Systems and methods for processing waste plastics are provided. One method includes mixing, heating and compacting a supply of the waste plastic based feedstock having an appreciable amount of halide compounds or heteroatoms from one or more sources of contamination; providing an amendment comprising alkaline earth oxides and/or hydroxides, oxides of iron, and/or oxides of aluminum to be mixed, heated and compacted with the waste plastic based feedstock to form a densified melt of plastic material including the amendment; and pyrolyzing the densified melt of plastic material including the amendment within a pyrolysis reactor. Another method includes pyrolyzing a supply of the waste plastic feedstock within a pyrolysis reactor to generate a hydrocarbon gas stream and a solids residue stream; condensing out a tars product from the hydrocarbon gas stream output from the pyrolysis reactor with a quenching apparatus; and pyrolyzing the tars product within a supplemental pyrolysis reactor.

Systems and methods for processing waste plastics are provided. One method includes mixing, heating and compacting a supply of the waste plastic based feedstock having an appreciable amount of halide compounds or heteroatoms from one or more sources of contamination; providing an amendment comprising alkaline earth oxides and/or hydroxides, oxides of iron, and/or oxides of aluminum to be mixed, heated and compacted with the waste plastic based feedstock to form a densified melt of plastic material including the amendment; and pyrolyzing the densified melt of plastic material including the amendment within a pyrolysis reactor. Another method includes pyrolyzing a supply of the waste plastic feedstock within a pyrolysis reactor to generate a hydrocarbon gas stream and a solids residue stream; condensing out a tars product from the hydrocarbon gas stream output from the pyrolysis reactor with a quenching apparatus; and pyrolyzing the tars product within a supplemental pyrolysis reactor.

The invention comprises methods of robotically separating unwanted heteroatom-containing materials from a plastic mixture and catalytically pyrolyzing the resulting mixed plastics to obtain olefins and aromatics. Systems and compositions useful in the catalytic pyrolysis of plastics are also described.

A method for preparing biochar, including steps as follows: dosing: putting pre-crushed biomass into a reactor; charring conversion: heating the reactor to a certain temperature and pressure, and putting an active group-containing active agent containing 1% to 5% by mass of biomass and a catalyst containing 1% to 10% by mass of biomass (or putting the catalyst first and then putting the active agent) into the reactor to perform solid solution charring on the biomass; and cooling: after the charring conversion is completed, cooling the reactor to 40° C. or lower to obtain the biochar. Feedstocks are abundant and cheap, farmland biomass waste is reused, and the active group-containing active agent is added in biomass charring, which can effectively inhibit side reactions and coordinate with the catalyst to perform solid solution charring on the biomass, thereby improving a biochar conversion rate and making the charring process clean and environmentally friendly.

The present disclosure relates to organic compound(s) (i.e., compound of formula I or compound of formula IA) and/or a composition including the organic compound(s) useful for utilization of non-coking coal in a blend including coking coal without deterioration of properties of coking coal, wherein the organic compound(s) is capable of releasing hydrogen in the plastic region of coal. The present disclosure provides a simple, economical, non-toxic and efficient method for the preparation of the organic polymer, and a method for utilization of non-coking coal in blend including coking coal without deterioration of the properties of coke.

The present disclosure relates to organic compound(s) (i.e., compound of formula I or compound of formula IA) and/or a composition including the organic compound(s) useful for utilization of non-coking coal in a blend including coking coal without deterioration of properties of coking coal, wherein the organic compound(s) is capable of releasing hydrogen in the plastic region of coal. The present disclosure provides a simple, economical, non-toxic and efficient method for the preparation of the organic polymer, and a method for utilization of non-coking coal in blend including coking coal without deterioration of the properties of coke.

Processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Pyrolysis in the presence of an inert gas is employed to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

Processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Pyrolysis in the presence of an inert gas is employed to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

Systems and methods are provided for co-processing of biomass oil with mineral coker feeds in a coking environment. The coking can correspond to any convenient type of coking, such as delayed coking or fluidized coking. The biomass oil can correspond to biomass oil with a molar ratio of oxygen to carbon of 0.24 or less on a dry basis. Such types of biomass oil can be formed from pyrolysis methods such as hydrothermal pyrolysis, and are in contrast to biomass oils formed from pyrolysis methods such as fast pyrolysis. By using a biomass oil with a molar ratio of oxygen to carbon of 0.24 or less, improved yields of light coker gas oil can be achieved in conjunction with a reduction in the yield of heavy coker gas oil.

A method for transforming organic waste into carbon using sequential physical and biological degradation, including fermentation, drying under vacuum and elevated temperature followed by heating to a temperature of between 300° C. and 500° C. to promote carbonization and production of charcoal.