Patent classifications
C10G67/10
Method for upgrading low-value and waste fats, oils, and greases
The present technology provides a method that includes contacting a composition with a caustic solution to produce a caustic-treated composition; combining the caustic-treated composition with silica particles to produce a slurry; and removing the silica particles from the slurry to produce a treated composition; wherein the composition includes one or more of animal fats, animal oils, plant fats, plant oils, vegetable fats, vegetable oils, greases, and used cooking oil and the composition includes: at least about 10 wppm of total metals, at least about 8 wppm of phosphorus, at least about 10 wppm of chlorine, at least about 10 wppm of sulfur, at least about 20 wppm of nitrogen, at least about 5 wt. % of free fatty acids; and has an acid number from about 10 mg KOH/g to about 150 mg KOH/g, and the silica particles has a particle size from about 10 microns to about 50 microns, a BET surface area from about 200 m.sup.2/g to about 1000 m.sup.2/g.
PURIFICATION OF RECYCLED AND RENEWABLE ORGANIC MATERIAL
A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material contains more than 20 ppm Cl. Exemplary methods include (a) providing the recycled or renewable organic material; (b) purifying the organic recycled or renewable organic material to obtain a purified recycled or renewable organic material, and (c) hydrotreating the purified recycled or renewable organic material in a presence of a hydrotreating catalyst at a temperature from 270 to 380° C. under pressure from 4 to 20 MPa and under continuous hydrogen flow; to obtain purified hydrotreated recycled or renewable organic material.
Method for upgrading low-value and waste fats, oils, and greases
The present technology provides a method that includes contacting a composition with a caustic solution to produce a caustic-treated composition; combining the caustic-treated composition with silica particles to produce a slurry; and removing the silica particles from the slurry to produce a treated composition; wherein the composition includes one or more of animal fats, animal oils, plant fats, plant oils, vegetable fats, vegetable oils, greases, and used cooking oil and the composition includes: at least about 10 wppm of total metals, at least about 8 wppm of phosphorus, at least about 10 wppm of chlorine, at least about 10 wppm of sulfur, at least about 20 wppm of nitrogen, at least about 5 wt. % of free fatty acids; and has an acid number from about 10 mg KOH/g to about 150 mg KOH/g, and the silica particles has a particle size from about 10 microns to about 50 microns, a BET surface area from about 200 m.sup.2/g to about 1000 m.sup.2/g.
Alkali-enhanced hydrothermal purification of plastic pyrolysis oils
A method is disclosed for preparing fuel components from waste pyrolysis oil. Exemplary embodiments include providing a waste pyrolysis oil having plastic pyrolysis oil and/or tyre pyrolysis oil, and impurities; purifying the waste pyrolysis oil by hydrothermal treatment with water or alkaline water; separating the hydrothermally treated waste pyrolysis oil from an aqueous phase; preparing a hydroprocessing feed from the hydrothermally treated waste pyrolysis oil; hydroprocessing the hydroprocessing feed catalytically with hydrogen to cause hydrogenation; and recovering a hydrocarbon fraction boiling in a liquid fuel range.
AN INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS FOR THE DIRECT PROCESSING OF A CRUDE OIL TO PRODUCE OLEFINIC AND AROMATIC PETROCHEMICALS
An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals by separating the crude oil into light components and heavy components.
AN INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS FOR THE DIRECT PROCESSING OF A CRUDE OIL TO PRODUCE OLEFINIC AND AROMATIC PETROCHEMICALS
An integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals by separating the crude oil into light components and heavy components.
METHOD FOR UPGRADING LOW-VALUE AND WASTE FATS, OILS, AND GREASES
The present technology provides a method that includes contacting a composition with a caustic solution to produce a caustic-treated composition; combining the caustic-treated composition with silica particles to produce a slurry; and removing the silica particles from the slurry to produce a treated composition; wherein the composition includes one or more of animal fats, animal oils, plant fats, plant oils, vegetable fats, vegetable oils, greases, and used cooking oil and the composition includes: at least about 10 wppm of total metals, at least about 8 wppm of phosphorus, at least about 10 wppm of chlorine, at least about 10 wppm of sulfur, at least about 20 wppm of nitrogen, at least about 5 wt. % of free fatty acids; and has an acid number from about 10 mg KOH/g to about 150 mg KOH/g, and the silica particles has a particle size from about 10 microns to about 50 microns, a BET surface area from about 200 m.sup.2/g to about 1000 m.sup.2/g.
A CATALYTIC PROCESS FOR REDUCING CHLORIDE CONTENT OF A HYDROCARBON FEED STREAM
A process for reducing a chloride content of a hydrocarbon feed stream involving contacting a hydrocarbon feed stream comprising a chloride containing pyrolysis oil obtained by cracking a chloride containing thermoplastic material with a sulfided catalyst comprising at least one of Co, Mo, and Ni or a catalyst comprising Pd, Pt, Cu, and/or Zn on a catalyst support in the presence of hydrogen gas to reduce one or more organic chloride compounds present in the hydrocarbon feed stream and form a hydrocarbon product stream and HCl. The HCl is removed from the hydrocarbon product stream, wherein the hydrocarbon product stream has a lower chloride content than the hydrocarbon feed stream based on the total weight of the chloride and the total weight of the hydrocarbon feed stream.
A CATALYTIC PROCESS FOR REDUCING CHLORIDE CONTENT OF A HYDROCARBON FEED STREAM
A process for reducing a chloride content of a hydrocarbon feed stream involving contacting a hydrocarbon feed stream comprising a chloride containing pyrolysis oil obtained by cracking a chloride containing thermoplastic material with a sulfided catalyst comprising at least one of Co, Mo, and Ni or a catalyst comprising Pd, Pt, Cu, and/or Zn on a catalyst support in the presence of hydrogen gas to reduce one or more organic chloride compounds present in the hydrocarbon feed stream and form a hydrocarbon product stream and HCl. The HCl is removed from the hydrocarbon product stream, wherein the hydrocarbon product stream has a lower chloride content than the hydrocarbon feed stream based on the total weight of the chloride and the total weight of the hydrocarbon feed stream.
Process for removing oxygenates from hydrocarbon streams
A system for removing oxygenates from a hydrocarbon stream includes a caustic wash unit comprising a plurality of caustic wash loops, and a hydrogenation reactor. The hydrogenation reactor is configured to receive a first gaseous stream from a first caustic wash loop of the plurality of caustic wash loops and pass a second gaseous stream from the hydrogenation reactor to a second caustic wash loop of the plurality of caustic wash loops, wherein the hydrogenation reactor comprises a sulfided catalyst.