This invention provides processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

A high-efficiency food waste carbonization process using a carbonizer specially designed to function at a specific range of temperatures to work efficiently, with minimal energy input and designed to reduce volume and to produce charcoal that may be used as a fuel. The invention is designed to work with high-moisture materials such as food waste.

A high-efficiency food waste carbonization process using a carbonizer specially designed to function at a specific range of temperatures to work efficiently, with minimal energy input and designed to reduce volume and to produce charcoal that may be used as a fuel. The invention is designed to work with high-moisture materials such as food waste.

Systems of producing hydrogen and biochar from biomass assisted by iron and steel slag extract include: a pretreatment system that the reactants, including the biomass, iron-based catalyst and alkaline reagent, are pretreated and fully mixed at specific ratios in the pretreatment system; thermal reactor that the mixed reactants from the pretreatment device are transferred into and fully reacted in the thermal reactor; a solid residue collector that the solid residue is collected by the solid residue collector at the discharge outlet of the thermal reactor after the reacted mixture is separated; a gas collection system that he generated hydrogen-based gas is collected by the gas collection system from the exhaust port of the thermal reactor.

Systems of producing hydrogen and biochar from biomass assisted by iron and steel slag extract include: a pretreatment system that the reactants, including the biomass, iron-based catalyst and alkaline reagent, are pretreated and fully mixed at specific ratios in the pretreatment system; thermal reactor that the mixed reactants from the pretreatment device are transferred into and fully reacted in the thermal reactor; a solid residue collector that the solid residue is collected by the solid residue collector at the discharge outlet of the thermal reactor after the reacted mixture is separated; a gas collection system that he generated hydrogen-based gas is collected by the gas collection system from the exhaust port of the thermal reactor.

The present invention relates to a novel process for the preparation of low molecular weight aromatic compounds such as benzene, toluene, and xylenes (BTX) from plastics. Provided is a thermo-catalytic pyrolysis process for the preparation of aromatic compounds from a feed stream comprising plastic, comprising the steps of: a) subjecting a feed stream comprising a plastic to a pyrolysis treatment at a pyrolysis temperature in the range of 600-1000° C. to produce pyrolysis vapors; b) optionally cooling the pyrolysis vapors to a temperature that is below the pyrolysis temperature; e) contacting the vaporous phase with an aromatization catalyst at an aromatization temperature in the range of 450 700° C., which aromatization temperature is at least 50° C. lower than the pyrolysis temperature, in a catalytic conversion step to yield a conversion product comprising aromatic compounds; and d) optionally recovering the aromatic compounds from the conversion product.

Systems and methods are provided for integration of a reactor for polyolefin pyrolysis with the effluent processing train for a steam cracker. The polyolefins can correspond to, for example, polyolefins in plastic waste. Integrating a process for polyolefin pyrolysis with a steam cracker processing train can allow a mixture of polymers to be converted to monomer units while reducing or minimizing costs and/or equipment footprint. This can allow for direct conversion of polyolefins to the light olefin monomers in high yield while significantly lowering capital and energy usage due to integration with a steam cracking process train. The integration can be enabled in part by selecting feeds with appropriate mixtures of various polymer types and/or by limiting the volume of the plastic waste pyrolysis product relative to the volume from the steam cracker(s) in the steam cracking process train. By selecting plastic waste and/or other polyolefin sources with an appropriate mixture of polyolefins as the feedstock, the resulting polyolefin pyrolysis product can be separated in a steam cracking process train to produce separate fractions for various polymer grade small olefin products.

A device and process for the conversion of aromatic compounds, includes/uses: a unit for the separation of the xylenes suitable for treating a cut comprising xylenes and ethylbenzene and producing an extract comprising para-xylene and a raffinate; an isomerization unit suitable for treating the raffinate and producing an isomerate enriched in para-xylene which is sent to a fractionation train; a pyrolysis unit suitable for treating biomass, producing a pyrolysis effluent feeding, at least partially, the feedstock, and producing a pyrolysis gas comprising CO and H.sub.2; a Fischer-Tropsch synthesis reaction section suitable for treating, at least in part, the pyrolysis gas, producing a synthesis effluent sent, at least in part, to the pyrolysis unit.

A device and process for the conversion of aromatic compounds, includes/uses: a unit for the separation of the xylenes suitable for treating a cut comprising xylenes and ethylbenzene and producing an extract comprising para-xylene and a raffinate; an isomerization unit suitable for treating the raffinate and producing an isomerate enriched in para-xylene which is sent to a fractionation train; a pyrolysis unit suitable for treating biomass, producing a pyrolysis effluent feeding, at least partially, the feedstock, and producing a pyrolysis gas comprising CO and H.sub.2; a Fischer-Tropsch synthesis reaction section suitable for treating, at least in part, the pyrolysis gas, producing a synthesis effluent sent, at least in part, to the pyrolysis unit.

A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.