A material, article, system and method include a probe composition that includes a hydrophobic portion, a hydrophilic portion, an analyte-binding portion and a fluorophore portion. The analyte-binding portion is configured to bind to an analyte in an aqueous solution. The fluorophore portion is configured to change an optical property of fluorescent light emitted in response to incident excitation light when the probe composition changes between a first state in which the analyte is not bound to the analyte-binding portion and a second state in which the analyte binds to the analyte-binding portion. A material includes the probe composition and a silicone hydrogel substrate having a hydrogel network that allows flow of aqueous solution through the solution and a silicone network that occupies interstices of the hydrogel network. A contact lens having the material enables remote detection of glucose concentration in tear fluid of a subject.

A material, article, system and method include a probe composition that includes a hydrophobic portion, a hydrophilic portion, an analyte-binding portion and a fluorophore portion. The analyte-binding portion is configured to bind to an analyte in an aqueous solution. The fluorophore portion is configured to change an optical property of fluorescent light emitted in response to incident excitation light when the probe composition changes between a first state in which the analyte is not bound to the analyte-binding portion and a second state in which the analyte binds to the analyte-binding portion. A material includes the probe composition and a silicone hydrogel substrate having a hydrogel network that allows flow of aqueous solution through the solution and a silicone network that occupies interstices of the hydrogel network. A contact lens having the material enables remote detection of glucose concentration in tear fluid of a subject.

A polymerizable composition for an optical material according to the present invention includes a photochromic composition (A), and a polymerizable composition (B) including a bi- or higher functional iso(thio)cyanate compound and a bi- or higher functional active hydrogen compound, in which the photochromic composition (A) is a composition including at least three types of photochromic compounds (i) to (iii), the photochromic compound (i) has a structure including a chromophore a and a monovalent or a divalent organic group including one or more types of a polysiloxane chain or a polyoxyalkylene chain, the photochromic compound (ii) has the chromophore a (which is not the photochromic compound (i)), and the photochromic compound (iii) has a chromophore b different from the chromophore a.

A polymerizable composition for an optical material according to the present invention includes a photochromic composition (A), and a polymerizable composition (B) including a bi- or higher functional iso(thio)cyanate compound and a bi- or higher functional active hydrogen compound, in which the photochromic composition (A) is a composition including at least three types of photochromic compounds (i) to (iii), the photochromic compound (i) has a structure including a chromophore a and a monovalent or a divalent organic group including one or more types of a polysiloxane chain or a polyoxyalkylene chain, the photochromic compound (ii) has the chromophore a (which is not the photochromic compound (i)), and the photochromic compound (iii) has a chromophore b different from the chromophore a.

The photochromic composition contains one or more compounds represented by General Formula A, one or more compounds represented by General Formula B, and one or more compounds represented by General Formula C is provided. In General Formula A, R.sup.1 to R.sup.6, B.sup.1, and B.sup.2 each independently represent a hydrogen atom or a substituent. In General Formula B, R.sup.7 to R.sup.12, B.sup.3, and B.sup.4 each independently represent a hydrogen atom or a substituent, and R.sup.13 and R.sup.14 each independently represent an electron-donating group. In General Formula C, R.sup.15 to R.sup.20, B.sup.5, and B.sup.6 each independently represent a hydrogen atom or a substituent, and one of R.sup.21 and R.sup.22 represents a hydrogen atom and the other represents an electron-donating group.

##STR00001##

The photochromic composition contains one or more compounds represented by General Formula A, one or more compounds represented by General Formula B, and one or more compounds represented by General Formula C is provided. In General Formula A, R.sup.1 to R.sup.6, B.sup.1, and B.sup.2 each independently represent a hydrogen atom or a substituent. In General Formula B, R.sup.7 to R.sup.12, B.sup.3, and B.sup.4 each independently represent a hydrogen atom or a substituent, and R.sup.13 and R.sup.14 each independently represent an electron-donating group. In General Formula C, R.sup.15 to R.sup.20, B.sup.5, and B.sup.6 each independently represent a hydrogen atom or a substituent, and one of R.sup.21 and R.sup.22 represents a hydrogen atom and the other represents an electron-donating group.

##STR00001##

The present invention pertains to polyurethane-urea based optical adhesives for formation of optical film laminates, optically functional film laminates, and ophthalmic or eyeglass lenses employing the same and methods for producing the same.

A pneumatic tire that rotates about a center axis includes a tread rubber that comprises a contact patch; a groove provided in the tread rubber, the groove having an inner surface that includes a bottom surface and side surfaces that connect the bottom surface to the contact patch; and a coating film disposed covering at least a portion of the inner surface, the coating film reducing exposure of ultraviolet light to the inner surface.

A pneumatic tire that rotates about a center axis includes a tread rubber that comprises a contact patch; a groove provided in the tread rubber, the groove having an inner surface that includes a bottom surface and side surfaces that connect the bottom surface to the contact patch; and a coating film disposed covering at least a portion of the inner surface, the coating film reducing exposure of ultraviolet light to the inner surface.

A coating composition includes: (i) a film-forming resin; (ii) an infrared reflective pigment; and (iii) an infrared fluorescent pigment or dye different from the infrared reflective pigment. A multi-layer coating including the coating composition, and a substrate at least partially coated with the coating composition is also disclosed. A method of detecting an article at least partially coated with the coating composition is also disclosed.