A crystalline titanium and magnesium compound having an X-ray diffraction pattern having interplanar spacing (d-spacing) values at about 5.94, 3.10, 2.97, 2.10, 1.98, 1.82, and 1.74±0.1 angstroms may be used in protective coatings for metal or metal alloy substrates. The coatings exhibit excellent corrosion resistances and provide corrosion protection equal to or better than typical non-chromate coatings.

A crystalline titanium and magnesium compound having an X-ray diffraction pattern having interplanar spacing (d-spacing) values at about 5.94, 3.10, 2.97, 2.10, 1.98, 1.82, and 1.74±0.1 angstroms may be used in protective coatings for metal or metal alloy substrates. The coatings exhibit excellent corrosion resistances and provide corrosion protection equal to or better than typical non-chromate coatings.

Provided is a metal-particle dispersion composition as a composition containing dispersed metal particles and being suitable for use in aqueous coating compositions, etc., the metal-particle dispersion composition comprising 10-80 mass % metal particles, 0.01-10 mass % organic titanate compound in a chelate form, 1-40 mass % water, and 2-30 mass % organic solvent having a higher boiling point than water, the amounts being based on the whole composition, wherein the organic titanate compound is an organic compound represented by Ti(OR).sub.4 (the OR groups include at least one chelatable substituent based on triethanolamine) and the organic solvent having a higher boiling point than water is a C.sub.7 or lower alcohol compound.

Provided is a metal-particle dispersion composition as a composition containing dispersed metal particles and being suitable for use in aqueous coating compositions, etc., the metal-particle dispersion composition comprising 10-80 mass % metal particles, 0.01-10 mass % organic titanate compound in a chelate form, 1-40 mass % water, and 2-30 mass % organic solvent having a higher boiling point than water, the amounts being based on the whole composition, wherein the organic titanate compound is an organic compound represented by Ti(OR).sub.4 (the OR groups include at least one chelatable substituent based on triethanolamine) and the organic solvent having a higher boiling point than water is a C.sub.7 or lower alcohol compound.

Disclosed is a corrosion inhibition coating, comprising: a base comprising a silicate matrix, wherein aluminum, an aluminum alloy, or a combination thereof, is present within the silicate matrix; and an inhibitor comprising: zinc molybdate, cerium citrate, magnesium metasilicate, a metal phosphate silicate, or a combination thereof, wherein a curing temperature of the corrosion inhibition coating is about 20° C. to about 190° C., preferably about 20° C. to about 120° C. Also disclosed is a substrate coated with the corrosion inhibition coating, wherein the substrate is a peened part.

A coating composition having an inorganic binder, metallic pigments, a filler, and functionalised graphene for at least partially replacing a proportion of the metallic pigments in the coating composition is disclosed.

A graphene-based zinc containing coating is provided to prevent or slow down the corrosion of steel. The graphene-based materials are selected from a group of modified single-layer graphene, double-layer graphene, few layer graphene, graphene nanoplatelet, doped graphene, and a combination thereof. The modified graphene-based materials in zinc-containing paints or coatings act as a barrier to prevent or slow down the diffusion of corrosive species to the steel surface to be protected. For such a purpose, the graphene has a high aspect ratio and good structural integrity, especially a lack of defects on the basal plane of the graphene.

Disclosed are a protective coating layer, and a preparation method and use thereof. The present application provides a protective coating layer, including: a rusty-surface liquid layer, a nano-zinc yellow epoxy primer layer, a nano-epoxy micaceous iron oxide (MIO) intermediate coating layer, and a nano-fluorocarbon top coating layer, where the rusty-surface liquid layer is applied on a metal substrate; the nano-zinc yellow epoxy primer layer is applied on a surface of the rusty-surface liquid layer; the nano-epoxy MIO intermediate coating layer is applied on a surface of the nano-zinc yellow epoxy primer layer; and the nano-fluorocarbon top coating layer is applied on a surface of the nano-epoxy MIO intermediate coating layer. The present application effectively solves the technical problem that the existing protective coating layer with nanoparticles exhibits poor adhesion to a substrate and cannot provide a protective effect for a long time.

Provided is a solution composition for steel sheet surface treatment, comprising 30 wt % to 60 wt % of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B); 0.2 wt % to 0.4 wt % of a rust-inhibiting and corrosion-resisting agent; 0.1 wt % to 0.3 wt % of a molybdenum-based compound; 5 wt % to 10 wt % of a water-soluble cationic urethane resin; 0.5 wt % to 2.0 wt % of a silane coupling agent; and 27.3 wt % to 64.2 wt % of water, a zinc-based plated steel sheet surface-treated with the same, and a manufacturing method therefor, the zinc-based plated steel sheet surface-treated with the solution composition for steel sheet surface treatment containing trivalent chromium may have an excellent effect on corrosion resistance, blackening resistance, fingerprint resistance, oil resistance, and alkali resistance.

Provided is a solution composition for steel sheet surface treatment, comprising 30 wt % to 60 wt % of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B); 0.2 wt % to 0.4 wt % of a rust-inhibiting and corrosion-resisting agent; 0.1 wt % to 0.3 wt % of a molybdenum-based compound; 5 wt % to 10 wt % of a water-soluble cationic urethane resin; 0.5 wt % to 2.0 wt % of a silane coupling agent; and 27.3 wt % to 64.2 wt % of water, a zinc-based plated steel sheet surface-treated with the same, and a manufacturing method therefor, the zinc-based plated steel sheet surface-treated with the solution composition for steel sheet surface treatment containing trivalent chromium may have an excellent effect on corrosion resistance, blackening resistance, fingerprint resistance, oil resistance, and alkali resistance.