A composite plate is mainly made from the following raw materials in percentage by weight: 35% to 45% of calcium carbonate, 45% to 55% of cullet, 5% to 15% of unsaturated polyester resin, 0.1% to 1% of a curing agent, 0.1% to 1% of an auxiliary agent, wherein a ratio of an amount of the calcium carbonate to an amount of the cullet is 0.75%. The invention employs cullet, calcium carbonate, and resin as the main raw materials to prepare an artificial stone plate; no natural quartz is used, and hence the raw material cost is low. A reasonable ratio of cullet to calcium carbonate reduces the use of resin, which further reduces the raw material cost. Through a reasonable combination of different raw materials, the composite plate of the invention has physical and chemical properties and decorative abilities that are similar to those of traditional artificial quartz stone.

A method of forming a three-dimensional body from a mixture, wherein the mixture can comprise dispersed solid polymeric particles and a curable binder. In a particular embodiment the solid polymeric particles can be fluoropolymeric particles. The method can include at least partial removal of the cured binder and sintering, to obtain a sintered polymeric three-dimensional body. In one embodiment, the sintered three-dimensional body can be PTFE.

A method of forming a three-dimensional body from a mixture, wherein the mixture can comprise dispersed solid polymeric particles and a curable binder. In a particular embodiment the solid polymeric particles can be fluoropolymeric particles. The method can include at least partial removal of the cured binder and sintering, to obtain a sintered polymeric three-dimensional body. In one embodiment, the sintered three-dimensional body can be PTFE.

The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a pre-polymer, which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polymer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.

The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a pre-polymer, which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polymer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.

The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a pre-polymer, which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polymer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.

A novel photocurable resin composition including: a polymer with a weight average molecular weight of 1,000 to 50,000, the polymer having a structural unit of formula (1), and having a structure of formula (2) at an end: wherein X is a C.sub.1-6 alkyl group, vinyl group, allyl group, or glycidyl group; m and n are each independently 0 or 1; Q is a divalent hydrocarbon group having a carbon atom number of 1 to 16; Z is a divalent linking group having a carbon atom number of 1 to 4, wherein the divalent linking group is attached to the O group in formula (1); and R.sup.1 is a hydrogen atom or methyl group; a radical photopolymerization initiator; and a solvent. ##STR00001##

A novel photocurable resin composition including: a polymer with a weight average molecular weight of 1,000 to 50,000, the polymer having a structural unit of formula (1), and having a structure of formula (2) at an end: wherein X is a C.sub.1-6 alkyl group, vinyl group, allyl group, or glycidyl group; m and n are each independently 0 or 1; Q is a divalent hydrocarbon group having a carbon atom number of 1 to 16; Z is a divalent linking group having a carbon atom number of 1 to 4, wherein the divalent linking group is attached to the O group in formula (1); and R.sup.1 is a hydrogen atom or methyl group; a radical photopolymerization initiator; and a solvent. ##STR00001##

A radical-curable adhesive composition comprising a rubber (a) having one or more (meth)acryloyl groups within a single molecular chain thereof, a polymerizable monomer (b) having both an epoxy group and a (meth)acryloyloxy group in a molecule thereof, a radical polymerization initiator (c) and an acicular filler (d) having a fiber length of 500 to 2000 m and an aspect ratio of 5 to 300.

A radical-curable adhesive composition comprising a rubber (a) having one or more (meth)acryloyl groups within a single molecular chain thereof, a polymerizable monomer (b) having both an epoxy group and a (meth)acryloyloxy group in a molecule thereof, a radical polymerization initiator (c) and an acicular filler (d) having a fiber length of 500 to 2000 m and an aspect ratio of 5 to 300.