A burner sub-system, a furnace comprising the same, a fuel combustion process and steam cracking process carried out in the furnace. The burner sub-system comprises a barrier wall segment between the burner tip and the flue-gas recirculation (“FGR”) duct, effectively blocking direct gas flow between the burner tip and the FGR duct opening, but without encircling the whole burner tip. The presence of the partial barrier wall has the advantage of preventing the temperature inside the FGR duct from becoming too high, while achieving low NOx emissions from the combustion process without overheating the burner tip because of reduced amount of heat reflection to the burner tip compared to an annular barrier wall. The invention is particularly useful in furnaces where hydrogen-rich fuel gas is combusted.

The present invention relates to inhibition of high temperature naphthenic acid corrosion occurring in hydrocarbon processing units. The invention provides an effective novel non-polymeric and non-fouling additive for inhibiting high-temperature naphthenic acid corrosion, comprising an effective corrosion-inhibiting amount of a second phosphate ester wherein said second phosphate ester is obtained by reacting a first phosphate ester with an oxirane compound selected from the group consisting of butylene oxide, ethylene oxide, propylene oxide or any other oxirane compound or a combination thereof, preferably with butylene oxide, capably yielding said second phosphate ester, having a structure A or B, ##STR00001##
wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of moieties having 1 to 20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different, X is H, CH.sub.3 or C.sub.2H.sub.5; and n may vary from 1 to 20,
wherein said first phosphate ester is having a structure I or II, ##STR00002##
wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of moieties having 1 to 20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different, said first phosphate ester being obtained as a reaction product of reaction of an alcohol with a phosphorous pentaoxide.

A method for upgrading a hydrocarbon feed is disclosed. The method may be carried out in a pyrolysis furnace that may have at least two coils and at least two thermal zones. The method may include two operating or run modes that may be repeated in a cycle. In one run, upgrading may be carried out in one coil while decoking may be carried out in the other coil. After a predetermined amount of time, the streams of the two coils may be switched for a second run, such that decoking may be carried out in the coil in which upgrading was done in the first run and upgrading may be carried out in the coil in which decoking was done in the first run. The first and the second run are cyclically repeated one after the other.

The present invention provides a metal cavity inwall decoking method, comprising: a. Process sealed compression to the metal cavity; b. Process rapid decompression to the metal cavity.

The present invention makes such substance as hydrocarbon volatiles, moisture and so on inside the coke gasify quickly because of fierce change of pressure differential by compressing and then decompressing the metal cavity rapidly, which makes the coke crush and fall off from the inwall of metal cavity and finally finish the decoking work. The decoking method claimed in the present invention is simply and convenient to operate, and can greatly increase the decoking efficiency.

Disclosed is a method for predicting corrosion and spontaneous combustion of sulfur-related petrochemical equipment. The method solves the issues in the existing techniques that includes narrow predicting range, high workload in installation and maintenance, and time lag in predicting corrosion and spontaneous combustion inside equipment. The method comprises a step of a dual index system prediction, which includes a step of monitoring a temperature and a step of detecting SO.sub.2 gas generated by spontaneous combustion. The time when spontaneous combustion occurs can be accurately calculated by using a fitted quantitative relationship formula generated by the spontaneous combustion of corrosion products. The method has a low Labor cost. The method has a low labor cost and, does not require on-site gas detection to be carried out by means of manual detection, which both reduces the cost and ensures the detection accuracy.

Methods of reducing drag in a flowing hydrocarbon include introducing to the flowing hydrocarbon an amount of a solid drag reducing additive effective to improve the flow, the solid drag reducing additive including a polymer particle prepared from at least one polar monomer and a percent by weight (wt %) of liquid of 50 wt % or less. Methods also include producing a solid drag reducing additive that includes forming a polymer from at least one polar monomer by emulsion polymerization; and disrupting the emulsion by adding at least one demulsifier and at least one anti-blocking agent to form the solid drag reducing additive. Compositions include a solid drag reducing additive comprising a polymer prepared from at least one polar monomer and having an average particle size in a range of about 100 μm to about 500 μm, wherein the solid drag reducing additive comprises less than 50 wt % of liquid.

Corrosion induced by the presence of naphthenic acids in hydrocarbon fluids, particularly where such fluids are at elevated temperatures, may be inhibited or controlled through use of corrosion inhibiting compositions comprising a combination of a minor portion of a phosphorus-based constituent and a major portion of a sulfur-based constituent, nitrogen-based constituent, or combination thereof. In another embodiment the sulfur-based constituent and/or nitrogen-based constituent may be used without any phosphorus-based constituent. Where the compounds are appropriately selected, the compositions may inhibit corrosion to a degree comparable or nearly comparable to the inhibition provided by an equal amount of some conventional phosphorus-based compounds alone, but are significantly less likely to impair catalyst activity in downstream cracking and refinery operations.

A method of improving the transportation of a crude oil which has been recovered from a crude oil well, the method comprising adding one or more glycerophospholipid(s) to a crude oil before and/or during the transportation of said crude oil.

Processes for preventing or minimizing the rate of upgrading catalyst deactivation in a petroleum refinery, preventing or minimizing the rate of silicone-containing deposits within refinery process equipment, or both utilizing high-field proton nuclear magnetic spectroscopy (NMR) to rapidly measure concentrations of polydimethylsiloxanes (PDMS) and its thermal degradation products in potential refinery feed stock and refinery intermediate streams with high sensitivity and precision.

Corrosion inhibitor compositions and methods for inhibiting corrosion on a metal surface exposed to a hydrocarbon fluid are provided. The corrosion inhibition compositions can include a corrosion inhibitor, such as 3-dimethylamino benzoic acid, 4-dimethylamino benzoic acid, or 2,5-dihydroxyterephthalic acid. The corrosion inhibitor composition can further comprise dimethyl sulfoxide, and heavy aromatic naphtha. The corrosion inhibitor composition can be phosphate-free and can inhibit naphthenic acid corrosion. In the methods, a corrosion inhibitor composition is added to the hydrocarbon fluid exposed to the metal surface to prevent or inhibit corrosion on the metal surface, including naphthenic acid corrosion.