The invention relates to cellulose esters, the ester groups of which are at least partially containing phosphorus and are based on unsaturated carboxylic acids and reactive phosphorus components, wherein the latter are preferably phosphorus derivatives of sugar alcohols or of tartaric acid derivatives. The invention also relates to methods for preparing novel phosphorus-containing cellulose esters and to their use as flame retardants for plastics.

A ply fibrous product comprises at least one ply selected from a nonwoven ply and a tissue paper ply, wherein the at least one ply selected from a nonwoven ply and a tissue paper ply comprises cellulosic fibers comprising an organic polycarboxylic acid and wherein the organic polycarboxylic acid has at least one carboxyl group covalently bound to the cellulosic fibers and at least one free carboxyl group. Due to the presence of covalent chemical bonds between a carboxyl group of the polycarboxylic acid and hydroxy groups of the cellulosic fibers present in all substrates, the ply fibrous products display a long-lasting acidic pH even after having been rinsed with water. In some embodiments a long-lasting acidic pH may be achieved in the nonwovens treated with an organic polycarboxylic acid even after washing with a washing detergent.

An electromagnetic shielding laminated sheet includes: an electromagnetic wave absorbing layer which includes a matrix and carbon nanotubes dispersed in the matrix and which has a bulk density equal to or less than 997 kg/m.sup.3; and a metal layer laid on top of the electromagnetic wave absorbing layer.

An electromagnetic shielding laminated sheet includes: an electromagnetic wave absorbing layer which includes a matrix and carbon nanotubes dispersed in the matrix and which has a bulk density equal to or less than 997 kg/m.sup.3; and a metal layer laid on top of the electromagnetic wave absorbing layer.

A fibrous cellulose having an excellent resin reinforcing effect, a method for manufacturing the fibrous cellulose, and a resin composition having high strength. The fibrous cellulose is microfiber cellulose having an average fiber diameter of 1 μm or more, and is hydrophobically modified. The method for manufacturing fibrous cellulose includes defibrating raw material fiber to obtain microfiber cellulose with an average fiber diameter of 1 μm or more, and hydrophobically modifying the microfiber cellulose. Further, the resin composition contains the fibrous cellulose and resin.

A fibrous cellulose having an excellent resin reinforcing effect, a method for manufacturing the fibrous cellulose, and a resin composition having high strength. The fibrous cellulose is microfiber cellulose having an average fiber diameter of 1 μm or more, and is hydrophobically modified. The method for manufacturing fibrous cellulose includes defibrating raw material fiber to obtain microfiber cellulose with an average fiber diameter of 1 μm or more, and hydrophobically modifying the microfiber cellulose. Further, the resin composition contains the fibrous cellulose and resin.

A biopolymer film is provided that comprises a combination of crystalline nano cellulose (CNC)/esterified crystalline nano cellulose (ECNC) reinforced with chitosan. The two polymer components can be present in any ratio, but an approximate CNC to ECNC 70:30 ratio is preferred. The chitosan component is derived from exoskeletons of crustaceans. Also provided are methods of preparing biopolymer film and preparing food packaging components from said biopolymer film. The CNC/ECNC mixture is dissolved in an ethanol solution and the chitin is dissolved in acetic acid and mixed together to form a polymer blend.

A biopolymer film is provided that comprises a combination of crystalline nano cellulose (CNC)/esterified crystalline nano cellulose (ECNC) reinforced with chitosan. The two polymer components can be present in any ratio, but an approximate CNC to ECNC 70:30 ratio is preferred. The chitosan component is derived from exoskeletons of crustaceans. Also provided are methods of preparing biopolymer film and preparing food packaging components from said biopolymer film. The CNC/ECNC mixture is dissolved in an ethanol solution and the chitin is dissolved in acetic acid and mixed together to form a polymer blend.

A biopolymer film is provided that comprises a combination of crystalline nano cellulose (CNC)/esterified crystalline nano cellulose (ECNC) reinforced with chitosan. The two polymer components can be present in any ratio, but an approximate CNC to ECNC 70:30 ratio is preferred. The chitosan component is derived from exoskeletons of crustaceans. Also provided are methods of preparing biopolymer film and preparing food packaging components from said biopolymer film. The CNC/ECNC mixture is dissolved in an ethanol solution and the chitin is dissolved in acetic acid and mixed together to form a polymer blend.

Disclosed herein is a degradable cellulose ester. The cellulose ester may be formed into tow for use in cigarette filters or into articles, such as molded articles. A basic material, an enzymatic material, or combinations thereof is included in the cellulose ester in order to degrade the cellulose ester.