Disclosed embodiments provide a system and method for producing hydrocarbons from biomass. Certain embodiments of the method are particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments of the method convert a biomass feedstock into a product hydrocarbon by hydropyrolysis. Catalytic conversion of the resulting pyrolysis gas to the product hydrocarbon and carbon dioxide occurs in the presence of hydrogen and steam over a CO.sub.2 sorbent with simultaneous generation of the required hydrogen by reaction with steam. A gas separator purifies product methane, while forcing recycle of internally generated hydrogen to obtain high conversion of the biomass feedstock to the desired hydrocarbon product. While methane is a preferred hydrocarbon product, liquid hydrocarbon products also can be delivered.

A process for the manufacture of one or more useful products comprises: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; supplying at least a portion of the raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; supplying the clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.

A method and a process arrangement for producing hydrocarbons from plastic-based raw material by a gasification in an integrated process The integrated process includes a gasification unit for forming a gasification product, a steam cracking unit for forming a cracking product and a recovery unit for recovering hydrocarbons. The plastic-based raw material is gasified with steam in the gasification unit having at least one fluidized bed gasifier and the gasification product is formed, the gasification product is cooled at least partly for slowing and/or stopping the chemical reactions after the gasification, The gasification product is supplied to a quench tower of the gasification unit in which the gasification product is treated and condensable components are removed from the gasification product forming a treated gasification product, and the treated gasification product and the cracking product of the steam cracking unit are supplied to the recovery unit for separating and recovering hydrocarbons.

Solid fuel in the form of particles is supplied to a pyrolyzer, and pyrolysis conditions are maintained in the pyrolyzer for separating condensable gaseous substances from the fuel. Heat required by the pyrolysis conditions is supplied at least partly with solid fluidized bed material which passes through the pyrolyzer simultaneously as it is fluidized by fluidizing gas in the pyrolyzer. Condensable gaseous substances separated from the fuel are conveyed from the pyrolyzer to a condenser, in which they are separated as so-called pyrolysis oil in liquid form, and solid fluidized bed material taken from the pyrolyzer and containing combustible pyrolysis residue originating from the fuel is circulated through a gasifier, in which product gas, which is burnt in a boiler or a kiln, is formed from the pyrolysis residue.

Methods and systems are provided for making gasoline. The method includes converting a resid-containing feed to a first fuel gas and a fluid coke in a fluidized bed reactor; gasifying the fluid coke with steam and air to produce a second fuel gas, said second fuel gas comprising a syngas; contacting the first fuel gas with a first conversion catalyst under first effective conversion conditions to form an effluent comprising C.sub.5+ hydrocarbon compounds; and converting the syngas to gasoline boiling range hydrocarbons by converting the syngas to a methanol intermediate product.

A method for thermal volume reduction of waste material contaminated with radionuclides includes feeding the waste material into a fluidized bed reactor, injecting fluidizing gas into the fluidized bed reactor to fluidize bed media in the fluidized bed reactor, and decomposing the waste material in the fluidized bed reactor. A system for thermal volume reduction of the waste material includes one or more of a feedstock preparation and handling system, a fluidized bed reactor system, a solids separation system, and an off-gas treatment system. The method and system may be used to effectively reduce the volume or radioactive wastes generated from the operation of nuclear facilities such as nuclear power plants including wastes such as spent ion exchange resin, spent granular activated carbon, and dry active waste. The majority of the organic content in the waste material is converted into carbon dioxide and steam and the solids, including the radionuclides, are converted into a waterless stable final product that is suitable for disposal or long-term storage.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production using partial oxidation of a solid or liquid fuel to form a partially oxidized stream that comprises a fuel gas. This fuel gas stream can be one or more of quenched, filtered, and cooled before being directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO.sub.2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The expanded and cooled exhaust stream can be further processed to provide the recycle CO.sub.2 stream, which is compressed and passed through one or more recuperator heat exchangers in a manner useful to provide increased efficiency to the combined systems.

This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO.sub.2 and the selective reaction with organic compounds.

The invention relates to a catalyst regeneration process for a tar reforming catalyst within a catalyst bed in a tar reformer. The process comprises the steps of:Admitting a main gas stream with controlled temperature and oxygen content to an inlet into the tar reformer;Passing the main gas stream through the catalyst bed to form an oxygen depleted gas stream;Exiting the oxygen depleted gas stream from the tar reformer; andRecycling at least a part of the oxygen depleted gas stream exiting from the tar reformer back into said main gas stream upstream said tar reformer. The temperature of said main gas stream at the inlet is controlled to be within the range from about 500 C. to about 1000 C.

This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO.sub.2 and the selective reaction with organic compounds.