The present invention provides a liquid polysiloxane comprising a siloxane-thiourea segment and a crosslinkable functional group(s) selected from one or more ethylenically unsaturated groups, silyl hydride groups, alkylenethiol groups and combinations thereof.

This invention provides a scrollable and foldable transparent polysiloxane film and its preparation and self-healing method. 2-Hydroxyethyl disulfide, diisocyanate and alkane chloride were mixed and reacted to get disulfide-containing diisocyanate. α,ω-Aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride were mixed and reacted get linear chain-extended polydimethylsiloxane. Linear chain-extended polydimethylsiloxane, multi-amino terminated hyperbranched polysiloxane, disulfide-containing diisocyanate and alkane chloride were mixed and poured into a mould. After drying, the scrollable and foldable transparent polysiloxane film was obtained. The polysiloxane film described in this invention are constructed by dynamic physical crosslinking induced by hydrogen bond and permanent chemical crosslinking generated by hyperbranched polysiloxane. Hence, the polysiloxane film achieves both high stiffness and toughness. The good self-healing behavior of the polysiloxane films is originated from the temperature controlled dissociation of hydrogen bonds and exchange reaction rate of disulfide bonds.

Urea and amine comprising sol-gel hybrid coatings have been developed for numerous applications, including capillary microextraction-high performance liquid chromatographic analysis from aqueous samples. A fused silica capillary may be coated from the inside with surface bonded coating material and may be created by in-situ sol-gel reaction(s). Urea-functionalized coatings can be immobilized on the inner surface of a capillary by condensing silanol groups of capillary and sol-solution. Urea functionalized, sol-gel coated capillaries may be installed, e.g., in HPLC manual injection ports, and optionally pre-concentrated analytes including phenols, ketones, aldehydes, and/or polyaromatic hydrocarbons, from highly polar to non-polar, maybe analyzed by online extraction and high-performance liquid chromatographic. Such coatings may achieve sensitivities with lower detection limits (S/N=3) of 0.10 ng/mL to 14.29 ng/mL, with reproducibilities of <12.0% RSD (n=3), or <10.0% RSD (n=3) by exchanging the capillary of the same size.

The invention is related to a cost-effective method for making a silicone hydrogel contact lens having a crosslinked hydrophilic coating thereon. A method of the invention involves heating a silicone hydrogel contact lens in an aqueous solution in the presence of a watersoluble, highly branched, thermally-crosslinkable hydrophilic polymeric material having positively-charged azetidinium groups, to and at a temperature from about 40° C. to about 140° C. for a period of time sufficient to covalently attach the thermally-crosslinkable hydrophilic polymeric material onto the surface of the silicone hydrogel contact lens through covalent linkages each formed between one azetidinium group and one of the reactive functional groups on and/or near the surface of the silicone hydrogel contact lens, thereby forming a crosslinked hydrophilic coating on the silicone hydrogel contact lens. Such method can be advantageously implemented directly in a sealed lens package during autoclave.

Aminofunctional silicone compositions are disclosed comprising: an organopolysiloxane having an average formula of (CH.sub.3).sub.3SiO[(CH.sub.3).sub.2SiO].sub.x [(CH.sub.3)R.sup.NSiO].sub.ySi(CH.sub.3).sub.3 with less than 1 weight % of nitrogen in its formula, where R.sup.N is an aminofunctional group, x is ≧100, y is ≧1 with the proviso the sum of x+y is from 250 to 350; wherein the viscosity of the silicone composition ranges from 1000 to 2500 cP at 25° C. and is measured by a Brookfield RV DV viscometer equipped with Pro CP 52 spindle at 20 RPM; and the aminofunctional silicone composition contains less than 0.1 weight % of D4 and less than 0.1 weight % D5 cyclic siloxanes.

Provided are a low-reflective coating layer, a porous layer, a method of fabricating the porous layer, and an optical member including the porous layer. According to an embodiment, a low-reflective coating layer comprising a porous film having hollow sphere structures or bowl-like structures is provided. Each hollow sphere structure or bowl-like structure may have cavity formed therein. The hollow sphere structures or the bowl-like structures may be formed from spherical micelles, and each spherical micelle may be formed by self-assembling a supramolecular complex of a first compound block and a second compound block. In addition, the first compound block may constitute a backbone of the supramolecular chemical compound and the second compound block may constitute a side chain of the supramolecular. The second compound block may be non-covalent bonded to the first compound block.

The present invention relates to a curable silicone composition comprising: (A) at least one organopolysiloxane having at least two alkenyl groups per molecule; (B) at least one mercapto functional organopolysiloxane having at least two thiol groups per molecule; (C) at least one photopolymerization initiator; and, (D) 2,6-di-tert-butyl-4-methylphenol (BHT), wherein the composition has a viscosity of less than 200 mPa.Math.s at 25° C.

A hardcoat film includes: a substrate; and a hardcoat layer, in which the hardcoat film satisfies the following Formulas (i) and (ii), (i) E′.sub.(0.4)HC×d.sub.HC≥8,000 MPa.Math.μm, (ii) E′.sub.(4)HC×d.sub.HC≤4,000 MPa.Math.μm, E′.sub.(0.4)HC is an elastic modulus of the hardcoat layer obtained in a case where an elongation rate is 0.4%, E′.sub.(4)HC is an elastic modulus of the hardcoat layer obtained in a case where an elongation rate is 4%, and d.sub.HC is a film thickness of the hardcoat layer.

Nanoemulsions are prepared by: a) solubilizing a silicone resin in an organic solvent system to yield a silicone resin solution concentration of 80% or less, wherein the organic solvent system comprises diethyleneglycol monobutyl ether and at least one additional solvent; b) mixing the silicone resin solution from a) with an aminosiloxane polymer to obtain an aminosiloxane polymer: silicone resin mixture; c) allowing the resin mixture to age for at least about 6 hours at ambient temperature; d) adding the resin mixture to a vessel; e) optionally adding with agitation an additional organic solvent to the resin mixture; f) mixing until homogenous; g) adding a protonating agent; h) adding an aqueous carrier in an amount to produce a desired concentration of emulsion.

The disclosure relates generally to a polymeric material for use in accommodating intraocular lenses for implantation in a lens chamber of a subject's eye. The present disclosure is directed to a polymeric material which comprises a fluorosilicone polymer and a silica component. The presently disclosed polymeric material is both optically clear and has a sufficiently low Young's modulus such that it can effectively respond to the eye's natural accommodative forces and thus can be used in accommodating intraocular lenses. When used in the fabrication of an intraocular lenses, the polymeric material disclosed herein protect the physical characteristics of the lens as the added hydrophobicity of the fluorosilicone polymer allows it to effectively resist diffusion of fluid from the eye and the adhesion of biologica materials.