The present invention provides selective extraction of sulfoxides, or sulfoxides in combination with sulfones, from hydrocarbon mixtures containing these compounds. A significant advantage of the invention is that oxidation products resulting from oxidative desulfurization of hydrocarbon feedstocks are selectively extracted with minimum co-extraction of non-oxidized products such as valuable hydrocarbon fuel components.

The present invention provides selective extraction of sulfoxides, or sulfoxides in combination with sulfones, from hydrocarbon mixtures containing these compounds. A significant advantage of the invention is that oxidation products resulting from oxidative desulfurization of hydrocarbon feedstocks are selectively extracted with minimum co-extraction of non-oxidized products such as valuable hydrocarbon fuel components.

Aspects of the present invention relate to systems and processes for obtaining desired mercaptans or thiophenes from a feed stream containing a mixture of mercaptans, thiophenes and other components. In one aspect of the invention, a system for separating one or more components from a feed stream of mixed mercaptans includes one or more distillation columns in connection with a feed containing mercaptans, the distillation column having a rectification section, a stripping section, and a feed side section separated from a side draw section by a dividing wall that extends from the rectification section to the stripping section. The distillation column further being in connection with a condenser and a reboiler; and a distillate stream, a side drawn stream, and a bottoms stream.

The present invention generally relates to methods for decreasing viscosity, yield stress, or viscosity and yield stress of an asphaltene precipitate-containing aqueous mixture. More specifically, the method comprises applying an effective amount of a water-soluble polymer to an asphaltene precipitate-containing aqueous mixture. The water-soluble polymers comprise polyanion, polycation, and polar water-soluble polymer components. The present invention also relates to water-soluble asphaltene dispersants.

The present invention generally relates to methods for decreasing viscosity, yield stress, or viscosity and yield stress of an asphaltene precipitate-containing aqueous mixture. More specifically, the method comprises applying an effective amount of a water-soluble polymer to an asphaltene precipitate-containing aqueous mixture. The water-soluble polymers comprise polyanion, polycation, and polar water-soluble polymer components. The present invention also relates to water-soluble asphaltene dispersants.

A method of upgrading a petroleum feedstock, the method comprising the steps of introducing a disulfide oil, a water feed, and a petroleum feedstock to a supercritical water upgrading unit, and operating the supercritical water upgrading unit to produce a product gas stream, a product oil stream, and a used water stream.

Compounds of biodegradable surfactants useful for optimizing the separation of impurities typical of hydrocarbons, and designed to intervene and stabilize the molecular structure of crude oil, with no significant alterations of the crude's intrinsic composition are disclosed. The biodegradable surfactants compounds coexist with a non-ionic surfactant and an organic mix in emulsion form with the purpose of isolating crude from the pipeline, reduce friction to improve crude flow and to enter the crude macromolecule to modify the hydrocarbon chain to reduce its density and thus its viscosity; including compounds of biodegradable surfactants that comprise sodium hydroxide 1N, potassium chloride, sulphonic acid, dodecanoic acid, nonylphenol, terpene-1 and water, preferably hard water.

Compounds of biodegradable surfactants useful for optimizing the separation of impurities typical of hydrocarbons, and designed to intervene and stabilize the molecular structure of crude oil, with no significant alterations of the crude's intrinsic composition are disclosed. The biodegradable surfactants compounds coexist with a non-ionic surfactant and an organic mix in emulsion form with the purpose of isolating crude from the pipeline, reduce friction to improve crude flow and to enter the crude macromolecule to modify the hydrocarbon chain to reduce its density and thus its viscosity; including compounds of biodegradable surfactants that comprise sodium hydroxide 1N, potassium chloride, sulphonic acid, dodecanoic acid, nonylphenol, terpene-1 and water, preferably hard water.

A composition is provided for chemically liquefying and dispersing heavy organic solids in hydrocarbon streams. The composition comprises oxyalkylated tertiary dodecyl mercaptan; alkylaryl sulfonic acid or its representative salts; alkyl di-substituted 9-decenamide; and a hydrocarbon distillate.

A composition is provided for chemically liquefying and dispersing heavy organic solids in hydrocarbon streams. The composition comprises oxyalkylated tertiary dodecyl mercaptan; alkylaryl sulfonic acid or its representative salts; alkyl di-substituted 9-decenamide; and a hydrocarbon distillate.