C10G2300/4025

Process for the conversion of oxygenates to C5+ hydrocarbons boiling in the gasoline boiling range
11060036 · 2021-07-13 · ·

Process for the conversion of oxygenates to C.sub.5+ hydrocarbons boiling in the gasoline boiling range, comprising the steps of continuously a) providing one or more feed streams of one or more oxygenate compounds; b) heating the one or more feed streams to an inlet temperature of one or more downstream conversion reactors; c) introducing the one or more heated feed stream into inlet of the one or more conversion reactors; d) converting in the one or more conversion reactors the one or more heated feed stream in presence of catalyst to a converted oxygenate product comprising C.sub.5+ hydrocarbons; e) withdrawing from the one or more conversion reactors the converted oxygenate product; f) determining at outlet of the one or more conversion reactors amount of the one or more unconverted oxygenate compounds in the withdrawn converted oxygenate product; g) separating the converted oxygenate product into a C.sub.4 hydrocarbon fraction, a fraction with the C.sub.5+ hydrocarbons boiling in the gasoline boiling range and a fraction comprising water and the one or more unconverted oxygenate compounds, wherein the inlet temperature of the one or more feed streams in step b is continuously adjusted to maintain a constant amount of the one or more unconverted oxygenate compounds as determined in step f.

Light olefin production via an integrated steam cracking and hydrocracking process

A process for producing olefins comprising introducing a steam cracker feed to a liquid steam cracker furnace section to produce a steam cracker product comprising olefins, and wherein an amount of olefins in the steam cracker product is greater than in the steam cracker feed; separating the steam cracker product in a separation unit into a hydrogen stream, a methane stream, an olefin gas stream (ethylene and propylene), a saturated gas stream (ethane and propane), a hydrocarbons gas stream (C.sub.4-5 hydrocarbons), an aromatics stream (C.sub.6-8 aromatic hydrocarbons), a raffinate stream (C.sub.6-8 non-aromatic hydrocarbons), and a heavies stream (C.sub.9+ hydrocarbons); feeding the hydrocarbons gas stream and hydrogen to one or more hydroprocessing reactors to produce a hydrocracking product comprising ethane and propane; and recycling the hydrocracking product and the saturated gas stream to the liquid steam cracker furnace section.

Fischer-Tropsch Processes with Modified Product Selectivity
20240002734 · 2024-01-04 ·

The present disclosure relates generally to compositions and processes for modifying Fischer-Tropsch product selectivity. In particular, the disclosure provides for a for converting a mixture of hydrogen and carbon monoxide gases to a product composition comprising alcohols and liquid hydrocarbons via Fischer-Tropsch synthesis in the presence of a supported cobalt-manganese Fischer-Tropsch synthesis catalyst, the process comprising: contacting the catalyst with a first gaseous feed comprising carbon monoxide and hydrogen for at least 12 hours to provide via Fischer-Tropsch synthesis a first product composition comprising C.sub.5+ hydrocarbons and alcohol; then contacting the catalyst with a first selectivity gaseous composition comprising at least 35 vol % H.sub.2 and a H.sub.2:CO molar ratio of at least 2; and then contacting the catalyst with a second gaseous feed comprising carbon monoxide and hydrogen to provide a second product composition comprising C.sub.5+ hydrocarbons, with a selectivity of no more than 5% for alcohols. Optionally, the catalyst selectivity to alcohols can be reversed by contacting the catalyst with a second selectivity gaseous composition comprising CO or a H.sub.2:CO molar ratio of at below 1.5.

PROCESS FOR THE CONVERSION OF OXYGENATES TO C5+ HYDROCARBONS BOILING IN THE GASOLINE BOILING RANGE
20210002557 · 2021-01-07 · ·

Process for the conversion of oxygenates to C.sub.5+ hydrocarbons boiling in the gasoline boiling range, comprising the steps of continuously a) providing one or more feed streams of one or more oxygenate compounds; b) heating the one or more feed streams to an inlet temperature of one or more downstream conversion reactors; c) introducing the one or more heated feed stream into inlet of the one or more conversion reactors; d) converting in the one or more conversion reactors the one or more heated feed stream in presence of catalyst to a converted oxygenate product comprising C.sub.5+ hydrocarbons; e) withdrawing from the one or more conversion reactors the converted oxygenate product; f) determining at outlet of the one or more conversion reactors amount of the one or more unconverted oxygenate compounds in the withdrawn converted oxygenate product; g) separating the converted oxygenate product into a C.sub.4 hydrocarbon fraction, a fraction with the C.sub.5+ hydrocarbons boiling in the gasoline boiling range and a fraction comprising water and the one or more unconverted oxygenate compounds, wherein the inlet temperature of the one or more feed streams in step b is continuously adjusted to maintain a constant amount of the one or more unconverted oxygenate compounds as determined in step f.

