The present disclosure relates to a chromium-free coating composition including at least one binder and at least one iron(III)-tris(N,N-dithiocarbamate) complex, where the binder includes at least one synthetic resin and at least one crosslinker. The present disclosure also relates to the use of such a coating composition for the protection against corrosion of metallic substrates, a process for at least partially coating a metallic substrate with such a priming coat, a substrate at least partially coated therewith and an article or a component made of such a substrate.

The present disclosure relates to a chromium-free coating composition including at least one binder and at least one iron(III)-tris(N,N-dithiocarbamate) complex, where the binder includes at least one synthetic resin and at least one crosslinker. The present disclosure also relates to the use of such a coating composition for the protection against corrosion of metallic substrates, a process for at least partially coating a metallic substrate with such a priming coat, a substrate at least partially coated therewith and an article or a component made of such a substrate.

A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.

A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.

Embodiments of the present disclosure describe a method of removing an end group from a polymer comprising contacting a polymer having a thiocarbonylthio end group, or a solution containing such a polymer, with an excess of a borane compound in the presence of oxygen. Embodiments of the present disclosure further describe a method of polymerization comprising contacting one or more monomers with an initiator and a chain transfer agent to form a polymer having a thiocarbonylthio end group in a reaction solution and contacting the polymer with a borane compound in the presence of oxygen to remove the thiocarbonylthio end group from the polymer.

Embodiments of the present disclosure describe a method of removing an end group from a polymer comprising contacting a polymer having a thiocarbonylthio end group, or a solution containing such a polymer, with an excess of a borane compound in the presence of oxygen. Embodiments of the present disclosure further describe a method of polymerization comprising contacting one or more monomers with an initiator and a chain transfer agent to form a polymer having a thiocarbonylthio end group in a reaction solution and contacting the polymer with a borane compound in the presence of oxygen to remove the thiocarbonylthio end group from the polymer.

An asphalt pavement modification system and method for improving aging resistance of asphalt pavement and a method of manufacturing reclaimed asphalt pavement. The asphalt pavement modification system and method include using one or more antioxidants and one or more recycling agents in a blended binder to provide improved short term and long term performance of the asphalt pavement. The method of manufacturing reclaimed asphalt pavement includes mixing at least one antioxidant with at least one recycling agent to form a binder that constitutes a portion of the reclaimed asphalt pavement. One of the antioxidants may be zinc diethyldithiocarbamate.

An asphalt pavement modification system and method for improving aging resistance of asphalt pavement and a method of manufacturing reclaimed asphalt pavement. The asphalt pavement modification system and method include using one or more antioxidants and one or more recycling agents in a blended binder to provide improved short term and long term performance of the asphalt pavement. The method of manufacturing reclaimed asphalt pavement includes mixing at least one antioxidant with at least one recycling agent to form a binder that constitutes a portion of the reclaimed asphalt pavement. One of the antioxidants may be zinc diethyldithiocarbamate.

The invention pertains to a (per)fluoroelastomer composition comprising at least one (per)fluoroelastomer comprising iodine and/or bromine atoms, at least one polyunsaturated compound, at least one organic peroxide and at least one organic compound selected from the group consisting of (thio)urea compounds, cyclic addition products of ammonia or primary amine and aldehyde; (thio)carbamates.

The invention pertains to a (per)fluoroelastomer composition comprising at least one (per)fluoroelastomer comprising iodine and/or bromine atoms, at least one polyunsaturated compound, at least one organic peroxide and at least one organic compound selected from the group consisting of (thio)urea compounds, cyclic addition products of ammonia or primary amine and aldehyde; (thio)carbamates.