Scavenging chemicals used in mitigation treatments of hydrogen sulfide in hydrocarbon streams often continue to react and form polymers that foul the processing system. Disclosed herein are methods for determining if a scavenging chemical mitigator, or its reaction or degradation product, will polymerized during or after mitigation treatments. This information allows for the optimization of mitigation treatments that pre-emptively control or prevent polymer formation. Such pre-emption measures reduce the cost and time related to remedial actions to treat polymer-fouled equipment.

An advanced regulatory controller for a converter of a catalytic olefins unit is disclosed. A Fluid Catalytic Cracking (FCC) type converter (i.e., reactor-regenerator) is combined with an ethylene style cold-end for product recovery. The regulatory controller operates using an Advanced Regulatory Control (ARC) application using variables, such as a controlled variable, four disturbance variables, associated variable, and a manipulated variable. The ARC application manipulates fuel oil or tail gas flow to a regenerator in response to an expected future steady state value of a regenerator bed temperature resulting from changes in the values of a selected set of the variables.

An ebullated bed hydroprocessing system is upgraded and operated at modified conditions using a dual catalyst system to produce less fouling sediment. The less fouling sediment produced by the upgraded ebullated bed reactor reduces the rate of equipment fouling at any given sediment production rate and/or concentration compared to the sediment produced by the ebullated bed reactor prior to upgrading. In some cases, sediment production rate and/or concentration are maintained or increased, after upgrading the ebullated bed reactor, while equipment fouling is reduced. In other cases, sediment production rate and/or concentration are increased, after upgrading the ebullated bed reactor, without increasing equipment fouling. In some cases, sediment production rate and/or concentration are decreased by a given percentage, after upgrading the ebullated bed reactor, and the rate of equipment fouling is decreased by a substantially greater percentage.

A system and method for purging an isolation valve using a liquid purge medium.

A refractory-lined equipment includes a vessel defining an interior at least partially lined with a refractory material, and a nozzle assembly coupled to the vessel and extending into the interior. The nozzle assembly includes an outer sleeve fixed to the sidewall and extending through an aperture defined in the sidewall, the outer sleeve defining a central passageway, and a nozzle cartridge assembly positionable within the central passageway and including an inner sleeve, a refractory lining disposed about the inner sleeve, and a nozzle positioned within the inner sleeve. The nozzle cartridge assembly is removably coupled to the outer sleeve external to the vessel.

Described herein are systems and methods of fouling mitigation in a hydrocarbon fractionation column. The methods correlate operating parameters of the fractionation column, specifically flow rate and temperature, with fouling. The methods can include measuring a temperature and a flow rate at a bottom stream of the hydrocarbon fractionation column; providing the measured temperature and flow rate to a processing device; determining, by the processing device, based on the measured temperature and flow rate of the bottom stream, an antifoulant treatment protocol for the hydrocarbon fractionation column; and treating the hydrocarbon fractionation column by controlling, by the processing device, a feed control unit in accordance with the determined antifoulant treatment protocol.

A process for removing or reducing the accumulation of foulant within furnaces and heat exchangers in industrial systems such as an oil refinery by introducing a periodic steam blast. The steam blast is directed into the fluid stream from which the foulants form on to the heat exchanger surfaces. The steam blast increases the flow rates, creates turbulence and increases the temperature within the heat exchanger to dislodge foulant in both a soft and hardened states from internal surfaces upon which foulants have adhered and accumulated.

A method of demulsifying an emulsion with an ionic liquid having a nitrogen or phosphorus cation.

Corrosion inhibitor compositions and methods for inhibiting corrosion on a metal surface exposed to a hydrocarbon fluid are provided. The corrosion inhibition compositions can include a corrosion inhibitor, such as 3-dimethylamino benzoic acid, 4-dimethylamino benzoic acid, or 2,5-dihydroxyterephthalic acid. The corrosion inhibitor composition can further comprise dimethyl sulfoxide, and heavy aromatic naphtha. The corrosion inhibitor composition can be phosphate-free and can inhibit naphthenic acid corrosion. In the methods, a corrosion inhibitor composition is added to the hydrocarbon fluid exposed to the metal surface to prevent or inhibit corrosion on the metal surface, including naphthenic acid corrosion.

A unit and system are operable with cooling fluid for handling effluent produced in a cleaning process of refinery equipment. A drum of the unit has an inlet for the effluent, a liquid outlet for condensed effluent, and a vapor outlet for uncondensed effluent. A shell disposed in an interior of the drum and has a passage communicating outside the drum. A heat exchanger is disposed in the passage of the shell. As the effluent from the inlet enters the shell’s passage at the distal end of the shell, the heat exchanger cools the effluent using cooling fluid cycled through the heat exchanger. Condensed effluent escaping from the shell can fill the drum’s interior up to a liquid level. Uncondensed effluent escaping from the shell can collect in the open space of the drum, being subject to further condensation.