C10G2300/1088

Pneumatically agitated ionic liquid alkylation using vaporization to remove reaction heat

Systems and apparatus for ionic liquid catalyzed hydrocarbon conversion, such as alkylation, using vaporization to remove reaction heat from an ionic liquid reactor and to provide mixing therein, wherein hydrocarbon vapors are withdrawn from the ionic liquid reactor and the withdrawn hydrocarbon vapor is recovered by a hydrocarbon vapor recovery unit in fluid communication with the ionic liquid reactor for recycling condensed hydrocarbons to the ionic liquid reactor. Processes for ionic liquid catalyzed alkylation are also disclosed.

Oligomerization of alpha olefins using metallocene-SSA catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends

Methods for making alpha olefin oligomers and polyalphaolefins include a step of contacting a C.sub.4 to C.sub.20 alpha olefin monomer and a catalyst system containing a metallocene, a first activator comprising a solid oxide chemically-treated with an electron withdrawing anion, and a second activator comprising an organoaluminum compound. The alpha olefin oligomers and polyalphaolefins prepared with these catalyst systems can have a high viscosity index combined with a low pour point, making them particularly useful in lubricant compositions and as viscosity modifiers.

Method for producing high-octane motor gasolines of low-octane hydrocarbon fractions, fractions of gaseous olefins and oxygenates and a plant for the method embodiment

The invention relates to method and plant for the production of high-octane gasolines from raw hydrocarbon fractions, fractions of gaseous olefins and oxygenates. A method has been proposed, wherein the feedstock component flow is supplied to a unit for supplying flows to be treated, into the reactor, wherein the reaction is carried out in the presence of a zeolite-containing catalyst, high-octane gasoline is isolated by separation of the conversion product, while diverting simultaneously the reaction water and the exhaust gases. A reactor contains at least two reaction zones, between which there are further arranged means for mixing the reaction product from the previous reaction zone and the supplied oxygenates and olefin-containing feedstock, whereas using the unit for supplying flows there is supplied a flow oxygenates and olefin-containing feedstock and the flow of raw hydrocarbon fractions into the first reaction zone of the reactor, and the flow oxygenates and olefin-containing feedstock into the second reaction zone of the reactor.

Process for oligomerization of gasoline to make diesel

A first oligomerization stream is oligomerized over a first catalyst in a first oligomerization reactor zone to make oligomerate. An oligomerate stream is separated to provide a heavy oligomerate boiling in the diesel range and a second oligomerization feed stream. The latter is fed to a second oligomerization reactor zone with a second different catalyst to produce the heavy oligomerate.

Method of increasing alpha-olefin content

Implementations described herein generally relate to methods for purifying alpha-olefins. The alpha-olefins may be used to form drag reducing agents for improving flow of hydrocarbons through conduits, particularly pipelines. In one implementation, a method of increasing alpha-olefin content is provided. The method includes providing an olefin feedstock composition having an alpha-mono-olefin and at least one of a diolefin having an equal number of carbon atoms to the alpha-mono-olefin and/or a triolefin having an equal number of carbon atoms to the alpha-mono-olefin. The method further includes contacting the olefin feedstock composition with ethylene in the presence of a catalyst composition including an olefin metathesis catalyst. The method further includes reacting the olefin feedstock composition and ethylene at metathesis reaction conditions to produce an alpha-olefin product comprising the alpha-mono-olefin and alpha-olefins having fewer carbon atoms than the alpha-mono-olefin.

Process for preparing hydrocarbon mixture exhibiting unique branching structure

Provided herein is a unique process that prepares a saturated hydrocarbon mixture with well-controlled structural characteristics that address the performance requirements driven by the stricter environmental and fuel economy regulations for automotive engine oils. The process allows for the branching characteristics of the hydrocarbon molecules to be controlled so as to consistently provide a composition that has a surprising CCS viscosity at −35° C. (ASTM D5329) and Noack volatility (ASTM D5800) relationship. The process comprises providing a specific olefinic feedstock, oligomerizing in the presence of a BF.sub.3 catalyst, and hydroisomerizing in the presence of a noble-metal impregnated, 10-member ring zeolite catalyst.

Branched saturated hydrocarbons derived from olefins

Methods of making branched isoparaffin compositions derived from natural oil based linear internal olefins are disclosed. Uses of branched isoparaffins formed by such methods are also disclosed.

Process for the oligomerization of olefins

A process for preparing a hydrocarbon fluid includes a step of oligomerising an initial hydrocarbon composition which contains, in relation to the total weight of said initial hydrocarbon composition, at least 2% by weight of 3-methyl-but-1-ene, at least 5% by weight of 2-methyl-but-2-ene and at least 5% by weight of 2-methyl-but-1-ene.

ALKYLATION PROCESS WITH IMPROVED OCTANE NUMBER

An improved alkylation process with improved octane number and lower final boiling point. Further, the present disclosure comprises an alkylation system that allows flexibility in the operating parameters without loss of productivity. This enhances the advantage of the solid acid alkylation process of the invention over the liquid acid processes, as the C9+ alkylate will mainly contain the desired highly branched paraffin's in the case of solid acid alkylation. By fractionation of C9+, the RON number of the gasoline alkylate after fractionation remains very high, while the final boiling point of the gasoline fraction will decrease, improving value and blending flexibility.

REGULATORY CONTROLLER FOR USAGE IN A CATALYTIC OLEFINS UNIT

An advanced regulatory controller for a converter of a catalytic olefins unit is disclosed. A Fluid Catalytic Cracking (FCC) type converter (i.e., reactor-regenerator) is combined with an ethylene style cold-end for product recovery. The regulatory controller operates using an Advanced Regulatory Control (ARC) application using variables, such as a controlled variable, four disturbance variables, associated variable, and a manipulated variable. The ARC application manipulates fuel oil or tail gas flow to a regenerator in response to an expected future steady state value of a regenerator bed temperature resulting from changes in the values of a selected set of the variables.