The invention involves an integrated process in which a hydrocarbon feedstock is treated with a caustic (alkaline) extraction to remove sulfides, disulfides, and mercaptans. These extracted materials are further treated, and are then used to activate hydrotreating catalysts.

Supercritical upgrading reactors and reactor systems are provided for upgrading a petroleum-based composition using one or more purging fluid inlets to prevent plugging of the catalyst layer in the reactor. Processes for upgrading petroleum-based compositions by utilizing a reactor having at least one purging fluid inlet are also provided.

The present invention deals with activation and start-up procedures of catalysts for the deep HDS of middle distillates for producing ultra low sulfur diesel (ULSD), consisting of two in situ activation stages: at stage 1, TGA is applied, and at stage 2, DMDS is used; kerosene is the transport means at these stages, which are carried out under given temperature and pressure conditions, and feedstock and hydrogen flows at established times. After the activation of the catalyst in situ, the stabilization stage takes place under selected temperature and pressure conditions, feedstock and hydrogen flow at established times, with which the stabilization of the highly dispersed metallic sulfides is achieved and, in this way, the activity of the catalysts removing contaminants for the production of ULSD is increased.

A process for hydrodealkylating a hydrocarbon stream comprising (a) contacting the hydrocarbon stream with a hydroprocessing catalyst in a hydroprocessing reactor in the presence of hydrogen to yield a hydrocarbon product, wherein the hydrocarbon stream contains C.sub.9+ aromatic hydrocarbons; and (b) recovering a treated hydrocarbon stream from the hydrocarbon product, wherein the treated hydrocarbon stream comprises C.sub.9+ aromatic hydrocarbons, wherein an amount of C.sub.9+ aromatic hydrocarbons in the treated hydrocarbon stream is less than an amount of C.sub.9+ aromatic hydrocarbons in the hydrocarbon stream due to hydrodealkylating of at least a portion of C.sub.9+ aromatic hydrocarbons from the hydrocarbon stream during the step (a) of contacting.

The present invention provides a process for upgrading a Fischer-Tropsch product by hydrocracking in the presence of a hydrocracking catalyst in a reactor, wherein the process is initiated by a series of steps (i) to (iv). The hydrocracking catalyst is (i) contacted with a hydrogen-containing stream having a feed temperature of from 360 C. to 420 C.; (ii) the feed temperature of the hydrogen-containing stream is reduced to a temperature of from 220 C. to 280 C.; (iii) the catalyst is contacted with a Fischer-Tropsch product stream having a feed temperature of from 220 C. to 280 C., which is co-fed with the hydrogen-containing stream; and (iv) the catalyst is co-fed with a Fischer-Tropsch product stream and hydrogen-containing stream having feed temperatures of from 380 C. and 400 C. for at least four days and wherein the hydrocracking catalyst is not activated by sulfiding.

A process for the hydrocracking of heavy oils and/or oil residues, the process comprising the step of contacting the heavy oils and/or oil residues with a non-metallised carbonaceous additive in the presence of a hydrogen-containing gas at a temperature of from 250 C. to 600 C. wherein the non-metallised carbonaceous additive has an average pore size of at least 2 nm.

A unique process and catalyst is described that operates efficiently for the direct production of a high cetane diesel type fuel or diesel type blending stock from stochiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 10,000 barrels of product per day, by eliminating traditional wax upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as gas to liquids production and other applications that require optimized economics based on supporting distributed feedstock resources.

The invention involves an integrated process in which a hydrocarbon feedstock is treated with a caustic (alkaline) extraction to remove sulfides, disulfides, and mercaptans. These extracted materials are further treated, and are then used to activate hydrotreating catalysts.

A method for hydrotreatment of a vacuum-distillate-type hydrocarbon feedstock that contains sulfur and nitrogen compounds is described, with said method for hydrotreatment of a vacuum-distillate-type feedstock comprising a specific concatenation of catalysts that makes it possible to increase the overall activity and the overall stability of the method.

The present invention relates to a catalyst for hydrogenation and a method for preparing the same, and more specifically, provides a catalyst having improved activity by including copper and copper oxide as a promoter when a hydrogenation catalyst including nickel is prepared by using a deposition-precipitation (DP) method. Accordingly, a catalyst having high activity may be provided in a hydrogenation process of a hydrocarbon resin.