Light Olefin Production Via an Integrated Steam Cracking and Hydrocracking Process

A process for producing olefins comprising introducing a steam cracker feed to a liquid steam cracker furnace section to produce a steam cracker product comprising olefins, and wherein an amount of olefins in the steam cracker product is greater than in the steam cracker feed; separating the steam cracker product in a separation unit into a hydrogen stream, a methane stream, an olefin gas stream (ethylene and propylene), a saturated gas stream (ethane and propane), a hydrocarbons gas stream (C.sub.4-5 hydrocarbons), an aromatics stream (C.sub.6-8 aromatic hydrocarbons), a raffinate stream (C.sub.6-8 non-aromatic hydrocarbons), and a heavies stream (C.sub.9+ hydrocarbons); feeding the hydrocarbons gas stream and hydrogen to one or more hydroprocessing reactors to produce a hydrocracking product comprising ethane and propane; and recycling the hydrocracking product and the saturated gas stream to the liquid steam cracker furnace section.

Process For The Production Of Petrochemical Feedstock And High Octane Gasoline From Middle Distillates

The present invention provides a process for upgrading LCO to (i) high octane gasoline and high aromatic feedstock for aromatic complex, (ii) Utilization of FCC for cracking unconverted diesel range stream from hydrocracker to high octane gasoline. This invention discloses the process to improve the quality (e.g., RON, Sulfur) of gasoline by utilizing FCC and hydrocracking processes.

Process and catalyst formulation for cracking crude oil

A process for converting crude oil may comprise contacting a crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent and contacting the hydroprocessed effluent with a fluidized catalytic cracking (FCC) catalyst composition in an FCC system to produce cracked effluent comprising at least olefins. The crude oil may have an API gravity from 30 to 35. The FCC system may operate at a temperature of greater than or equal to 580 C., a weight ratio of the FCC catalyst composition to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. The FCC catalyst composition may comprise ultrastable Y-type zeolite (USY zeolite) impregnated with lanthanum; ZSM-5 zeolite impregnated with phosphorous; an alumina binder; colloidal silica; and a matrix material comprising Kaolin clay.

Processes To Convert Naphtha To Heavier Products
20200325401 · 2020-10-15 ·

In an embodiment, a process for converting a hydrocarbon feed includes introducing a hydrocarbon feed comprising a C.sub.2-C.sub.50 acyclic alkane and a C.sub.3-C.sub.50 cyclic alkane to a catalyst composition in a reactor. The process further includes converting the hydrocarbon feed in the reactor under reactor conditions to a product mixture comprising at least one of a C.sub.6-C.sub.9 aromatic product or a C.sub.12+ distillate product.

PROCESS FOR CONVERTING PLASTIC INTO WAXES BY CRACKING AND A MIXTURE OF HYDROCARBONS OBTAINED THEREBY

The present invention relates to a process for converting plastic into waxes by cracking. The process comprises the steps of introducing the plastic within a reactor; allowing at least a portion of the plastic to be converted to waxes, the waxes being part of a pyrolysis gas formed within the reactor; and removing a product stream containing said waxes from the reactor. The invention also relates to a mixture of hydrocarbons obtainable by that process.

Methods for separating light fractions from hydrocarbon feedstock

A process for facile separation of lighter hydrocarbon fractions from the heavier fractions of hydrocarbon oil feedstocks is disclosed, which utilizes novel sparging and reverse distillation techniques. The present invention can be utilized for the facile topping of crude oil extracted on-site. Moreover, while heavier hydrocarbon fractions may be shipped to refineries for further processing, this invention will also prove useful for quick separation of light fractions produced by cracking processes off-site.