Provided are a polyhedral oligomeric silsesquioxane and a preparation method thereof, more particularly, a polyhedral oligomeric silsesquioxane itself which has a low refractive property and enables formation of a coating layer with excellent chemical and mechanical properties, and provides excellent adhesive strength for the surfaces of various substrates, and a preparation method thereof.

A vulcanizate prepared by a method comprising introducing an elastomer, a filler, and a mercapto-functional siloxane to form a masterbatch and introducing a curative to the masterbatch to form a vulcanizable composition.

Disclosed is an active energy ray curable hot melt silicone composition that is non-flowable at 25? C. and has a viscosity of 1,000 Pa.Math.s or less at 100? C. The active energy ray curable hot melt silicone composition comprises: (A) a mixture of (A1) an organopolysiloxane having an aliphatic unsaturated bond-containing organic group and (A2) an organopolysiloxane optionally having an aliphatic unsaturated bond-containing organic group, (B) a compound having at least two mercapto groups in a molecule, and (C) a photoradical initiator. A cured product and a method of making a film are also disclosed.

An anti-reflective film having a stacked structure including a transparent substrate, a high refraction layer and a low refraction layer, and more specifically, the low refraction layer may include, as a binder, a siloxane compound synthesized by reacting alkoxysilane and organosilane having a fluoroalkyl group.

A hybrid crosslinked polymeric membrane and a process for fabricating the same are provided. Specifically, the hybrid crosslinked polymer membrane comprises a glassy polymer and a ladder-structured polysilsesquioxane and has a crosslinked structure. The hybrid crosslinked polymer membrane can have an excellent permeability of carbon dioxide by virtue of an increase in the free volume and enhanced plasticization resistance, chemical resistance, and durability.

Methods for forming a coated digitally manufactured part include forming an article by a digital manufacturing method; coating a surface of the article with a reactive silicon-containing precursor polymer; and treating the polymer to form a silica-containing coating, thereby forming the coated digitally manufactured part. An article includes a digitally manufactured part having surface striations; and a coating encapsulating the digitally manufactured part and comprising silica. An article includes a digitally manufactured part (i) formed by selective lase sintering, (ii) comprising a surface defined by coalesced particles, and (iii) having a surface roughness R.sub.a of at least 0.1 microns; and a coating encapsulating the part and comprising silica. A composition comprising polysilazane is described.

Coating compositions including about 50-80% by weight of a water-based silicone elastomer composition, about 0.5-4.0% by weight of a silane adhesion promoter, about 0.02-0.5% by weight of a silicone surfactant, and about 10-50% by weight water are disclosed herein. Also included are methods of preparing the coating compositions and methods of using the coating compositions.

A curable composition comprising a polymer A, a polymer B, and one or more fillers, wherein the polymer A includes organic molecules or siloxane molecules comprising two or more epoxy functional groups, and the polymer B includes an organic amine or a hybrid silicone amine.

A polymer brush includes a substrate material, a polymerization initiator layer containing a hydrolysis and condensation polymerization polymer comprising a first organosilane and a metal alkoxide on a surface of said substrate material, and polymer chains extending from a surface of the polymerization initiator layer. The first organosilane is a polymerization initiator group-containing organosilane having the following formula (I): XR.sup.1-Ph-(R.sup.2).sub.mSiR.sup.3.sub.nR.sup.4.sub.3-n . . . (I) where X stands for a halogen atom, R.sup.1 stands for an alkylene group having 1 to 3 carbon atoms, Ph stands for a phenylene group, R.sup.2 stands for a C1 to C10 alkylene group optionally via an oxygen atom, R.sup.3 stands for an alkoxy group having 1 to 3 carbon atoms or chloro group, R.sup.4 stands for an alkyl group having 1 to 6 carbon atoms, m is 0 or 1, n is 1, 2 or 3.

Provided herein are ionically conductive solid-state compositions that include ionically conductive inorganic particles in a matrix of an organic material. The resulting composite material has high ionic conductivity and mechanical properties that facilitate processing. In particular embodiments, the ionically conductive solid-state compositions are compliant and may be cast as films. In some embodiments of the present invention, solid-state electrolytes including the ionically conductive solid-state compositions are provided. In some embodiments of the present invention, electrodes including the ionically conductive solid-state compositions are provided. The present invention further includes embodiments that are directed to methods of manufacturing the ionically conductive solid-state compositions and batteries incorporating the ionically conductive solid-state compositions.