The present invention relates to a method and system for recovering and processing a hydrocarbon mixture from a subterranean formation. The method comprises: (i) mobilizing said hydrocarbon mixture; (ii) recovering said mobilized hydrocarbon mixture; (iii) deasphalting said recovered hydrocarbon mixture to produce deasphalted hydrocarbon and asphaltenes; (iv) gasifying said asphaltenes in a gasifier to generate hydrogen, steam and/or energy and CO.sub.2; (v) upgrading said deasphalted hydrocarbon by hydrogen addition to produce upgraded hydrocarbon; and (vi) adding a diluent to said upgraded hydrocarbon, wherein said method is at least partially self-sufficient in terms of hydrogen and diluent.

The present invention relates to net-zero hydrogen plants and methods of operating said plants having a lower cost and much larger scale compared to electrolysis driven plants utilized to produce green hydrogen.

An amount of atmospheric emission of carbon dioxide can be reduced by a method for producing a synthetic fuel including a gasification step G of gasifying waste by reacting it with oxygen and water at a high temperature, a carbon dioxide separation step S of separating carbon dioxide from a gasified gas G1 produced in the step G and an FT synthesis step FT of producing the synthetic fuel by Fischer-Tropsch synthesis from a synthetic gas G2 from which carbon dioxide has been separated in the step S, the method for producing a synthetic fuel further including a carbon dioxide electrolysis step E of electrolyzing the carbon dioxide separated in the step S to produce an electrolyzed gas G3 containing carbon monoxide and carbon dioxide and a methanol synthesis step M of reacting the electrolyzed gas G3 produced in the step E with hydrogen to produce methanol.

A system includes a radiant syngas cooler which receives and cools syngas generated in a gasifier. The radiant syngas cooler includes an outer shell of the radiant syngas cooler defining an annular space of the radiant syngas cooler and a heat exchange tube of the radiant syngas cooler positioned within the annular space and configured to flow a cooling medium. The heat exchange tube is configured to enable heat exchange between the syngas and the cooling medium to cool the syngas. The radiant syngas cooler includes a downcomer tube of the radiant syngas cooler which supplies the cooling medium to the heat exchange tube, where the downcomer tube includes a downflow portion positioned outside of the annular space of the radiant syngas cooler. The downflow portion is fluidly coupled to a header, and the header fluidly couples the downcomer tube to the heat exchange tube.

A method of start-up for a gasification system includes establishing a flow of a start-up fuel external to the gasifier prior to ignition of the gasifier. The method also includes establishing a start-up liquid feed external to the gasifier during gasifier start-up. The method further includes channeling the start-up liquid feed and the start-up fuel to the gasifier during gasifier start-up.

In one aspect, a gasification system for use with low rank fuel is provided The system includes a pyrolysis unit positioned to receive a feed of low rank fuel, the pyrolysis unit being configured to pyrolyze the low rank fuel to produce pyrolysis gas and fixed carbon. The system also includes a gasifier configured to produce a syngas stream using the received fixed carbon, a cooler configured to receive and cool the syngas stream, and a first conduit coupled between the cooler and the pyrolysis unit. The first conduit is configured to recycle at least a portion of the syngas stream to the pyrolysis unit such that the recycled syngas stream is mixed with the pyrolysis gas to produce a hydrocarbon-rich syngas stream containing gasification by-products. The system also includes a by-product recovery system coupled to the pyrolysis unit for removing the gasification by-products from the hydrocarbon-rich syngas stream.

There is provided coal gasification unit including: a coal gasifier; a char recovery unit; flare equipment; an air flow rate adjustment valve and an oxygen supply flow passage that supply oxygen-containing gas to the coal gasifier; an inert gas supply flow passage that supplies nitrogen gas to an upstream side of the char recovery unit; and a control unit that controls a supply amount of the oxygen-containing gas and a supply amount of the nitrogen gas, in which the coal gasifier has a starting burner, and in which the control unit controls the supply amount of the nitrogen gas prior to starting combustion of starting fuel by the starting burner so that an oxygen concentration of mixed gas in which combustion gas generated by combustion of the oxygen-containing gas and the starting fuel has been mixed with the nitrogen gas becomes not more than an ignition concentration.

Novel redox based systems for fuel and chemical production with in- situ CO.sub.2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydro genation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO.sub.2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

Processes for converting ethane into ethylene include the steps of subjecting a water feed stream to electrolysis to form O.sub.2 and H.sub.2, subjecting a mixture of ethane and O.sub.2 to oxidative dehydrogenation to form a reaction product containing ethylene, acetic acid, water, and CO/CO.sub.2, separating the reaction product into an ethylene product stream, an acetic acid product stream, a water product stream, and a gas stream containing CO/CO.sub.2, and introducing the water product stream into the water feed stream for electrolysis. The ethylene product stream can be contacted with a suitable polymerization or oligomerization catalyst composition to produce ethylene polymers or ethylene oligomers.

A carbon capture enabled system and method for generating electric power and/or fuel from methane containing sources using oxygen transport membranes by first converting the methane containing feed gas into a high pressure synthesis gas. Then, in one configuration the synthesis gas is combusted in oxy-combustion mode in oxygen transport membranes based boiler reactor operating at a pressure at least twice that of ambient pressure and the heat generated heats steam in thermally coupled steam generation tubes within the boiler reactor; the steam is expanded in steam turbine to generate power; and the carbon dioxide rich effluent leaving the boiler reactor is processed to isolate carbon. In another configuration the synthesis gas is further treated in a gas conditioning system configured for carbon capture in a pre-combustion mode using water gas shift reactors and acid gas removal units to produce hydrogen or hydrogen-rich fuel gas that fuels an integrated gas turbine and steam turbine system to generate power. The disclosed method and system can also be adapted to integrate with coal gasification systems to produce power from both coal and methane containing sources with greater than 90% carbon isolation.