A film is provided with void spaces having a porous structure with less cracks and a high proportion of void space as well as having strength. The film with void spaces includes one kind or two or more kinds of structural units that form a structure with minute void spaces, wherein the structural units are chemically bonded through catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The film with void spaces can be produced by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products.

A hardcoat comprising a host matrix, a nanoporous filler in which the dispersed phase is a gas, and nonporous nanoparticles. Also, coating and curable compositions useful for preparing the hardcoat, methods of preparing the hardcoat and compositions, articles comprising the hardcoat or composition, and uses thereof.

According to at least one embodiment, there is provided a hard coat laminate film having a total light transmittance of 80% or more and having (γ) a hard coat on at least one surface of (α) an aromatic-polycarbonate resin film containing 30 mol % or more of a structural unit derived from 4,4′-(3,3,5-trimethylcyclohexane-1,1-diyl)diphenol when the total of the structural units derived from aromatic dihydroxy compounds is 100 mol %. According to another embodiment, there is provided a hard coat laminate film having a total light transmittance of 80% or more and having (γ) a hard coat on at least one surface of a transparent laminate film constituted of (α) an aromatic-polycarbonate resin film containing 30 mol % or more of a structural unit derived from 4,4′-(3,3,5-trimethylcyclohexane-1,1-diyl)diphenol, when the total of the structural units derived from aromatic dihydroxy compounds is 100 mol %, and (β) a poly(meth)acrylimide resin film.

A composite filament includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite filaments.

In an embodiment, a heat-seal film includes 10-90 wt % of a first polymer component and 10-90 wt % of a second polymer component, based on a total weight of the first polymer component and the second polymer component, wherein: the first polymer component includes propylene, and optionally, up to 18 wt % of a C.sub.2 and/or a C.sub.4-C.sub.20 α-olefin based on a total weight of the first polymer component; and the second polymer component includes 91-99.9 wt % of propylene and 0.1-9 wt % of ethylene based on a total weight of the second polymer component, the second copolymer component having a melt flow rate of 2-60 g/10 min. In another embodiment, a multi-layer film structure includes a heat-seal layer including a heat-seal film described herein; and an unoriented, an uniaxially oriented, or a biaxially oriented base layer including polypropylene homopolymer, a polypropylene random copolymer, or a combination thereof.

This invention relates to a resin composition for a hard coating, including a siloxane resin configured such that compounds including an alkoxysilane and an alkoxy metal compound are chemically bound, and to a hard coating film including a hard coating layer formed using the resin composition.

Body protection devices, particularly protective helmets are provided, which comprise a shell of plastic material or of fiber-reinforced plastic material, wherein the shell comprises an outer coating layer formed of a polyacrylic or polyepoxide polymeric matrix including graphene fillers. Processes for the production of body protection devices are also provided.

Modified plastic surfaces with perfluoropolymers are provided, whereby plastic surfaces that are intended for use under tribological conditions have substantially improved assembly properties and/or sliding friction properties and exhibit a very low degree of wear. Accordingly, modified plastic surfaces with perfluoropolymers are provided in which, after a reactive conversion under mechanical stress at room temperature, at least the reactive —NH groups and/or —OH groups present at the surface of plastics are present in a chemically covalently coupled manner with the perfluoropolymer carboxylic acid halide present at least in the surface-proximate region of modified perfluoropolymer (micro)powders and/or with the grafted (meth)acrylic acid halide present via perfluoropolymer (peroxy) radicals of the perfluoropolymer (micro)powders and/or (meth)acrylic acid that has been modified into (meth)acrylic acid halide before the reactive conversion.

According to one aspect, a composite film may include a substrate, and a protection coating overlying the substrate. The protection coating may include a urethane acrylate 6-functional oligomer, and a urethane acrylate 2-functional oligomer. The protection coating may further include a urethane acrylate oligomer ratio UAC.sub.6/UAC.sub.2 of at least about 0.5 and not greater than about 3, where UAC.sub.6 is equal to the content of the urethane acrylate 6-functional oligomer in wt. % for a total weight of the protection coating and UAC.sub.2 is equal to the content of the urethane acrylate 2-functional oligomer in wt. % for a total dry weight of the protection coating.

Disclosed herein are compositions to use in biofouling-resistant coatings, biofouling-resistant coatings, methods of making biofouling-resistant coatings, biofouling-resistant devices, and methods of making biofouling-resistant devices.