The invention relates to aqueous polyurethane dispersions that are curable with UV radiation. The polyurethanes are chain-extended with aromatic, cycloaliphatic or aliphatic diamine compound and cross-linked with aliphatic triamine compound. The polyurethanes are useful dispersions for coating various substrates. The use of the invented dispersions results in high hardness, very good flexibility and good chemical resistance in both clear coats and pigmented coatings before and after UV curing combined with very good adhesion to different substrates.

A two-component polyurethane composition includes a first component, including at least one polybutadiene polyol P1 having an average molecular weight of 2,000 to 10,000 g/mol and an average OH functionality of 2.1 to 4, and a second component, including at least one polyisocyanate and optionally at least one isocyanate-terminated polyurethane prepolymer. The composition also contains at least one hydrophobic diol P2 having an average molecular weight of 500 to 5,000 g/mol, selected from polybutadiene diols, polyester diols, polycarbonate diols, polyether diols having a repeat unit having at least 4 C atoms, and/or at least one hydrophobic compound P3, which is terminated with amino groups and has an average molecular weight in the range of 200 to 2,000 g/mol. The ratio of the number of hydroxyl groups from P1 to the number of hydroxyl and primary and secondary amino groups from P2 and P3 is 2:1 to 16:1.

The present invention is to provide a hard coating layered optical film, comprising a poly(methylmethacrylate) (PMMA) base film and a hard coating layer thereon. The hard coating layer comprises a (meth)acrylate composition and an initiator, wherein the (meth)acrylate composition comprises a urethane (meth)acrylate oligomer of functionalities from 6 to 15, at least one (meth)acrylate monomer of functionalities from 3 to 6 and at least one (meth)acrylate monomer of functionalities less than 3, wherein the molecular weight of the (meth)urethane acrylate oligomer of functionalities from 6 to 15 is ranging between 1,000 to 4,500. The hard coating layer of the hard coating layered optical film can be further coated with a functional layer, such as a low reflection layer to form an anti-reflection hard coating layered optical film. The hard coating layer can optionally comprise micro-particles to generate an anti-glare hard coating film. The anti-glare hard coating film can be further coated with a functional layer, such as a low reflection layer to form an anti-reflection anti-glare hard coating layered optical film.

The present invention is to provide a hard coating layered optical film, comprising a poly(methylmethacrylate) (PMMA) base film and a hard coating layer thereon. The hard coating layer comprises a (meth)acrylate composition and an initiator, wherein the (meth)acrylate composition comprises a urethane (meth)acrylate oligomer of functionalities from 6 to 15, at least one (meth)acrylate monomer of functionalities from 3 to 6 and at least one (meth)acrylate monomer of functionalities less than 3, wherein the molecular weight of the (meth)urethane acrylate oligomer of functionalities from 6 to 15 is ranging between 1,000 to 4,500. The hard coating layer of the hard coating layered optical film can be further coated with a functional layer, such as a low reflection layer to form an anti-reflection hard coating layered optical film. The hard coating layer can optionally comprise micro-particles to generate an anti-glare hard coating film. The anti-glare hard coating film can be further coated with a functional layer, such as a low reflection layer to form an anti-reflection anti-glare hard coating layered optical film.

The invention is to provide an anti-reflective film. The anti-reflective film comprises a substrate, a hard coating layer disposed on the substrate and a low refractive layer disposed on the hard coating layer. The low refractive layer comprises a (meth)acrylate resin, hollow silica nanoparticles, an initiator and a leveling agent. Wherein the leveling agent comprises a (meth)acrylic-modified organosilicone compound having a perfluoropolyether group. The reflectivity of the anti-reflective film of the present invention is in the range of 1.2% to 1.4%.

The invention is to provide an anti-reflective film. The anti-reflective film comprises a substrate, a hard coating layer disposed on the substrate and a low refractive layer disposed on the hard coating layer. The low refractive layer comprises a (meth)acrylate resin, hollow silica nanoparticles, an initiator and a leveling agent. Wherein the leveling agent comprises a (meth)acrylic-modified organosilicone compound having a perfluoropolyether group. The reflectivity of the anti-reflective film of the present invention is in the range of 1.2% to 1.4%.

A curable coating for a substrate is disclosed that includes a curable resin containing at least one polyester urethane acrylate and monomers, a cure system and diamond particles. Methods of making the curable coatings and methods of making a coated flooring material are also included.

The present invention relates to an aqueous coating composition comprising polyurethane A and vinyl polymer, wherein the polyurethane A comprises as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1.

The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least one cyclic group, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has 5 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.

A two-component polyurethane composition made of a polyol component and a polyisocyanate component, wherein the polyol component includes at least one reaction product of castor oil with ketone resins A1, at least one aliphatic triol A2, an aliphatic diol A3, and a polybutadiene polyol A4. The polyurethane composition has high strength and only a minor dependence of mechanical properties, especially of strength, on temperature, especially in the range from 60 C. to +60 C. Moreover, the composition is capable of curing without blistering under ambient conditions, even in the presence of substrates that typically promote foaming reactions owing to the presence of residual moisture, for example glass fiber weave.