The present application can provide a preparation method capable of preparing a desired polymer or conductive polymer film with excellent polymerization efficiency and conversion rates without consumption or modulation in the polymerization process, and a polymer and a conductive polymer film formed by the method. The present application can provide a method for preparing a polymer or a conductive polymer film having a desired level of transparency and conductivity, wherein desired physical properties such as solubility in a solvent or resistance to a solvent are effectively imparted thereto as necessary, and a polymer and a conductive polymer film formed by the method.

Embodiments of the invention are directed to yellow/orange-to-transmissive conjugated polymers, a method to prepare the yellow/orange conjugated polymers, and an electrochromic and/or electroluminescent device comprising the neutral state yellow/orange conjugated polymers as one of a plurality of primary subtractive colored conjugated polymers. The yellow/orange conjugated polymers show enhanced redox stability and can have a (D.sub.2Ar.sub.z).sub.n structure with a dioxyheterocycle repeating unit or a (DAr.sub.z).sub.n structure with a dioxythiophene monomer that has at least one substituted carbon α to an oxygen of the monomer; and where the one to three Ar groups have at least one carbon α to the carbon attached to a D unit substituted that has at least 5 atoms in the substituent. The yellow/orange conjugated polymers show enhanced redox stability. The yellow/orange conjugated polymers are prepared by cross-condensation reactions.

A gel electrolyte precursor composition, an electrochromic device including a gel electrolyte formed from the precursor composition, and methods of forming the electrochromic device, the precursor composition including polymer network precursors including polyurethane acrylate oligomers, an ionically conducting phase, and an initiator.

The present disclosure presents a disulfide containing monomer, its reduced form, its derivative, the synthesis method of this disulfide containing monomer, and the polymer containing the monomers disclosed thereof

An all-donor black color electrochromic polymer is disclosed as well as a method for preparing the all-donor black color electrochromic polymer. The electrochromic polymer comprises conjugated polymers, and the conjugated polymers are chemically linked, or physically blended, or both.

The present application relates to an electrochromic composite, an electrochromic device comprising the same, and a method for manufacturing an electrochromic device.

Black-to-transmissive electrochromic polymers have superior properties such as absorbance of across the entire visible spectrum and an obvious color change from black to transmissive with an applied voltage. Methods for synthesizing or using the same include contacting monomers under polymerization conditions. Black-to-transmissive electrochromic polymer thin films include the black-to-transmissive electrochromic polymers, and electrochromic devices include the black-to-transmissive electrochromic polymers or thin films.

Electrochromic polymers include conjugated chromophores in spaced relation with one another, and conjugation-break spacers (CBSs). At least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

Various photocrosslinkable electrochromic polymers are disclosed. The polymers are suitable for an electrochromic layer of an electrochromic device. The polymers are formed with a two-step synthesis method that includes forming a polymer precursor with one or more chromophore blocks, and mixing the polymer precursor with photocrosslinkable monomer units to form the polymer.

The present application can provide a preparation method capable of preparing a desired polymer or conductive polymer film with excellent polymerization efficiency and conversion rates without consumption or modulation in the polymerization process, and a polymer and a conductive polymer film formed by the method. The present application can provide a method for preparing a polymer or a conductive polymer film having a desired level of transparency and conductivity, wherein desired physical properties such as solubility in a solvent or resistance to a solvent are effectively imparted thereto as necessary, and a polymer and a conductive polymer film formed by the method.