Patent classifications
C08K5/57
Method for manufacturing room-temperature-curable organopolysiloxane composition, room-temperature-curable organopolysiloxane composition, and article
Through the present invention, by undergoing a step in which a straight-chain diorganopolysiloxane having silanol groups at both terminal ends of the molecular chain thereof, a hydrolyzable silane and/or a partial hydrolysis condensate thereof having a hydrolyzable group capable of detaching a lactic acid ester, and an amino-group-containing hydrolyzable organosilane and/or a partial hydrolysis condensate thereof are pre-mixed/reacted in advance and silanol groups at both terminal ends of the molecular chain of a main agent (base polymer) are blocked by specific hydrolyzable silyl groups, it is possible to manufacture a lactic-acid-ester-type room-temperature-curable organopolysiloxane composition excellent in all characteristics including curability, adhesive properties, workability, and the like that were not attainable by the conventional lactic-acid-ester-type room-temperature curable (RTV) silicone rubber composition.
Room-temperature-curable organopolysiloxane composition, structure, and method for assessing cured state of said composition
A room-temperature-curable organopolysiloxane composition; a structure obtained from the composition; and a method for assessing the cured state of the composition are provided. The room-temperature-curable organopolysiloxane composition, which changes in color with the progress of curing from the uncured state, comprises the following ingredients: (A) 100 parts by mass of one or more organopolysiloxanes represented by formula (1)
HO(SiR.sub.2O).sub.nH (1)
and/or formula (2) ##STR00001##
(with variables as defined herein); (B) 0.1-50 parts by mass of an organosilicon compound having at least three silicon-atom-bonded hydrolyzable groups in the molecule, which is not any of ingredients (A), (C), and (D), and/or a product of the partial hydrolytic condensation of the organosilicon compound; (C) 0.01-20 parts by mass of a curing catalyst; (D) 0.1-10 parts by mass of a silane coupling agent; and (E) 0.01-10 parts by mass of a pH indicator.
Room-temperature-curable organopolysiloxane composition, structure, and method for assessing cured state of said composition
A room-temperature-curable organopolysiloxane composition; a structure obtained from the composition; and a method for assessing the cured state of the composition are provided. The room-temperature-curable organopolysiloxane composition, which changes in color with the progress of curing from the uncured state, comprises the following ingredients: (A) 100 parts by mass of one or more organopolysiloxanes represented by formula (1)
HO(SiR.sub.2O).sub.nH (1)
and/or formula (2) ##STR00001##
(with variables as defined herein); (B) 0.1-50 parts by mass of an organosilicon compound having at least three silicon-atom-bonded hydrolyzable groups in the molecule, which is not any of ingredients (A), (C), and (D), and/or a product of the partial hydrolytic condensation of the organosilicon compound; (C) 0.01-20 parts by mass of a curing catalyst; (D) 0.1-10 parts by mass of a silane coupling agent; and (E) 0.01-10 parts by mass of a pH indicator.
Functional initiator for anionic polymerization
An ethylenically unsaturated polymer includes at a terminus the radical of an allylic compound that includes a functional group free of active hydrogen atoms that is bonded to the allylic C atom through a S, P, Si or Sn atom and a vinyl aromatic compound. The polymer can be used as a component of a variety of elastomeric compounds used in the production of vulcanizates.
Functional initiator for anionic polymerization
An ethylenically unsaturated polymer includes at a terminus the radical of an allylic compound that includes a functional group free of active hydrogen atoms that is bonded to the allylic C atom through a S, P, Si or Sn atom and a vinyl aromatic compound. The polymer can be used as a component of a variety of elastomeric compounds used in the production of vulcanizates.
Process and catalyst for hydrogen mediated saline hydride initiated anionic chain transfer polymerization
This invention relates to processes for forming hydrogen mediated saline hydride initiated anionic polystyrene distributions via novel polymerization conditions. This invention also relates to novel hydrocarbon soluble super active saline hydride catalyst and reagent compositions useful in conducting the hydrogen mediated saline hydride initiated polymerizations of this invention. This invention also relates to novel low molecular weight polystyrene polymer composition formed exclusively from styrene and molecular hydrogen as the monomers.
Process and catalyst for hydrogen mediated saline hydride initiated anionic chain transfer polymerization
This invention relates to processes for forming hydrogen mediated saline hydride initiated anionic polystyrene distributions via novel polymerization conditions. This invention also relates to novel hydrocarbon soluble super active saline hydride catalyst and reagent compositions useful in conducting the hydrogen mediated saline hydride initiated polymerizations of this invention. This invention also relates to novel low molecular weight polystyrene polymer composition formed exclusively from styrene and molecular hydrogen as the monomers.
Curable silicone rubber composition
The present disclosure provides a curable silicone rubber composition containing 0.1 to 15 mass % of a biuret compound represented by the general formula: ##STR00001##
wherein R.sup.1 represents the same or different alkyl groups having 1 to 6 carbons, R.sup.2 represents the same or different alkyl groups having 1 to 3 carbons, R.sup.3 represents the same or different alkylene groups having 2 to 6 carbons, and “a” represents the same or different integers of from 0 to 2. The curable silicone rubber composition may be cured by a condensation reaction, an addition reaction, or the like. The curable silicone rubber composition generally has good adhesion to plastics, metals, and the like.
Curable silicone rubber composition
The present disclosure provides a curable silicone rubber composition containing 0.1 to 15 mass % of a biuret compound represented by the general formula: ##STR00001##
wherein R.sup.1 represents the same or different alkyl groups having 1 to 6 carbons, R.sup.2 represents the same or different alkyl groups having 1 to 3 carbons, R.sup.3 represents the same or different alkylene groups having 2 to 6 carbons, and “a” represents the same or different integers of from 0 to 2. The curable silicone rubber composition may be cured by a condensation reaction, an addition reaction, or the like. The curable silicone rubber composition generally has good adhesion to plastics, metals, and the like.
MOLDING RESIN COMPOSITION AND MOLDED ARTICLE
The present invention aims to provide a resin composition for molding that makes it possible to achieve excellent continuous productivity and to produce a molded article having high surface smoothness, capable of reducing defective molding, less likely to crack during use, and also having excellent shock resistance. The present invention also aims to provide a molded article including the resin composition for molding. Provided is a resin composition for molding, containing: a chlorinated polyvinyl chloride resin; and a melt additive, the resin composition containing three components including a A.sub.100 component, a B.sub.100 component, and a C.sub.100 component, and having a percentage of the C.sub.100 component [C.sub.100 component/(A.sub.100 component+B.sub.100 component+C.sub.100 component)] of 30% or less, the three components being identified by measuring the resin composition by a solid echo method using pulse NMR at 100° C. to give a free induction decay curve of .sup.1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into three curves derived from the A.sub.100 component, the B.sub.100 component, and the C.sub.100 component in order of shorter relaxation time using the least square method.