Patent classifications
C08K5/5398
Rubber composition for treads and pneumatic tire
Provided are: a rubber composition for treads which contains a diene rubber in the rubber component and can simultaneously achieve blowing resistance during dry running, wet grip performance and abrasion resistance; and a pneumatic tire including a tread formed from the rubber composition for treads. The rubber composition contains: a diene rubber including styrene-butadiene rubber; zinc dithiophosphate; an inorganic filler including at least one selected from the group consisting of: a compound of the formula: mM.xSiO.sub.y.zH.sub.2O wherein M represents at least one metal selected from the group consisting of Al, Mg, Ti, Ca, and Zr, or an oxide or hydroxide of the metal, m represents an integer of 1-5, x represents an integer of 0-10, y represents an integer of 2-5, and z represents an integer of 0-10; magnesium sulfate; and silicon carbide, and having a BET value of 5-120 m.sup.2/g and a linseed oil absorption of 30-80 mL/100 g; and sulfur, wherein, per 100 parts by mass of the diene rubber, there are 0.2-15 parts by mass of the zinc dithiophosphate, 1-70 parts by mass of the inorganic filler, and less than 2.5 parts by mass of zinc oxide.
FLAME-RETARDANT EPOXY RESIN COMPOSITION, PREPREG AND LAMINATED PLATE USING THE SAME
A flame-retardant epoxy resin composition wherein (A) epoxy resin, (B) a curing agent and (C) a phosphorous-containing compound expressed by the following general formula (1) are contained; a prepreg using the same and a laminated plate using said prepreg;
##STR00001##
wherein m expresses an integer from 2 to 10, R.sup.1 and R.sup.2 each independently express an alkyl group or an aryl group, R.sup.3 expresses a hydrocarbon group that may contain an oxygen atom, a sulfur atom or a nitrogen atom, X expresses an oxygen atom or a sulfur atom, Y expresses an oxygen atom, a sulfur atom or NR.sup.4, and in this regard, R.sup.4 expresses a hydrogen atom, an alkyl group or an aryl group.
FLAME-RETARDANT EPOXY RESIN COMPOSITION, PREPREG AND LAMINATED PLATE USING THE SAME
A flame-retardant epoxy resin composition wherein (A) epoxy resin, (B) a curing agent and (C) a phosphorous-containing compound expressed by the following general formula (1) are contained; a prepreg using the same and a laminated plate using said prepreg;
##STR00001##
wherein m expresses an integer from 2 to 10, R.sup.1 and R.sup.2 each independently express an alkyl group or an aryl group, R.sup.3 expresses a hydrocarbon group that may contain an oxygen atom, a sulfur atom or a nitrogen atom, X expresses an oxygen atom or a sulfur atom, Y expresses an oxygen atom, a sulfur atom or NR.sup.4, and in this regard, R.sup.4 expresses a hydrogen atom, an alkyl group or an aryl group.
ORGANIC SILICON RESIN COMPOSITION, WHITE PREPREG AND WHITE LAMINATE USING SAME
Provided are an organic silicon resin composition, prepreg and laminate using the same. The organic silicon resin composition glue solution contains a condensation silicon resin, a catalyst, an auxiliary agent, a white filler and a solvent as necessary components, and is impregnated in a reinforced material such as a sheet-like fiberglass fiber base material and then dried to prepare the prepreg. The prepreg has a net structure via crosslinking of the silicon resin using a condensation reaction. Since the organic silicon resin has ultrahigh heat resistance and yellowing resistance, the present invention applies the silicon resin to a white LED copper-clad laminate instead of a traditional organic resin, satisfying the demand for high heat resistance, and replacing the ceramic substrate to be a new heat-dissipating substrate base material.
TREAD RUBBER COMPOSITION AND PNEUMATIC TIRE
Provided are: a rubber composition for treads having high grip performance, abrasion resistance, and tensile properties and capable of reducing the occurrence of blowing even during high-temperature running although it is a high softener content composition incorporating at least a certain amount of a softener with a rubber component including diene rubber; and a pneumatic tire including a tread formed from the rubber composition for treads. Included is a rubber composition for treads containing: a diene rubber including styrene-butadiene rubber; at least one softener selected from the group consisting of low temperature plasticizers, process oils, and resins having a softening point of 160 C. or lower; zinc dithiophosphate; and sulfur, wherein, per 100 parts by mass of the diene rubber, there are 40 parts by mass or more of the softener, 0.2-15 parts by mass of the zinc dithiophosphate, and less than 2.5 parts by mass of zinc oxide.
TREAD RUBBER COMPOSITION AND PNEUMATIC TIRE
Provided are: a rubber composition for treads having high grip performance, abrasion resistance, and tensile properties and capable of reducing the occurrence of blowing even during high-temperature running although it is a high softener content composition incorporating at least a certain amount of a softener with a rubber component including diene rubber; and a pneumatic tire including a tread formed from the rubber composition for treads. Included is a rubber composition for treads containing: a diene rubber including styrene-butadiene rubber; at least one softener selected from the group consisting of low temperature plasticizers, process oils, and resins having a softening point of 160 C. or lower; zinc dithiophosphate; and sulfur, wherein, per 100 parts by mass of the diene rubber, there are 40 parts by mass or more of the softener, 0.2-15 parts by mass of the zinc dithiophosphate, and less than 2.5 parts by mass of zinc oxide.
Process for regenerating sulfur-crosslinked rubber vulcanizates to give regenerates
A process for regenerating sulfur-crosslinked rubber vulcanizates to regenerates, wherein at least one regenerating agent is used in the regeneration. The regenerating agent is selected from the group consisting of dithiophosphoryl polysulfides and/or silanes having a polysulfane group. Regenerates which have been produced by means of the process lead to improved or equal rolling resistance indicators and a lower compression set in vulcanized rubber mixtures compared to regenerates known in the prior art.
DOPO-Based Hybrid Flame Retardants
The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.
DOPO-Based Hybrid Flame Retardants
The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.
DOPO-Based Hybrid Flame Retardants
The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.