The present disclosure is directed to surfactants (in particular olefin sulfonates), surfactant packages, compositions derived thereof, and uses thereof in hydrocarbon recovery. Methods of making olefin sulfonate surfactants are also described.

An inhibition corrosion package for use with an acidic composition, where the package comprises a terpene component; a propargyl alcohol or derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are acidic compositions combining the corrosion inhibition package according to a preferred embodiment of the present invention for use in various industrial operations including but not limited to oil and gas operations. Also disclosed are methods of use of such compositions.

Compositions and methods for use in fracturing treatments using friction reducing additives that include nanoparticles are provided. In some embodiments, the methods include: providing a treatment fluid that includes an aqueous base fluid and a friction reducing additive, the friction reducing additive including at least one polymer and a plurality of nanoparticles; and introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

The present disclosure is directed to surfactants (in particular olefin sulfonates), surfactant packages, compositions derived thereof, and uses thereof in hydrocarbon recovery. Methods of making olefin sulfonate surfactants are also described.

A fluid for use in hydraulic fracturing contains underivatized guar or a guar gum derivative as viscosifying or gelling polymer, a crosslinking agent, carbon dioxide as foaming agent and urea and, optionally, a bifunctional organic compound containing at least one hydroxyl group and at least one quaternary group and, optionally, a non-gaseous foaming agent. The fluid may be characterized by a low pH such as a pH than or equal to 3.0 and less than or equal to 5.0.

Some reservoirs have tight oil formations, such as the Changqing reservoir. The surfactant polymer flooding and low tension gas flooding are two potential chemical flooding methods for use in tight oil formations. In these methods, an oil displacement agent, or surfactant, is added. Nonionic surfactants with extended chains (by propylene oxide and ethylene oxide) from dialkyl alcohols or dialkyl amines were tested. A synergistic blend of surfactants was developed between the nonionic surfactants and anionic surfactants that lowers interfacial tension and improves surfactant solubility in water and oil.

A non-linear surfactant, and particularly a non-linear surfactant comprising bi-functionalized molecules or particles having both hydrophobic and hydrophilic groups. The non-linear surfactant includes a nanoparticle template of a rigid molecular structure, wherein the nanoparticle comprises a molecule or a particle that is bi-functionalized with both hydrophilic and hydrophobic groups to obtain an amphiphilic nanoparticle. The template nanoparticle can be used as a surfactant, wetting agent, emulsifier, detergent or other surface active agents or for the preparation of nanoemulsions or dispersions. The non-linear surfactant can provide smaller particle sizes for emulsion suspensions and foams.

Methods for delivering treatment chemicals into a subterranean formation using treatment fluids that include nanoemulsions are provided. In some embodiments, the methods include providing a treatment fluid including an aqueous base fluid and a nanoemulsion including a water-soluble internal phase, a water-soluble external phase, and a surfactant, the nanoemulsion being formed by mechanically-induced shear rupturing; and introducing the treatment fluid into at least a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.

A method for the fracking or stimulation of a hydrocarbon-bearing formation, said method comprising the steps of: providing a wellbore in need of stimulation; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and a spearhead or breakdown acid into the wellbore; positioning the tool at said predetermined location; perforating the wellbore with the tool thereby creating a perforated area; allowing the spearhead acid to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for fracking or stimulation; removing the tool from the wellbore; and initiating the fracking of the perforated area using a fracking fluid. Also disclosed is a corrosion inhibiting composition for use with the acid composition.

A viscoelastic surfactant fluid composition comprising: a surfactant; a counterion; and a modified nanoparticle.