A gasification process may include (a) introducing a liquid hydrocarbon feedstock and at least one of a dry feedstock or a first slurried feedstock into a reactor lower section, wherein the at least one dry feedstock or first slurried feedstock is introduced through two primary feed nozzles while the liquid hydrocarbon feedstock is introduced through at least two secondary feed nozzles; (b) partially combusting the feedstocks in the reactor lower section with a gas stream comprising an oxygen-containing gas or steam to evolve heat and form products comprising hot synthesis gas; (c) passing said hot synthesis gas from step (b) upward into a reactor upper section; (d) and introducing a second slurried feedstock into said reactor upper section, whereby heat from said hot synthesis gas supports reaction of the second slurried feedstock by pyrolysis and gasification reactions.

The invention relates to the field of gasification of a carbonaceous feedstock and can be used in the chemical, petrochemical, coke-gas and energy industries. A method for gasification of a carbonaceous feedstock comprises partial oxidation of the carbonaceous feedstock in an oxidation chamber in a mixture of oxygen-containing gas and water vapour in a partial oxidation channel, which is mounted coaxially in the vertical oxidation chamber. The water vapour for the partial oxidation of the carbonaceous feedstock is supplied at the input and output of the vertical oxidation chamber of a combustion chamber. A gas producer comprises a housing, a burner device, a vertical oxidation chamber, manifolds for supplying carbonaceous feedstock, water vapour and oxygen-containing gas, a pipe for discharging gasification products, a slag removal chamber, and also a partial oxidation channel, which is arranged coaxially in the vertical oxidation chamber and is attached to an upper internal part of the housing, in which the burner device is installed. What is achieved is the production of producer gas with an elevated concentration of hydrogen.

An apparatus and a method for gasifying carbon-containing materials in which the material for gasification and oxygen, usually in the form of air, are supplied to a gas generator where the gasification takes place in a fixed bed reactor. The product gas is drawn off via a product gas line and introduced into a hot gas filter. A filter, preferably provided with filter candles, removes solids such as particles not yet gasified, ash and foreign bodies, while clean gas passes through and is taken off via a clean gas line. An outlet is provided in the bottom region of the hot gas filter to remove residual solids. The hot gas filter is supplied through a line with oxygen, preferably in the form of air, in its middle height region, between the filter bottom and the outlet.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

Provided is a carbonizing furnace capable of improving combustion efficiency of combustible gas generated by combustion of organic waste and of improving carbonization efficiency of organic waste by appropriately controlling the temperature of carbide. Provided is a pyrolytic furnace in which heating gas can be suppressed from outflowing to the outside from a gap between the upper surface of the body part of the pyrolytic furnace and the outer circumferential surface of a reaction tube where a pyrolysis reaction between carbide and a gasification agent is caused, and in which the temperature of a region where the pyrolysis reaction is caused can be suppressed from being reduced. Provided is a water gas generation system which improves thermal efficiency without using a dedicated heat source for generating water steam to be used as a gasification agent for carbide, promotes a pyrolysis reaction, and thereby, achieves the excellent heat efficiency. Provided are a hydrogen gas generation system and a power generation system which use water gas generated by a water gas generation system including a carbonizing furnace and a pyrolytic furnace and which have excellent productivity. Provided is a carbonizing furnace which improves combustion efficiency by controlling the supply amount of air being supplied to the carbonizing furnace according to the temperature of combustion gas in the carbonizing furnace, and which improves carbonization efficiency by controlling the discharge amount of carbide to be discharged to the outside according to the temperature of carbide or the deposit amount of organic waste in the carbonizing furnace, to make the temperature of carbide appropriate, and by controlling the temperature of air being supplied to the carbonizing furnace. In addition, provided is a pyrolytic furnace which blocks outflow of heating gas or water gas by providing seal portions at the attachment positions of a body part, a reaction tube, and a water gas outlet part, etc. of the pyrolytic furnace, and which maintains a pyrolysis reaction temperature by providing a pyrolysis promoting mechanism to the reaction tube. Provided is a water gas generation system which has excellent thermal efficiency and in which a combustion gas flow path is formed so as to allow combustion gas generated by a carbonizing furnace to flow through a carbonizing furnace, a pyrolytic furnace, a steam superheater, a steam generator, a dryer, and the like. Provided is a hydrogen gas generation system or a power generation system formed by combining the water gas generation system with a hydrogen purifying apparatus or a power generation equipment.

