The hot melt adhesive composition includes from 1% by weight to less than 10% by weight total polymer content, of which less than 10% by weight, based on the hot melt adhesive composition, is a single site-catalyzed propylene polymer selected from the group consisting of a single site-catalyzed propylene homopolymer, a single site-catalyzed propylene/alpha-olefin copolymer, and combinations thereof, liquid plasticizer, and at least 45% by weight of a hydrocarbon tackifying agent having a softening point greater than 90° C.

The hot melt adhesive composition includes from 1% by weight to less than 10% by weight total polymer content, of which less than 10% by weight, based on the hot melt adhesive composition, is a single site-catalyzed propylene polymer selected from the group consisting of a single site-catalyzed propylene homopolymer, a single site-catalyzed propylene/alpha-olefin copolymer, and combinations thereof, liquid plasticizer, and at least 45% by weight of a hydrocarbon tackifying agent having a softening point greater than 90° C.

The inventors have discovered hot melt adhesive compositions that can be formulated to have a high percentage of environmentally conscious components and still provide performance over a broad temperature range.

The invention features a hot melt adhesive composition including from 5% by weight to 50% by weight of a styrene block copolymer, from 15% by weight to 75% by weight of a bio-based tackifying agent, and from 5% by weight to 40% by weight of an aliphatic plasticizer having a cyclo-aliphatic content of no greater than 1% by weight as tested by .sup.1H-NMR Spectroscopy, wherein said hot melt adhesive composition has an environmentally conscious component content of at least 50% by weight.

The inventors have discovered hot melt adhesive compositions that can be formulated to have a high percentage of environmentally conscious components and still provide performance over a broad temperature range.

The invention features a hot melt adhesive composition including from 5% by weight to 50% by weight of a styrene block copolymer, from 15% by weight to 75% by weight of a bio-based tackifying agent, and from 5% by weight to 40% by weight of an aliphatic plasticizer having a cyclo-aliphatic content of no greater than 1% by weight as tested by .sup.1H-NMR Spectroscopy, wherein said hot melt adhesive composition has an environmentally conscious component content of at least 50% by weight.

Disclosed herein are hard coat compositions and composite films including a thermoplastic polyurethane. A hard coat composition includes a thermoplastic polyurethane having a hard segment content of 80 percent by weight or greater. The thermoplastic polyurethane is a reaction product of a) a diisocyanate; b) a polyol optionally comprising a cyclic structure; and c) a chain extender. At least one of the polyol or the chain extender comprises at least one side chain and at least one of the diisocyanate or the chain extender comprises a cyclic structure. A composite film includes 1) a hard coat layer having opposing first and second major surfaces; and 2) a second layer disposed on at least a portion of the hard coat layer. These materials can serve decorative and/or protective functions while displaying both good elongation at moderate temperatures and high hardness.

Disclosed herein are hard coat compositions and composite films including a thermoplastic polyurethane. A hard coat composition includes a thermoplastic polyurethane having a hard segment content of 80 percent by weight or greater. The thermoplastic polyurethane is a reaction product of a) a diisocyanate; b) a polyol optionally comprising a cyclic structure; and c) a chain extender. At least one of the polyol or the chain extender comprises at least one side chain and at least one of the diisocyanate or the chain extender comprises a cyclic structure. A composite film includes 1) a hard coat layer having opposing first and second major surfaces; and 2) a second layer disposed on at least a portion of the hard coat layer. These materials can serve decorative and/or protective functions while displaying both good elongation at moderate temperatures and high hardness.

Provided herein are films comprising a core layer sandwiched between an outer layer and a scaling layer. The film has a seal initiation temperature at 5 N/15 mm between about 82° C. and about 88° C., a 1% secant modulus m MD between about 300 MPa and about 400 MPa, and plateau seal strength at between about 16 and about 17 N/15 mm. While the outer layer and core layers comprise polyethylene compositions, the sealing layer comprises a polyethylene blend. The polyethylene blend comprises a plastomer and a polyethylene composition in an amount equal to or less than 50 wt %.

Provided are methods and systems for dispensing filament adhesive onto a target substrate. A filament adhesive is applied on a target substrate according to a bead application plan, then the applied bead is checked against performance criteria. A second bead application plan is generated, and subsequent filament bead applied according to the second bead application plan.

Provided are methods and systems for dispensing filament adhesive onto a target substrate. A filament adhesive is applied on a target substrate according to a bead application plan, then the applied bead is checked against performance criteria. A second bead application plan is generated, and subsequent filament bead applied according to the second bead application plan.

An object of the present invention is to provide a laminated sheet for a metal-clad laminate and a method of manufacturing the same, the laminated sheet including: a substrate that includes a liquid crystal polymer or a fluoropolymer; and an adhesive layer, in which adhesiveness with a metal layer formed on the adhesive layer is excellent. Another object of the present invention is to provide a metal-clad laminate and a method of manufacturing the same.

A laminated sheet for a metal-clad laminate includes: a substrate that includes a liquid crystal polymer or a fluoropolymer; an inorganic oxide layer; and an adhesive layer, in which the substrate, the inorganic oxide layer, and the adhesive layer are laminated in this order.