A lubricant composition for high compression spark ignition engines that contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A method for preventing or reducing engine knock and pre-ignition in an engine lubricated with a formulated oil. The formulated oil has a composition including at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A fuel composition for high compression spark ignition engines that contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A method for preventing or reducing engine knock and pre-ignition in an engine by using a fuel additive composition in a gasoline fuel composition. The fuel additive composition contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

A lubricant composition for high compression spark ignition engines that contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A method for preventing or reducing engine knock and pre-ignition in an engine lubricated with a formulated oil. The formulated oil has a composition including at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A fuel composition for high compression spark ignition engines that contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A method for preventing or reducing engine knock and pre-ignition in an engine by using a fuel additive composition in a gasoline fuel composition. The fuel additive composition contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

The present invention relates to lubricating compositions comprising a compound of Formula I: ##STR00001##
wherein R.sub.1-R.sub.4 and R.sub.5-R.sub.8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q.sub.1 and Q.sub.2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2?, [Mo.sub.2S.sub.9O].sup.2?, [Mo.sub.2S.sub.10].sup.2?, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.

The present invention relates to lubricating compositions comprising a compound of Formula I: ##STR00001##
wherein R.sub.1-R.sub.4 and R.sub.5-R.sub.8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q.sub.1 and Q.sub.2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2?, [Mo.sub.2S.sub.9O].sup.2?, [Mo.sub.2S.sub.10].sup.2?, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.

Disclosed is a method using a lubricating composition including at least one base oil and at least one organomolybdenum compound chosen from among molybdenum dithiophosphate compounds for preventing or reducing pre-ignition in an engine, preferably in a motor vehicle.

The present invention provides a Molybdenum or Tungsten chalcogenide nanoobject having: (a) an object size comprised from 0.1 to 500 nm, and (b) from 1 to 99% by weight of molecules of formula (I) with respect to the total weight of the nanoobject, wherein: A is OH; X is selected from: (C.sub.1-C.sub.20)alkyl optionally substituted with one or more radicals; a 2 to 20-member heteroalkyl optionally substituted with one or more radicals; and a homopolymer or copolymer comprising a polymeric chain; B is selected from: H, OH, NH.sub.2, (C.sub.1-C.sub.4)alkyl, halogen, phenyl substituted with one or more halogen radicals, benzyl substituted with one or more halogen radicals, C(O)R.sub.3, C(O)(R.sub.7), OC(O)(O)R.sub.3, C(O)(O.sup.), C(O)(O)R.sub.3, OR.sub.3, CH(OR.sub.3)(OR.sub.4), C(OR.sub.3)(OR.sub.4)(R.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5)(OR.sub.6), NR.sub.1R.sub.2, N.sup.+R.sub.1R.sub.2R.sub.3, C(NR.sub.1)(R.sub.2), C(O)(NR.sub.1R.sub.2), N(C(O)(R.sub.1)) (C(O)(R.sub.2))(R.sub.3), O(CN), NC(O), ONO.sub.2, CN, NC, ON(O), NO.sub.2, NO, C.sub.5H.sub.4N, SR.sub.1, SSR.sub.1, S(O)(R.sub.1), S(O)(O)(R.sub.1), S(O)(OH), S(O)(O)(OH), SCN, NCS, C(S)(R.sub.1), PR.sub.1R.sub.2, P(O)(OH).sub.2, OP(O)(OH).sub.2, OP(O)(OR.sub.1)(OR.sub.2), B(OH), B(OR.sub.1)(OR.sub.2), and B(OR.sub.1)(R.sub.2); provided that when B is H or (C.sub.1-C.sub.4) alkyl, then X is a homopolymer, a copolymer, or a 2 to 20-member heteroalkyl optionally substituted with one or more radicals as defined above.

The present invention also provides processes for the preparation of the nanoobjects, their use as additive for reducing the friction coefficient of a material, and compositions comprising thereof.

A-X-B(I)

The present invention provides a Molybdenum or Tungsten chalcogenide nanoobject having: (a) an object size comprised from 0.1 to 500 nm, and (b) from 1 to 99% by weight of molecules of formula (I) with respect to the total weight of the nanoobject, wherein: A is OH; X is selected from: (C.sub.1-C.sub.20)alkyl optionally substituted with one or more radicals; a 2 to 20-member heteroalkyl optionally substituted with one or more radicals; and a homopolymer or copolymer comprising a polymeric chain; B is selected from: H, OH, NH.sub.2, (C.sub.1-C.sub.4)alkyl, halogen, phenyl substituted with one or more halogen radicals, benzyl substituted with one or more halogen radicals, C(O)R.sub.3, C(O)(R.sub.7), OC(O)(O)R.sub.3, C(O)(O.sup.), C(O)(O)R.sub.3, OR.sub.3, CH(OR.sub.3)(OR.sub.4), C(OR.sub.3)(OR.sub.4)(R.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5)(OR.sub.6), NR.sub.1R.sub.2, N.sup.+R.sub.1R.sub.2R.sub.3, C(NR.sub.1)(R.sub.2), C(O)(NR.sub.1R.sub.2), N(C(O)(R.sub.1)) (C(O)(R.sub.2))(R.sub.3), O(CN), NC(O), ONO.sub.2, CN, NC, ON(O), NO.sub.2, NO, C.sub.5H.sub.4N, SR.sub.1, SSR.sub.1, S(O)(R.sub.1), S(O)(O)(R.sub.1), S(O)(OH), S(O)(O)(OH), SCN, NCS, C(S)(R.sub.1), PR.sub.1R.sub.2, P(O)(OH).sub.2, OP(O)(OH).sub.2, OP(O)(OR.sub.1)(OR.sub.2), B(OH), B(OR.sub.1)(OR.sub.2), and B(OR.sub.1)(R.sub.2); provided that when B is H or (C.sub.1-C.sub.4) alkyl, then X is a homopolymer, a copolymer, or a 2 to 20-member heteroalkyl optionally substituted with one or more radicals as defined above.

The present invention also provides processes for the preparation of the nanoobjects, their use as additive for reducing the friction coefficient of a material, and compositions comprising thereof.

A-X-B(I)

Disclosed is a lubricating composition including at least one base oil and at least one organomolybdenum compound selected from the molybdenum dithiophosphate compounds or the sulphur-free molybdenum complexes, for preventing or reducing pre-ignition in an engine, preferably in a vehicle engine.

The purpose of the present invention is to provide organometallic salt compositions that are useful as lubricant additives and/or in lubricant additive compositions to reduce friction and wear, and also have improved solubility in all four types of hydrocarbon base oils (Groups I-IV) at a variety of concentrations and under a variety of conditions. The organometallic salt composition is derived from at least one long chain monocarboxylic acid and a single metal in combination with at least one short or medium branched-chain monocarboxylic acid. The compositions are particularly useful in combination with activated complexes comprising a first metal component, a second metal component and particles comprising the first metal component.

The purpose of the present invention is to provide organometallic salt compositions that are useful as lubricant additives and/or in lubricant additive compositions to reduce friction and wear, and also have improved solubility in all four types of hydrocarbon base oils (Groups I-IV) at a variety of concentrations and under a variety of conditions. The organometallic salt composition is derived from at least one long chain monocarboxylic acid and a single metal in combination with at least one short or medium branched-chain monocarboxylic acid. The compositions are particularly useful in combination with activated complexes comprising a first metal component, a second metal component and particles comprising the first metal component.