A reactor for reforming a liquid hydrocarbon fuel, and associated processes and systems, are described herein. In one example, a two stage process is disclosed in which a first reactor is coupled to a second stage reactor having a reaction volume greater than the first reactor. In the first reactor, the liquid hydrocarbon fuel is partially reformed and thereafter is inputted into the second stage reactor for complete partial oxidation. The reaction product is at last partially synthesis gas, a mixture of carbon monoxide, hydrogen, as well as other low hydrocarbons such as methane, ethylene, ethane, and acetylene. The low hydrocarbons can be reformed further in a solid oxide fuel cell. A portion of the gaseous, rotating contents of the second stage reactor may be input into the first reactor to help generate and sustain rotation within the first reactor.

A method is provided for removing tar from a gas by contacting a first gas containing tar with a second gas containing oxygen for time period sufficient to effect oxidation of at least a portion of the tar in the first gas, thus producing an oxidized product gas that contains less tar than the first gas. The method can also include heating a fluidized particulate material in a combustor, introducing the heated fluidized particulate material from the combustor and a biomass feedstock into a gasifier, such that heat from the heated fluidized particulate material causes the gasification of at least a portion of the biomass feedstock to form a tar-containing product gas, the first gas may contain at least a portion of the tar-containing gas, and the tar-containing gas may be extracted from the gasifier prior to contacting the first gas with the second gas.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; recovering at least part of the raw synthesis gas from the gasification zone and supplying at least part of the recovered raw synthesis gas to a partial oxidation zone; equilibrating the H.sub.2:CO ratio of the raw synthesis gas in the partial oxidation zone to obtain equilibrated synthesis gas; recovering at least part of the equilibrated synthesis gas from the partial oxidation zone and treating the gas to remove impurities and generate a fine synthesis gas; and converting the optionally adjusted fine synthesis gas into the useful product in a further chemical reaction requiring a usage ratio.

A two-reactor catalytic system including a catalytic membrane gasification reactor and a catalytic membrane water gas shift reactor. The catalytic system, for converting biomass to hydrogen gas, features a novel gasification reactor containing both hollow fiber membranes that selectively allow O.sub.2 to permeate therethrough and a catalyst that facilitates tar reformation. Also disclosed is a process of converting biomass to H2. The process includes the steps of, among others, introducing air into a hollow fiber membrane; mixing the O.sub.2 permeating through the hollow fiber membrane and steam to react with biomass to produce syngas and tar; and reforming the tar in the presence of a catalyst to produce more syngas.

A system includes a first reactor that may gasify a first feed to generate a first syngas. The first feed has a first particle size distribution (PSD.sub.1). The system also includes a second reactor that may receive the first feed, a second feed, and at least a portion of the first syngas. The second reactor may gasify the second feed to generate additional syngas, and the second feed has a second particle size distribution (PSD.sub.2) that is different from the first PSD. The second reactor includes an elutriation zone disposed on a first end of the second reactor. The elutriation zone may receive the first and second feed. The second reactor also includes a fluidized bed disposed at a second end of the second reactor that is substantially opposite the first end. The fluidized bed is fluidly coupled to the first reactor and may receive the portion of the first syngas via a syngas inlet. The system also includes a gas-solids separation section fluidly coupled to the first and second reactors. The gas-solids separation section may receive the first feed and partially reacted particles of the second feed from the elutriation zone and may feed a combined feed consisting of the first feed and the partially reacted particles of the second feed to the first reactor.