Methods for modification of surface wettability of fluorine-containing polymers by sequential treatments first with gaseous plasma rich in ultraviolet radiation, and then oxidation using neutral reactive oxidative species. The methods are rapid and permit treatment of fluorine-containing polymers of any shape and size including ‘infinite’ materials such as foils. A surface layer of an object made from a fluorine-containing polymer is depleted of fluorine upon interaction with gaseous plasma rich in ultraviolet radiation. The depleted surface layer is then exposed to reactive oxygen species such as neutral oxygen atoms in the ground state. The wettability of objects made from or containing fluorine-containing polymers treated according to the methods of the present disclosure is close to the theoretical limit for smooth polymers well functionalized with polar functional groups. Unlike conventional treatment of fluorine-containing polymers with oxygen plasma, the methods of the present disclosure do not produce hazardous gases such as oxy or peroxy fluorinated carbon compounds.

A foamable composition includes a base polymer, talc blended with the base polymer, and a citrate compound blended with the base polymer. The foamable composition is usable as an insulator, a separator and a jacket for cables, such as communications cable. The foamable composition can include conductive inclusions in the foamable composition.

Disclosed are a polymer electrolyte membrane, a method of manufacturing the membrane, and a membrane-electrode assembly including the membrane. The polymer electrolyte membrane contains a porous support having a plurality of pores, a first layer including a first ion conductor that fills the pores adjoining one surface of the porous support, and a second layer including a second ion conductor that fills the pores adjoining the other surface of the porous support, wherein the first ion conductor and the second ion conductor are different from each other, and one selected from the group consisting of the first layer, the second layer, and a combination thereof includes an organic-based antioxidant.

A resin sheet that contains one or more kinds of resin materials and a liquid crystal polymer, wherein a weight of the liquid crystal polymer is less than a total weight of the one or more kinds of resin materials. The resin sheet has a thermal expansion coefficient in a plane direction smaller than a thermal expansion coefficient in the plane direction of a comparative resin sheet containing the one or more kinds of resin materials and not containing the liquid crystal polymer.

To provide a polymer wherein a linking group that connects the main chain of the polymer and a cyclic perfluoroaliphatic disulfonimide skeleton, is a fluoroalkylene group which may have an ether oxygen atom. A polymer which has either one or both of units represented by formula u1-1 and units represented by formula u1-2:

##STR00001##

R.sup.F1, R.sup.F2: a C.sub.1-3 perfluoroalkylene group; R.sup.F3: a C.sub.1-6 perfluoroalkylene group; m: 0 or 1; and X: a hydrogen atom, an alkali metal atom, a fluorine atom, an alkyl group, ammonium or the like.

The invention relates to a composition based on a thermoplastic fluoropolymer powder, in particular on polyvinylidene fluoride (PVDF) with improved flowability, particularly suitable for manufacturing parts by 3D laser sintering. The invention also relates to a method for agglomerating powder layer by layer, by melting or sintering using said composition. The invention finally relates to a three-dimensional article obtained by implementing said method.

Disclosed are a method for a preparing fluorine- and chlorine-containing conductive polymer resin, a single-side or double-side filled composite film prepared using the fluorine- and chlorine-containing conductive polymer resin, and a method for preparing the film. The fluorine- and chlorine-containing conductive polymer single-side or double-side filled composite film comprises a microporous film skeleton and the fluorine- and a chlorine-containing conductive polymer resin. The composite film is mechanically stronger, more waterproof, more impervious to water and toxic and harmful chemicals, and more moisture permeability. When applied to biochemical protective clothing, it can greatly enhance the combat effectiveness of the soldiers because it is light and more impervious to water and toxic and harmful chemicals, brings about comfort, and keeps the soldiers warm. When applied to fuel cells, it can provide better electrical properties due to its high conductivity and can allow the fuel, such as hydrogen or alcohol, to burn more completely.

The present disclosure relates to a process for the processing of perfluoropolymer materials, and to the use of the resultant products in different potential applications, such as in the medical device field. The process can include, for example, the steps of: (i) dissolving one or more uncured perfluoropolymer materials in a solvent containing one or more liquid perfluorinated solvent(s) to form a solution; (ii) optionally adding one or more porogens and/or one or more functional additives to the solution formed in (i) to form a mixture; (iii) applying the resultant solution or mixture formed in steps (i) and (ii) to a substrate to form one or more partial or continuous deposited layers on the substrate; (iv) curing the perfluoropolymer within the deposited layer to form a perfluoroelastomeric product; and (v) optionally removing the porogen from the perfluoroelastomeric product.

Provided are a fluororesin-containing composition having significantly improved fluidity and a method for producing the same. The fluororesin-containing composition contains 99.99 to 97% by mass of a fluororesin having a melting point of 205° C. to 225° C. and 0.01 to 2% by mass of a thermotropic liquid crystal polymer. The method for producing the fluororesin-containing composition includes kneading polychlorotrifluoroethylene and a thermotropic liquid crystal polymer at 285° C. to 320° C.

The present invention provides composite particles which are capable of forming an ion exchange membrane with fewer defects and an ion exchange membrane. The composite particles according to the present invention comprise pellets comprising a fluorinated polymer having groups convertible to ion exchange groups, and a powder held on the pellet surface which comprises a polymer, wherein the powder has an average particle diameter of at least 1 μm and at most 1,000 μm, and the ratio of the average particle diameter of the pellets to the average particle diameter of the powder is 2 to 4,500.