provided are a photocurable fluoropolyether-based elastomer composition having both a favorable preservation stability and fast curability, being bondable at a low temperature in a short period of time, and generating no air bubbles in the resin at the time of curing; and a bonding method thereof. The photocurable fluoropolyether-based elastomer composition contains: (A) a linear polyfluoro compound; (B) a fluorine-containing organohydrogenpolysiloxane; (C) a photoactive hydrosilylation reaction catalyst; and (D) a zeolite having an average primary particle size of not larger than 30 μm.

Provided is a composition capable of forming a cured product having excellent adhesion to a substrate, hardness, scratch resistance, and chemical resistance. The composition of the present disclosure includes a polyol compound (A) and an isocyanate compound (B), the polyol compound (A) containing a compound (a1) having a number average molecular weight calibrated with polystyrene standards of less than 800 and being represented by Formula (1), where R.sup.1 to R.sup.3 are a group represented by Formula (1a); and the isocyanate compound (B) containing a compound (b) represented by Formula (2), where L.sup.1 to L.sup.3 are a hydrogen atom, an NCO group, or an alkyl group having from 1 to 10 carbon atom(s) and having a group represented by Formula (2′).

A water-repellent coating composition, and particularly, a water-repellent coating composition having improved adhesion and durability by including a phosphoric acid or a phosphoric acid-based compound, is provided.

An epoxy-functionalized polyorganosiloxane toughener providing toughening properties for thermosetting resins is described. The epoxy-functionalized polyorganosiloxane toughener is an epoxy-functionalized siloxane polyether with a siloxane backbone, at least one epoxy-containing alkyl chain, and at least one alkoxyl polyether chain, each said at least one epoxy-containing alkyl chain and at least one alkoxyl polyether chain grafted to the siloxane backbone. Also disclosed is a thermosetting resin-based composition comprising the epoxy-functionalized polyorganosiloxane toughener of claim 1 and at least one of an epoxy resin, a hardener, and an accelerator.

Sidechain functionalized organosiloxane compounds are provided having a first end and a second end; a polysiloxane backbone; and a first plurality of sidechains covalently attached to the polysiloxane backbone and a second plurality of sidechains covalently attached to the polysiloxane backbone; wherein the first plurality of sidechains comprise polyalkylene glycol sidechains; wherein the first plurality of sidechains and the second plurality of sidechains comprise a tethered end covalently attached to the polysiloxane backbone and a free end opposite to the tethered end; and wherein the free end in one or both of the first plurality of sidechains and the second plurality of sidechains comprises a reactive end group. Compositions comprising the sidechain functionalized organosiloxane compounds are also provided, as well as coated articles. Sidechain functionalized lubricants are also provided that can be used with compositions and coated articles herein.