A black-color polymer composite film comprising a phthalocyanine compound dispersed in a polymer selected from the group consisting of polyimide, polyamide, polyoxadiazole, polybenzoxazole, polybenzobisoxazole, polythiazole, polybenzothiazole, polybenzobisthiazole, poly(p-phenylene vinylene), polybenzimidazole, polybenzobisimidazole, and combinations thereof, wherein the phthalocyanine compound occupies a weight fraction of 0.1% to 50% based on the total polymer composite weight. Preferably, the phthalocyanine compound is selected from copper phthalocyanine, zinc phthalocyanine, tin phthalocyanine, iron phthalocyanine, lead phthalocyanine, nickel phthalocyanine, vanadyl phthalocyanine, fluorochromium phthalocyanine, magnesium phthalocyanine, manganous phthalocyanine, dilithium phthalocyanine, aluminum phthalocyanine chloride, cadmium phthalocyanine, chlorogallium phthalocyanine, cobalt phthalocyanine, silver phthalocyanine, a metal-free phthalocyanine, or a combination thereof.

The present invention relates to a process for preparing a resin composition comprising benzoxazine, a prepreg and a laminate prepared therefrom. Said resin composition comprising benzoxazine is prepared by adding an acidic filler into the resin composition comprising benzoxazine, wherein said resin composition comprising benzoxazine comprises a benzoxazine resin, an epoxy resin A1 having an epoxy equivalent of 150-450, and an epoxy resin A2 having an epoxy equivalent of 451-1000. By adding an acidic filler into the resin composition, the present invention promotes the polymerization of benzoxazine and epoxy resins, and decreases the curing temperature needed for the polymerization of benzoxazine and epoxy resins. The laminates prepared from the resin composition added with an acidic filler have a high anti-stripping stability, a high glass transition temperature, a low water absorption, a high heat resistance, a high bending strength and a better processability, and achieves a low coefficient of thermal expansion.

The present invention relates to a process for preparing a resin composition comprising benzoxazine, a prepreg and a laminate prepared therefrom. Said resin composition comprising benzoxazine is prepared by adding an acidic filler into the resin composition comprising benzoxazine, wherein said resin composition comprising benzoxazine comprises a benzoxazine resin, an epoxy resin A1 having an epoxy equivalent of 150-450, and an epoxy resin A2 having an epoxy equivalent of 451-1000. By adding an acidic filler into the resin composition, the present invention promotes the polymerization of benzoxazine and epoxy resins, and decreases the curing temperature needed for the polymerization of benzoxazine and epoxy resins. The laminates prepared from the resin composition added with an acidic filler have a high anti-stripping stability, a high glass transition temperature, a low water absorption, a high heat resistance, a high bending strength and a better processability, and achieves a low coefficient of thermal expansion.

Compositions for additive manufacturing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed or formed from the compositions. The compositions may also impart desirable mechanical properties to the articles. In some embodiments, a composition comprises a sinterable powder or a thermoplastic polymer in an amount of 10-99 wt. %, based on the total weight of the composition, and an oxygen-deprivation additive in an amount of up to 25 wt. %, up to 15 wt. %, or up to 10 wt. % based on the total weight of the composition. The oxygen-deprivation additive comprises at least one of (a) an organophosphorus component, (b) a heptazine or melamine-derived component, and (c) a polymeric organobromine component.

Compositions for additive manufacturing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed or formed from the compositions. The compositions may also impart desirable mechanical properties to the articles. In some embodiments, a composition comprises a sinterable powder or a thermoplastic polymer in an amount of 10-99 wt. %, based on the total weight of the composition, and an oxygen-deprivation additive in an amount of up to 25 wt. %, up to 15 wt. %, or up to 10 wt. % based on the total weight of the composition. The oxygen-deprivation additive comprises at least one of (a) an organophosphorus component, (b) a heptazine or melamine-derived component, and (c) a polymeric organobromine component.

An optical member includes a laminated body configured to reduce light reflection disposed on a substrate, wherein a surface of the laminated body is a porous layer or a layer having a textured structure, and at least one layer of the laminated body is a polymer layer containing a linear polymer and a branched polymer. A method for manufacturing the optical member is also provided. The branched polymer content is 10% by weight or more and 90% by weight or less of the total weight of the linear polymer and the branched polymer. The layer having a textured structure contains crystals mainly composed of aluminum oxide.

An optical member includes a laminated body configured to reduce light reflection disposed on a substrate, wherein a surface of the laminated body is a porous layer or a layer having a textured structure, and at least one layer of the laminated body is a polymer layer containing a linear polymer and a branched polymer. A method for manufacturing the optical member is also provided. The branched polymer content is 10% by weight or more and 90% by weight or less of the total weight of the linear polymer and the branched polymer. The layer having a textured structure contains crystals mainly composed of aluminum oxide.

A production method for a fiber-reinforced composite material comprises: a step of stacking a prepreg plurally to obtain a prepreg-stacked body; and a step of heating the prepreg-stacked body to cure a resin, wherein the prepreg comprises: a reinforcing fiber layer including reinforcing fibers and a resin composition with which the space between fibers of the reinforcing fibers is impregnated and which contains (A) a benzoxazine resin, (B) an epoxy resin, and (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule; and a surface layer provided on at least one surface of the reinforcing fiber layer and containing (A) to (C) components, and (D) polyamide resin particles having an average particle size of 5 to 50 m.

A production method for a fiber-reinforced composite material comprises: a step of stacking a prepreg plurally to obtain a prepreg-stacked body; and a step of heating the prepreg-stacked body to cure a resin, wherein the prepreg comprises: a reinforcing fiber layer including reinforcing fibers and a resin composition with which the space between fibers of the reinforcing fibers is impregnated and which contains (A) a benzoxazine resin, (B) an epoxy resin, and (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule; and a surface layer provided on at least one surface of the reinforcing fiber layer and containing (A) to (C) components, and (D) polyamide resin particles having an average particle size of 5 to 50 m.

The present invention discloses a method for preparing graphene-polyamide nanocomposite fiber. The method includes the following steps of: mixing polyamide chips with graphene or modified graphene, and then extruding and palletizing to obtain graphene-polyamide masterbatch; melt-spinning the graphene-polyamide masterbatch after drying the same, to prepare the graphene-polyamide nanocomposite fiber. Compared with the existing industrial polyamide composite fiber, the method of the present invention has the advantages of simple process and low cost, and can effectively improve the production efficiency and capacity; the modified graphene has such an excellent compatibility with the matrix that it can be uniformly dispersed in the matrix, so that the graphene reinforced phase is perfectly compounded with the polyamide matrix material, thereby greatly improving the performance of graphene-polyamide nanocomposite fiber.