The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

The present disclosure provides compounds of formula (I), and preparation method thereof,

##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

Disclosed are refrigerants comprising at least about 97% by weight of a blend of three compounds, said blend consisting of:

from about 38% by weight to about 48% by weight difluoromethane (HFC-32),
from about 6% by weight to about 12% by weight pentafluoroethane (HFC-125),
from about 33% by weight to about 41% by weight trifluoroiodomethane (CF.sub.3I) and
from about 2% by weight to about 16% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf)
wherein the percentages are based on the total weight of the three compounds in the blend, and methods and systems which use same.

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

The present disclosure relates to a lubricant composition including an anti-wear additive and metal nanoparticles. The lubricant composition according to the disclosure has, simultaneously, good stability as well as good, long-lasting friction properties.

The invention provides a lubricant composition for an eccentrically oscillating speed reducer of planetary gear type, which is capable of extending the life of the speed reducer under high temperatures and keeping low input torque at low temperatures, and includes (a) a base oil containing a synthetic oil, (b) a hydrocarbon wax, and (c) at least one calcium salt selected from the group consisting of a calcium salt of petroleum sulfonic acid, a calcium salt of alkyl aromatic sulfonic acid, a calcium salt of oxidized wax, an overbasic calcium salt of petroleum sulfonic acid, an overbasic calcium salt of alkyl aromatic sulfonic acid, and an overbasic calcium salt of oxidized wax.

A refrigerator oil composition containing an epoxy compound (X) having at least one of an olefin skeleton and a terpene skeleton, and a base oil (Y).

The invention discloses synergistic combinations of surfactant blends and cleaning compositions employing the same. In certain embodiments a surfactant system is disclosed which includes an extended anionic surfactant with novel linker surfactants including one or more of an alkyl glycerol ether, an ethoxylated alkyl glycerol ether, an alcohol ethoxylate and/or a Gemini surfactant. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.

A bearing grease includes a base oil and a thickener, and the base oil includes mineral oil and poly-α-olefin. The poly-α-olefin may be a blend of poly-α-olefin having a kinetic viscosity higher than that of the mineral oil and poly-α-olefin having a kinetic viscosity equal to or lower than that of the mineral oil, and the kinetic viscosity of the base oil at 40° C. is in a range of 40 through 90 mm.sup.2/s. The amount of the poly-α-olefin by mass in the base oil is greater than the amount of the mineral oil by mass in the base oil. The worked penetration of the grease is in a range of 200 through 250. The grease reduces flying grease and outgas and has superior low-temperature characteristics.

Provided herein is a unique process that prepares a saturated hydrocarbon mixture with well-controlled structural characteristics that address the performance requirements driven by the stricter environmental and fuel economy regulations for automotive engine oils. The process allows for the branching characteristics of the hydrocarbon molecules to be controlled so as to consistently provide a composition that has a surprising CCS viscosity at −35° C. (ASTM D5329) and Noack volatility (ASTM D5800) relationship. The process comprises providing a specific olefinic feedstock, oligomerizing in the presence of a BF.sub.3 catalyst, and hydroisomerizing in the presence of a noble-metal impregnated, 10-member ring zeolite catalyst.